• 제목/요약/키워드: High ozone

검색결과 664건 처리시간 0.026초

CMAQ-HDDM을 이용한 광양만 오존 농도의 국외 기여도 분석 (Quantitative Assessment on Contributions of Foreign NOx and VOC Emission to Ozone Concentrations over Gwangyang Bay with CMAQ-HDDM Simulations)

  • 배창한;김병욱;김현철;김순태
    • 한국대기환경학회지
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    • 제34권5호
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    • pp.708-726
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    • 2018
  • In this study, we examined the contribution of nitrogen oxides and volatile organic compounds emitted from China and Japan to ozone concentrations over Gwangyang-bay, South Korea. We used a chemical transport model, Community Multi-scale Air Quality model, and its instrumented sensitivity tool, High-order Decoupled Direct Method. Intercontinental Chemical Transport Experiment-Phase B 2006 for East Asia and Clean Air Policy Support System 2007 emissions inventories for South Korea were used for the ozone simulation. During the study period, May 2007, the modeled maximum daily 8-hr average ozone concentration among seven air quality monitors in Gwangyang-bay was 68.8 ppb. The contribution of $NO_x$ emissions from China was 19.5 ppb (28%). The highest modeled ozone concentrations and Chinese contributions appeared when air parcels were originated from Shanghai area. The observed 8-hr average ozone concentrations in Gwangyang Bay exceeded the national ambient air quality standard (60 ppb) 203 times by daytime and 56 times by nighttime during the period. It was noticed that many exeedances happened when contribution of Chinese emissions to ozone concentrations over the area increased. Sensitivity analysis shows that a reduction in Chinese $NO_x$ and VOC emissions by 15% could lessen the total exceedance hours by 24%. This result indicates that high ozone concentrations over Gwangyang-bay are strongly enhanced by Chinese emissions.

백판지의 휨강성 증대를 위한 목질섬유의 이용 (2) 오존처리 (Improvement of Bending Stiffness in White Duplex Board by Utilization of Wood Fibers from Medium Density Fiberboard (2) Ozone treatment)

  • 서영범;김현준
    • 펄프종이기술
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    • 제47권1호
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    • pp.1-9
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    • 2015
  • Wood fibers for medium density fiberboard (MDF) was used in the filler layer of the white duplex board for increasing thickness and bulk of the board. The MDF fibers were treated with ozone (3% based on dry weight of the fibers), and mixed together with OCC (old corrugated container) to form paper. Ozone-treated MDF fibers gave high bulk, high tensile strength, high internal bond and fast drainage to the furnish mixed with OCC. It was shown that there were possibilities to reduced basis weight of the filler layer without loss of thickness, stiffness, and tensile strength. Furthermore, it showed the possibility to develop a new kind of board product that has high stiffness as well as high strength properties with light basis weight by application of the ozone-treated MDF fibers.

E. coli B. MQ1844 균주의 오존감수성 유전자의 특성 (A gene responsible for ozone sensitivity (ozrB) in chromosome of escherichia coli B. MQ 1844)

  • 정영섭;;최영길
    • 미생물학회지
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    • 제25권2호
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    • pp.103-109
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    • 1987
  • An ozone-sensitive mutant of Escherichia coli strain B, MQ 1844 is described. Its properties, including high sensitivity to ozone and radiation, inducible filamentation, extensive DNA degradation and impaired DNA synthesis following ozonation, are attributable to a mutation in ozrB, a gene which is cotransducible with malB. Based on differences in phenotypic expression as well as on the particular location of this gene on the bacterial chromosome, ozrB appears as distinct from the other ozone-or radiation-sensitivity genes previously described.

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2009년 봄, 여름철 광양만 지역 오존의 광화학적 특성 분석 (Photochemical Analysis of Ozone Levels in the Gulf of Gwangyang in the Spring and Summer of 2009)

  • 손장호;송상근;이강웅
    • 한국대기환경학회지
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    • 제26권2호
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    • pp.161-176
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    • 2010
  • We examined high ozone episodes observed during the intensive measurement periods (11 May~21 June and 30 July~11 August 2009) in the Gulf of Gwangyang. During that period, there were a few events (or days) in which 1 hr averaged ozone concentrations were greater than 100 ppbv. The analysis of ozone budget and photochemical characteristics related to the ozone production was carried out using a photochemical box model. Ozone sensitivity to $NO_x$ and VOCs was also examined in the study area during the measurement period. Diurnal variation of ozone during the episodes was similar to that of odd hydrogen radicals ($HO_2,CH_3O_2$, and $RO_2$), suggesting significant correlation with photochemical production of ozone during the episodes. In general, ozone concentration in the study area during the measurement period was sensitive to VOCs, whereas ozone was sensitive to $NO_x$ under certain conditions. Ozone sensitivity assessment using a radical budget analysis and $NO_x$/VOCs-control strategy was consistent with that using indicator species ($H_2O_2/HNO_3$ ratio).

한반도를 포함한 동아시아 영역에서 오존전량과 유해자외선의 특성과 예측 (Characteristics and Prediction of Total Ozone and UV-B Irradiance in East Asia Including the Korean Peninsula)

  • 문윤섭;민우석;김유근
    • 한국환경과학회지
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    • 제15권8호
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    • pp.701-718
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    • 2006
  • The average ratio of the daily UV-B to total solar (75) irradiance at Busan (35.23$^{\circ}$N, 129.07$^{\circ}$E) in Korea is found as 0.11%. There is also a high exponential relationship between hourly UV-B and total solar irradiance: UV-B=exp (a$\times$(75-b))(R$^2$=0.93). The daily variation of total ozone is compared with the UV-B irradiance at Pohang (36.03$^{\circ}$N, 129.40$^{\circ}$E) in Korea using the Total Ozone Mapping Spectrometer (TOMS) data during the period of May to July in 2005. The total ozone (TO) has been maintained to a decreasing trend since 1979, which leading to a negative correlation with the ground-level UV-B irradiance doting the given period of cloudless day: UV-B=239.23-0.056 TO (R$^2$=0.52). The statistical predictions of daily total ozone are analyzed by using the data of the Brewer spectrophotometer and TOMS in East Asia including the Korean peninsula. The long-term monthly averages of total ozone using the multiplicative seasonal AutoRegressive Integrated Moving Average (ARIMA) model are used to predict the hourly mean UV-B irradiance by interpolating the daily mean total ozone far the predicting period. We also can predict the next day's total ozone by using regression models based on the present day's total ozone by TOMS and the next day's predicted maximum air temperature by the Meteorological Mesoscale Model 5 (MM5). These predicted and observed total ozone amounts are used to input data of the parameterization model (PM) of hourly UV-B irradiance. The PM of UV-B irradiance is based on the main parameters such as cloudiness, solar zenith angle, total ozone, opacity of aerosols, altitude, and surface albedo. The input data for the model requires daily total ozone, hourly amount and type of cloud, visibility and air pressure. To simplify cloud effects in the model, the constant cloud transmittance are used. For example, the correlation coefficient of the PM using these cloud transmissivities is shown high in more than 0.91 for cloudy days in Busan, and the relative mean bias error (RMBE) and the relative root mean square error (RRMSE) are less than 21% and 27%, respectively. In this study, the daily variations of calculated and predicted UV-B irradiance are presented in high correlation coefficients of more than 0.86 at each monitoring site of the Korean peninsula as well as East Asia. The RMBE is within 10% of the mean measured hourly irradiance, and the RRMSE is within 15% for hourly irradiance, respectively. Although errors are present in cloud amounts and total ozone, the results are still acceptable.

살균과 탈취를 위한 오존 발생장치의 설계

  • 김현종;윤영미;한지혜;김영란;이은미;이현철;정봉우
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2001년도 추계학술발표대회
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    • pp.509-512
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    • 2001
  • Recently, our country's piggery has been becoming large-sized and crowded gradually in scale. Thus, the environment in a piggery is getting worse, which leads to a drop in livestock's immunoactivity. Therefore, livestocks are exposured to many diseases(stress, hypertension, stomach ulcer etc.). In this paper, our intention is to design a low cost ozone-generating device with high capacity to maintain a reasonable ozone level, that is necessary for cleaning the environment in a piggery, but is not too high to cause any harmful influence to human beings and livestock. The results showed that the UV-lamp tube with baffle has an increase of 25% in ozone generation efficiency compared to without baffle and the short retention time of air or high inlet air rate shows high level of ozone.

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입상 활성탄을 이용한 오존공정의 개선에 관한 연구 (A study on improvement of ozone process by Granular Activated Carbon)

  • 이유미;이동석
    • 산업기술연구
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    • 제28권A호
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    • pp.23-26
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    • 2008
  • Ozone/GAC and ozone-GAC processes were introduced for treatment of humic acid, which is representative refractory organic compound. The treatment efficiencies of humic acid in each process were analyzed in pH variation, DOC removal, and $UV_{254}$ decrease. $UV_{254}$ decrease in all processes was comparatively high with efficiency over 92%. $UV_{254}$ decrease in ozone alone process was 85%. DOC removal in Ozone-GAC process was the highest with 75%. Removal by Ozone/GAC, Ozone alone processes were 71% and 33% respectively.

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방전간극변화가 오존생성특성에 미치는 영향 (The Effects of Discharge Gap Variation for Ozone Generation Characteristics)

  • 이상근;전병준;박용권;박원주;이광식
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2001년도 학술대회논문집
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    • pp.135-138
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    • 2001
  • Recently, ozone is utilized In various fields and its needs are expanding. therefore, so many ozone generation methods have been reported in the latest years, its main purpose Is to get the high ozone concentration and to improve the ozone yield. One of them is a plate-type ozone generator. In this paper, the plate-type ozone generator is piled up many folds(3 and 5 electrodes). Ozone concentration and yield were investigated in accordance with power, quantity of supplied gas and gap spacing of plate electrodes.

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기상 오존처리법을 이용한 견직물의 표백성에 관한 연구 (A Study on the Bleaching Properties of Silk Fabric Using Vapor Type Ozone Treatment)

  • 김정민;이문수
    • 한국의류산업학회지
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    • 제6권4호
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    • pp.511-514
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    • 2004
  • We studied on the bleaching properties of silk fabric by vapor type ozone processing using ozone's strong oxidation instead of 28% $H_2O_2$ chemical treatment. When vapor type ozone processing was directly treated to fabrics retaining water to 50~70% pick up ratio, high concentration ozone was generated 14,000ppm(168 mg/h) approximately and finally its bleaching improved. The fabric's bleaching effect was improved because vapor type ozone generated the highest decomposition to oxidation of surface and inter molecules. The experiment revealed that fabric's bleaching was improved by change of the pick-up ratio of vapor type ozone processing. However, tensile strength and elongation were reduced by increase of time, and the time that was assumed as the most optimized time to minimize the reduction of fabric's tensile strength and elongation as well as maximizing the fabric's bleaching was 30 minutes.

오존과 초음파를 이용한 실리콘 웨이퍼의 Post Sliced Cleaning (Post Sliced Cleaning of Silicon Wafers using Ozone and Ultrasound)

  • 최은석;배소익
    • 한국재료학회지
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    • 제16권2호
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    • pp.75-79
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    • 2006
  • The effect of ozone and/or ultrasound treatments on the efficiency of slurry removal in post sliced cleaning (PSC) of silicon ingot was studied. Efficiency of slurry removal was evaluated as functions of time, temperature and surfactant with DOE (Design of Experiment) method. Residual slurries were observed on the wafer surface in case of cleaning by ozone or ultrasound separately. However, a clean wafer surface was appeared when cleaned with ozone and ultrasound simultaneously. It has found that cleaning time was the main effect among temperature, time and surfactant. Elevated temperature, addition of surfactant and high ozone concentration helped to accelerate efficient removal of slurry. The improvement of removal efficiency seems to be related to the formation of more active OH radicals. The highly cleaned surface was achieved at 10 wt% ozone, 1 min and 10 vol% surfactant with ultrasound. Application of ozone and ultrasound might be a useful method for PSC process in wafer cleaning.