• Title/Summary/Keyword: High ozone concentration

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Studies of High-Ozone Episodes in the Greater Seoul Area between 1990 and 1997 (1990~1997 기간 중 서울.수도권 지역의 고농도 오존 사례 연구)

  • 김영성;오현선
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.3
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    • pp.267-280
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    • 1999
  • To investigate the characteristics of high-ozone occurrences in the Greater Seoul Area(GSA), three high-ozone episodes were selected, for which the ozone warning for concentration above 120 ppb might be issued. The selection was on the basis of morning wind directions and speeds, and daily maximum ozone concentrations measured between 1990 and 1997. The episodes chosen to meet selection criteria were seven days in July 1992, nine days in July 1994, and three days in August 1994, as respectively characterized by southwesterly, easterly, and calm winds in the morning. However, more than 80% of high-ozone days in the GSA were associated with calm winds and the concomitant accumulation of local emission in the morning, rather than being due to transport of ozone or its precursors. This is believed to be the primary reason why ozone concentrations in the GSA varied in a completely different manner even between adjacent monitoring stations. Several premises for initiating research studies for resolving these local variations of ozone concentrations in the GSA are also discussed.

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The Influences of 5ea Breeze on Surface Ozone Concentration in Pusan Coastal Area, Korea (부산 연안역의 오존 농도에 미치는 해풍의 영향)

  • 김유근;이화운
    • Journal of Environmental Science International
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    • v.5 no.3
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    • pp.265-275
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    • 1996
  • Air pollution characteristics and the influence of sea breeze on surface ozone concentration were studied using the data measured at 7 air quality continuous monitoring stations from June to September using 3 years (1990, 1993, 1994) in Pusan coastal area. Among the 246 sea breeze days for research Period, there were approximately 89 sea breeze days (36%) from lune to September, And there were 120 the episode days (68%) of ozone greater than or equal to 60 ppb in summer season. In 89 sea breeze days, the episode day was highly marked as 56 days (63%). So, we knew that the sea breeze greatly affects the occurence of ozone episode day. the ozone concentration under the condition of the sea breeze increase about 40% in the daytime. Frequencies distribution of $O_3$ concentration for sea breeze moved toward high concentration class. The characteristics of ozone concentration in relation to meteorological conditions of sea breeze is significant because we can discover major weather factors for eastablishing an air pollution- weather forecast system. For further. study about meterological approach method for photochemical air pollution, it is necessary to explain the characteristics of atmosphere below 1, 000 m, especially concerning the formation mechanism of inversion layers. And finally, we will study the relationships to synoptic weather conditions and vertical structure and diurnal variation of local wind systems including sea breeze, and the vertical movements of atmosphere in the city.

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Forecasting High-Level Ozone Concentration with Fuzzy Clustering (퍼지 클러스터링 이용한 고농도오존예측)

  • 김재용;김성신;왕보현
    • Journal of the Korean Institute of Intelligent Systems
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    • v.11 no.4
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    • pp.336-339
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    • 2001
  • The ozone forecasting systems have many problems because the mechanism of the ozone concentration is highly complex, nonlinear, and nonstationary. Especially, the performance of the prediction results in the high-level ozone concentration are not good. This paper describes the modeling method of the ozone prediction system using neuro-fuzzy approaches and fuzzy clustering methods. The dynamic polynomial neural network (DPNN) based upon a typical algorithm of GMDH (group method of data handling) is a useful method for data analysis, the identification of nonlinear complex systems, and prediction of dynamical systems.

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Growth, Physiological Responses and Ozone Uptake of Five Betula Species Exposed to Ozone

  • Lee, Jae-Cheon;Han, Sim-Hee;Kim, Pan-Gi;Jang, Suk-Seong;Woo, Su-Young
    • The Korean Journal of Ecology
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    • v.26 no.4
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    • pp.165-172
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    • 2003
  • The objectives of this study were to examine the physiological responses to ozone and to measure ozone uptake rates of Betula species exposed to relatively high concentration of pollutants. At the end of the growing season, photosynthesis, pigments contents, antioxidants (SOD and GR) and ozone uptake rates were measured or estimated at the leaves of five Betula species (Betula costata, B. davurica, B. platyphylla var. japonica, B. schmidtii and B. ermanii) exposed to 100ppb ozone concentration. On the termination of the experiment, growth effects were determined by measuring leaf area and dry weights of leaf, stem and root. Ozone treatment showed the significant reduction the leaf area and dry weight of four Betula species, except for B. ermanii. Shoot / root (SR) ratio of five species represented two different types. SR ratio of B. costata and B. davurica were lower than control, in contrast, SR ratio of B. platyphylla var. japonica, B. schimidtii and B. emani, were higher than that of control. The photosynthetic responses of five species were different in responses to ozone exposure. Four species, except for B. emanii, maintained or increased the stomatal conductance, but B. emanii decreased both stomatal conductance and photosynthesis. SOD activities of five species decreased by the ozone exposure, especially B. ermanii showed the largest reduction, GR activities of B. platyphylla var. japonica and B. schmidtii increased, B. costata and B. emanii decreased. Instantaneous ozone uptake rate was the highest at the leaves of B. ermanii and B. costata, ozone uptake per seedling was the highest at the leaf of B. schmidtii and B. emanii. It was concluded that B. costata, B. davurica and B. platyphylla var. japonica, appeared the growth reduction and visible ozone injury, were sensitive species to ozone, and B. schmidtii with the increased antioxidant activity and B. ermanii without the growth reduction were relatively resistant species to high ozone concentration at the early growing stage.

Analysis of Time Series Models for Ozone Concentrations at the Uijeongbu City in Korea

  • Lee, Hoon-Ja
    • Journal of the Korean Data and Information Science Society
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    • v.19 no.4
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    • pp.1153-1164
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    • 2008
  • The ozone data is one of the important environmental data for measurement of the atmospheric condition of the country. In this article, the Autoregressive Error (ARE) model have been considered for analyzing the ozone data at the northern part of the Gyeonggi-Do, Uijeongbu monitoring site in Korea. The result showed that both overall and monthly ARE models are suited for describing the ozone concentration. In the ARE model, seven meteorological variables and four pollution variables are used as the as the explanatory variables for the ozone data set. The seven meteorological variables are daily maximum temperature, wind speed, relative humidity, rainfall, dew point temperature, steam pressure, and amount of cloud. The four air pollution explanatory variables are Sulfur dioxide(SO2), Nitrogen dioxide(NO2), Cobalt(CO), and Promethium 10(PM10). Also, the high level ozone data (over 80ppb) have been analyzed four ARE models, General ARE, HL ARE, PM10 add ARE, Temperature add ARE model. The result shows that the General ARE, HL ARE, and PM10 add ARE models are suited for describing the high level of ozone data.

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Construction and Evaluation of Oxidation System for Superconductor Thin Film (초전도 박막 제작을 위한 산화 시스템 구축 및 평가)

  • 임중관;박용필;송경용
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.2
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    • pp.163-167
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    • 2003
  • Ozone is strong and useful oxidizing gas for the fabrication of oxidation thin films. In order to obtain high quality thin film, the ozone concentration must be increased. An ozone condensation system is evaluated in the viewpoint of an ozone supplier for oxidation thin film growth. Ozone is condensed by the adsorption method and ozone concentration reaches 8.5 mol% by 2.5 h after the beginning of the ozone condensation is negligible if the condensed ozone is transferred between the ozone condensation system and the film growth chamber within a few minutes. CuO peak which is the result of the obtained Cu-films using condensed ozone appears by XRD patterns.

A Study on the Development of Thin ESP for High Efficient Air-conditioner (공조용 박형 전기집진장치 개발에 관한 연구)

  • Hong, Yeong-Gi;Sin, Su-Yeon;Jo, Jeong-Su;Park, Jeong-Hu
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.1
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    • pp.34-38
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    • 1999
  • In order to develop a thin type ESP(Electrostatic Precipitator) for high efficient air-conditioner with low concentration of ozone generation, collecting electrode spacing should be narrower than that from Deutsch formula and minimizes discharge current in ionizer. In this paper, the effect of applied voltage on the precipitation efficiency and ozone concentration of scroll type ESP was studied. As a result, precipitation efficiency(one pass) was improved by about 30[%] from increment of collector voltage(3.5[㎸]). Precipitation efficiency was increased with increasing ionizer voltage. And after some point, the efficiency was saturated. At the point, voltage and ionizer current was 5.2[㎸] and 95$[\muA]$ per meter respectively. At these applied voltage conditions, ozone concentration was saturated about 0.01[ppm] after 3 hours in 23$[m^3]$ closed room test.

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Development of a Short-term Model for Ozone Using OPI (오존최대농도지표를 이용한 오존단기예측모형 개발)

  • 전의찬;김정욱
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.545-554
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    • 1999
  • We would like to develop a short-term model to predict the time-related concentration of ozone whose reaction mechanism is complex. The paper targets Seoul where an ozone alert system has recently been employed. In order to develop a short-term prediction model for ozone, we suggested the Ozone Peak Indicator(OPI), an equivalent of the potential daily maximum ozone concentration, with precursors being the only limiting factor, and we calculated the Ozone Peak Indicarot as OPI={$ rac{(O_3)_{max}cdot(H_{eH})_{max}(Rad)_{max}$ to preclude the influence of mixing height and solar radiation on the daily maximum ozone concentration. The OPI on the day of the prediction is to be calcultated by using the relation between OPI and the initial value of precursors. The basic prediction formula for time-related ozone concentration was established as $O_3(1)={(OPI)cdot Rad(t-2)H_{eH}}$, using the OPI, solar radiation two hours before prediction and mixing height. We developed, along with the basic formula for predicting photochemical oxidants, "SEOM"(Seoul Empirical Oxidants Model), a Fortran program that helps predict solar radiation and mixing height needed in the prediction of ozone pollution. When this model was applied to Seoul and an analysis of the correlation between the observed and the predicted ozone concentrations was made through SEOM, there appeared a very high correlation, with a coefficient of 0.815. SEOM can be described as a short-term prediction model for ozone concentration in large cities that takes into account the initial values of precursors, and changes in solar radiation and mixing height. SEOM can reflect the local characteristics of a particular and region can yield relatively good prediction results by a simple data input process.t process.

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A Study on Safety Treatment of NOx by Discharge Plasma Reaction (방전Plasma 반응에 의한 NOx의 안전처리에 관한 연구)

  • Choi, Jae-wook;Yamaguma, Mizuki
    • Journal of the Korean Society of Safety
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    • v.15 no.2
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    • pp.92-96
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    • 2000
  • In this experiment, we studied about concentration characteristics of $NO_x$ and generation of ozone in the reactor of corona discharge type by using mixed gas of $NO/N_2$ and $N_2/O_2$. In the case of the initial NO concentration increased, decrease rate of NO concentration was weakened and discharge input power of minimum NO concentration became high. When NO concentration was high, NO decomposition limit was appeared. And NO reduction rate was decreased, when initial NO concentration and discharge input power increased. When discharge input power was 5W, we could know the most proper energy value for treatment of NO. When the concentration of initial NO increased, generation of ozone decreased and in the case of same concentration of NO, according to discharge input power increase, generation of ozone increased.

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Measutements of the ground-level ozone in a rural area of Chongwon, Korea (충북 청원군에서 관측된 지표면 부근의 오존)

  • 윤마병;정용승
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.1
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    • pp.85-93
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    • 1995
  • Measurements of ground level ozone concentrations were made in a rural area of Chongwon (Choongbook Province) from June 1993 to July 1994. High values frequently exceeding 100 ppb (ambient air qualyty standard of Korea) were recorded. High ozone concentrations in the boundary layer were primarily correlated with the several meteorological parameters in warm seasons: pressure, radiation, temperature, precipitation and wind velocity. The annual average concentration of ozone at Chongwon was 17ppb, and this value was relatively higher than those for other cities in Korea. O$\_$3/ concentrations were observed to increase when the ridge of a surface anticyclone was passing over the region, and maximum values(.geq.100 ppb) were observed on the rear sides of high pressure centers and in the warm sectors of cyclones(well head of cold fronts). The ozone concentrations had a negative correlation with the concentration of primary pollutants(e.g., total hydrocarbons).

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