• Title/Summary/Keyword: High pressures

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Triaxial shear behavior of calcium sulfoaluminate (CSA)-treated sand under high confining pressures

  • James Innocent Ocheme;Sakiru Olarewaju Olagunju;Ruslan Khamitov;Alfrendo Satyanaga;Jong Kim;Sung-Woo Moon
    • Geomechanics and Engineering
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    • v.33 no.1
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    • pp.41-51
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    • 2023
  • Cementitious materials such as Ordinary Portland Cement (OPC), fly ash, lime, and bitumen have been employed for soil improvement over the years. However, due to the environmental concerns associated with the use of OPC, substituting OPC with calcium sulfoaluminate (CSA) cement offers good potential for ground improvement because it is more eco-friendly. Although earlier research has investigated the stabilizing effects of CSA cement-treated sand, no attempt has been made to examine soil behavior under high confining pressure. As a result, this study aimed to investigate the shear strength and mechanical behavior of CSA cement-treated sand using a consolidated drained (CD) triaxial test with high confining pressure. The microstructure of the examined sand samples was investigated using scanning electron microscopy. This study used sand with CSA cement contents of 3%, 5%, and 7% and confining pressures of 0.5, 1.0, and 1.5 MPa. It revealed that the confining pressures and CSA cement content significantly affected the stress-strain and volumetric change behavior of CSA cement-treated sand at high confining pressures.

Viscosity of Liquids under High Pressures

  • Wonsoo Kim;Hyungsuk Pak;Tong-Seek Chair
    • Bulletin of the Korean Chemical Society
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    • v.11 no.1
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    • pp.28-31
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    • 1990
  • By using Pak's theory of liquid, a phenomenological theory of viscosity proposed by the authors is applied to liquids under high pressures. The calculated viscosities for various simple substances are in good agreements with those of the observed values over wide pressure ranges.

Isotope Selectivity in the CO$_2$Laser Induced Decomposition of Trichloroethylene-H and Trichloroethylene-D

  • Koo Sang Man;Chun Byung Soo;Choo Kwang Yul
    • Bulletin of the Korean Chemical Society
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    • v.10 no.1
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    • pp.96-101
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    • 1989
  • The infrared multiphoton decomposition of trichloroethylene-H(TCE-H) and trichloroehtylene-D(TCE-D) was studied by using the high power $CO_2$ laser. The pressure dependence of TCE-H decomposition showed that the HCl elimination channel to form ClC ≡ CCl was the major step at high pressures, while the HC ≡ CCl formation step became important at low pressures. $Cl_2C$ = CHCl ${\rightarrow}$ (high pressure) ClC ${\equiv}$ CCl + HCl ${\rightarrow}$ (low pressure) HC ${\equiv}$ CCl + 2Cl${\cdot}$($Cl_2$) The IRMPD of TCE-H and TCE-D mixtures with 10P(20) laser line showed that optimum conditions of large isotope selectivity were the low system pressures and high laser powers. The experimentally observed dependence of the branching ratios on the pressure and laser fluence, and the isotope selectivity coefficients were quantitatively explained by using the modified energy grained master equations (EGME) model.

Numerical investigation of flow structures and aerodynamic pressures around a high-speed train under tornado-like winds

  • Simin Zou;Xuhui He;Teng Wu
    • Wind and Structures
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    • v.38 no.4
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    • pp.295-307
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    • 2024
  • The funnel-shaped vortex structure of tornadoes results in a spatiotemporally varying wind velocity (speed and direction) field. However, very limited full-scale tornado data along the height and radius positions are available to identify and reliably establish a description of complex vortex structure together with the resulting aerodynamic effects on the high-speed train (HST). In this study, the improved delayed detached eddy simulation (IDDES) for flow structures and aerodynamic pressures around an HST under tornado-like winds are conducted to provide high-fidelity computational fluid dynamics (CFD) results. To demonstrate the accuracy of the numerical method adopted in this study, both field observations and wind-tunnel data are utilized to respectively validate the simulated tornado flow fields and HST aerodynamics. Then, the flow structures and aerodynamic pressures (as well as aerodynamic forces and moments) around the HST at various locations within the tornado-like vortex are comprehensively compared to highlight the importance of considering the complex spatiotemporal wind features in the HST-tornado interactions.

Numerical study on extinction and acoustic response of diluted hydrogen-air diffusion flames with detailed and reduced chemistry (상세 및 축소 반응 메커니즘을 이용한 희석된 수소-공기 확산화염의 소염과 음향파 응답 특성에 관한 수치해석)

  • Son, Chae-Hun;Jeong, Seok-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.11
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    • pp.1527-1537
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    • 1997
  • Extinction characteristics and acoustic response of hydrogen-air diffusion flames at various pressures are numerically studied by employing counterflow diffusion flame as a model flamelet in turbulent flames in combustion chambers. The numerical results show that extinction strain rate increases linearly with pressure and then decreases, and increases again at high pressures. Thus, flames are classified into three pressure regimes. Such nonmonotonic behavior is caused by the change in chemical kinetic behavior as pressure rises. The investigation of acoustic-pressure response in each regime, for better understanding of combustion instability, shows different characteristics depending on pressure. At low pressures, pressure-rise causes the increase in flame temperature and chain branching/recombination reaction rates, resulting in increased heat release. Therefore, amplification in pressure oscillation is predicted. Similar phenomena are predicted at high pressures. At moderate pressures, weak amplification is predicted since flame temperature and chain branching reaction rate decreases as pressure rises. This acoustic response can be predicted properly only with detailed chemistry or proper reduced chemistry.

High Pressure Effect of Vibration in a Hydrogen Bonding Crystal :$NH_4I$ (수소결합을 가진 결정내의 진동의 고압효과 : $NH_4I$)

  • Jeon Seung-Joon
    • Journal of the Korean Chemical Society
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    • v.36 no.5
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    • pp.627-631
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    • 1992
  • A simple one dimensional model was proposed to describe a hydrogen bonding in crystals, which was based on the Lippincott's empirical potential. The model was used to calculate internal stretching vibrational frequencies of $NH_4I$ crystal at high pressures. The calculated results were in agreement with Raman experimental results qualitatively. At relatively lower high pressures, as pressure increases internal stretching vibrational frequencies shift lower due to increase of the hydrogen bonding effect. At higher pressures, the frequencies shift higher due to the repulsive contribution of interatomic potential induced by the reduction of interatomic distance as pressure increases.

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The Development of High Oxygen Pressures and the Stabilization of Unusual Oxidation States of Transition Metals

  • Gerard DEMAZEAU
    • Journal of the Korean Chemical Society
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    • v.42 no.1
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    • pp.135-140
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    • 1998
  • High oxygen pressures appear an important tool in Solid State Chemistry. Two main routes can be developed: (i) the stabilization of thermally unstable oxides, used as precursors, in order to open the synthesis of new materials, (ii) the stabilization of the highest oxidation states of transition metals. This paper is essentially devoted to this second research axis. The methodology developed for preparing new oxides containing Fe(Ⅴ), Ir(Ⅵ), high spin Fe(Ⅳ) and Cu(Ⅲ) is described.

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Numerical Simulation of Wind Pressures on a High-rise Building by Auto-mesh System

  • Tang, Yuanzhe;Cao, Shuyang
    • International Journal of High-Rise Buildings
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    • v.8 no.4
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    • pp.255-264
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    • 2019
  • This paper describes large eddy simulation of wind pressures on a square cylinder in a uniform flow and a high-rise building immersed in an atmospheric turbulent boundary layer. For the atmospheric boundary layer case, the inflow turbulence is generated by a numerical wind tunnel. In the numerical simulation, particular attention is devoted to the performance of an auto hexahedral non-structural mesh. Both simulations are performed for three grid systems: an auto hexahedral non-structured grid, a structured Cartesian grid and a non-structured triangular prism grid, and for three grid numbers. The present study shows that the auto hexahedral unstructured mesh achieves the best simulation results for wind pressures on the square cylinder and the high-rise building. When the grid number is sufficiently large, the differences among the results obtained from the three investigated grid systems are not significant. However, the advantage of the auto hexahedral unstructured mesh becomes clear when the grid number decreases, because it enables a balanced distribution of orthogonal grids. The results described in this paper demonstrate that the auto hexahedral non-structured mesh has good potential applicability to simulation of urban flows.

Marital Satisfaction and Marital Stability : A Comparison of Two Theoretical Models (결혼만족도와 결혼안정성 : 두 이론의 비교)

  • 윤경자
    • Journal of the Korean Home Economics Association
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    • v.35 no.4
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    • pp.31-46
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    • 1997
  • The controversy between Lewis and Spanier's theory and Thomas and kleber's theory on marital satisfaction and marital stability was tested empirically. The results show that while marital satisfaction was the best predictor for marital stability the impact of alternative attractions and external pressures to remaim married was more complicated than both theories predicted depending on the nature of alternative attractions. Thomas and Kleber's theory was supported in most of groups Contrary to Lewis and Spanier's theory alternative atteractions did not negatively affect marital stability of marriages of high qulity. Contrary to both theories external pressures to remain married was not an important predictor of marital stability . In some cases high external pressures to remain married even lowered marital stability. The validity of both theories are discussed.

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