• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.184-187
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• 2007

Hydrogen could be produced from any substance containing hydrogen atoms, such as water, hydrocarbon (HC) fuels, acids or bases. Hydrocarbon fuels couold be converted to hydrogen-rich gas through reforming process for hydrogen production. Even though fuel cell have high efficiency with pure hydrogen from gas tank, it is more beneficial to generate hydrogen from city gas (mainly methane) in residential application such as domestic or office environments. Thus hydrogen is generated by reforming process using hydrocarbon. Unfortunately, the reforming process for hydrogen production is accompanied with unavoidable impurities. Impurities such as CO, $CO_2$, $H_2S$, $NH_3$, and $CH_4$ in hydrogen could cause negative effects on fuel cell performance. Those effects are kinetic losses due to poisoning of electrode catalysts, ohmic losses due to proton conductivity reduction including membrane and catalyst ionomer layers, and mass transport losses due to degrading catalyst layer structure and hydrophobic property. Hydrogen produced from reformer eventually contains around 73% of $H_2$, 20% or less of $CO_2$, 5.8% of less of $N_2$, or 2% less of $CH_4$, and 10ppm or less of CO. Most impurities are removed using pressure swing adsorption (PSA) process to get high purity hydrogen. However, high purity hydrogen production requires high operation cost of reforming process. The effect of carbon dioxide on fuel cell performance was investigated in this experiment. The performance of PEM fuel cell was investigated using current vs. potential experiment, long run (10 hr) test, and electrochemical impedance measurement when the concentrations of carbon dioxide were 10%, 20% and 30%. Also, the concentration of impurity supplied to the fuel cell was verified by gas chromatography (GC).

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.819-826
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• 2022

Fuel cell systems are being supplied to households and buildings to reduce greenhouse gases. The fuel cell systems have problems of high cost and slow startup due to fuel processors. Greenhouse gas reduction of the fuel cell systems is also limited by using natural gas. The problems can be solved by using a hydrogen generator consisting of a reformer and pressure swing adsorption (PSA). However, part load operation of the hydrogen generator is required depending on the hydrogen consumption. In this paper, PSA operation strategies are investigated for part load of the hydrogen generator. Adsorption and purge time were changed in the range of part load ratio between from 0.5 to 1.0. As adsorption time increased, hydrogen recovery increased from 29.09% to 48.34% at 0.5 of part load ratio. Hydrogen recovery and hydrogen purity were also improved by increasing adsorption and purge time. However, hydrogen recovery dramatically decreased to 35.01% at 0.5 of part load ratio.

• Progress in Superconductivity and Cryogenics
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• v.24 no.3
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• pp.62-67
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• 2022

Liquid hydrogen (LH₂) has a higher density than gaseous hydrogen, so it has high transport efficiency and can be stored at relatively low pressure. In order to use efficient bulk hydrogen in the industry, research for the LH₂ supply system is needed. In the high-pressure hydrogen station based on LH₂ currently being developed in Korea, a heat exchanger is used to heat up supercritical hydrogen at 700 bar and 60 K, which is pressurized by a cryogenic high-pressure pump, to gas hydrogen at 700 bar and 300 K. Accordingly, the heat exchanger used in the hydrogen station should consider the design of high-pressure tubes, miniaturization, and freezing prevention. A helical heat exchanger generates secondary flow due to the curvature characteristics of a curved tube and can be miniaturized compared to a straight one on the same heat transfer length. This paper evaluates the heat transfer performance through parametric study on the distance between coils, guide effect, and anti-icing design of helical heat exchanger. The helical heat exchanger has better heat transfer performance than the straight tube exchanger due to the influence of the secondary flow. When the distance between the coils is uniform, the heat transfer is enhanced. The guide between coils increases the heat transfer performance by increasing the heat transfer length of the shell side fluid. The freezing is observed around the inlet of distribution tube wall, and to solve this problem, an anti-icing structure and a modified operating condition are suggested.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.1
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• pp.67-76
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• 2022

We developed a technology that can measure the hydrogen uptake and diffusivity of rubber materials by using the volumetric analysis method and diffusivity analysis program through the measurement of the water level in the graduated cylinder. In this method, hydrogen gas is charged at a certain pressure for a certain period of time for a rubber material exposed to a high-pressure hydrogen gas environment, and then the pressure is reduced to measure the change in the water level in the graduated cylinder in real time, and based on the measured value, it is a technology that can evaluate hydrogen uptake and diffusivity using diffusivity analysis program. Using this method, the hydrogen uptake and diffusivity of the NBR material were measured with respect to the change in the type and weight ratio of the filler used to improve the physical properties of the rubber material. In addition, uncertainty analysis was performed on the diffusivity measurement method.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.3 no.5
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• pp.337-349
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• 1991

Heat and mass transfer rates to spray water droplets for spray transients in a high pressure vessel have been predicted by two different droplet models: the complete mixing model and the non-mixing model. In this process, the ambient fluid surrounding the droplets is a real-gas mixture composed of saturated steam and noncondensable hydrogen gas at high pressure. The physical properties of the mixture are estimated by applying the concept of compressibility factor and using appropriate correlations. A computer program, DROPHMT, to calculate the heat and mass transfer rates for two different droplet models has been developed. As an illustrative application of the computer program to engineering practices, heat and mass transfer rates to spray water droplets for spray transients in a Pressurized Water Reactor (PWR) pressurizer have been calculated, and the typical results have been provided.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.6 no.1
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• pp.57-64
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• 2010

PHE(Process Heat Exchanger) is a key component required to transfer heat energy of $950^{\circ}C$ generated in a VHTR(Very High Temperature Reactor) to the chemical reaction that yields a large quantity of hydrogen. Korea Atomic Energy Research Institute established the gas loop for the performance test of components, which are used in the VHTR, and they manufactured a PHE prototype to be tested in the loop. In this study, as part of the high-temperature structural-integrity evaluation of the PHE prototype, which is scheduled to be tested in the gas loop, we carried out high-temperature structural-analysis modeling, thermal analysis, and thermal expansion analysis of the PHE prototype. The results obtained in this study will be used to design the performance test setup for the PHE prototype.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.7 no.3
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• pp.48-53
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• 2011

A PHE (Process Heat Exchanger) is a key component required to transfer heat energy of $950^{\circ}C$ generated in a VHTR (Very High Temperature Reactor) to the chemical reaction that yields a large quantity of hydrogen. A small-scale PHE prototype made of Hastelloy-X is being tested in a small-scale gas loop at Korea Atomic Energy Research Institute. In this study, as a part of the evaluation on the high-temperature structural integrity of the small-scale PHE prototype, we carried out macroscopic high-temperature structural analysis of the small-scale PHE prototype under the gas loop test conditions considering the pipeline stiffness.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.383-386
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• 2008

The four-bed PSA process using a layered bed of activated carbon and zeolite 5A was studied to produce a high purity hydrogen product from SMR off-gas. At a desired product purity (99.999%+), the recovery increased with decreasing the linear velocity. However, the difference of the increasing of the recovery became smaller with the decreasing of the linear velocity and then was similar from below the linear velocity 3.9 cm/s. When the adsorbents, the feed gas composition, and the operating conditions are given, the residence time is mainly a function for design of the PSA bed size. The minimum residence time exists to obtain the maximum recovery at desired product purity.

• Journal of the Korean Institute of Gas
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• v.23 no.1
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• pp.62-69
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• 2019

The high pressure underground pipelines of industrial states such as Ulsan, Yeosu consist with not only the pipelines for the utility support such as Raw material of petrochemical industry and steam, but also high pressure pipelines of toxic, flammable gas intricately like a web. Therefore, in this study, based on in-depth comparison analysis of industrial estate pipelines, and underground city gas pipelines' safety management status, excavation frequency, excavation depth, patrol period which are pipe damage impact factor by the other construction are analyzed. And, as a result, risk changes and correlations due to risk reduction strategy of the other construction are compared to be presented the safety inspection operation model for the high pressure underground pipelines of industrial estates.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.4
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• pp.425-435
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• 2014

Simulation studies on catalytic methanation reaction in externally cooled tubular reactor filled with monolithic catalysts were carried out using a general purpose modelling tool $gPROMS^{(R)}$. We investigated the effects of operating parameters such as gas space velocity, temperature and pressure of feeding gas on temperature distribution inside the reactor, overall CO conversion, and chemical composition of product gas. In general, performance of methanation reaction is favored under low temperature and high pressure for a wide range of their values. However, methane production becomes negligible at temperatures below 573K when the reactor temperature is not high enough to ignite methanation reaction. Capacity enhancement of the reactor by increasing gas space velocity and/or gas inlet pressure resulted no significant reduction in reactor performance and heat transfer property of catalyst.