• Title/Summary/Keyword: High ozone

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Influence of Isoprene Emissions on Ozone Concentrations in the Greater Busan Area during a High Ozone Episode in 2006 (2006년 오존 고농도 사례 시 부산권 지역 isoprene 배출이 오존 농도에 미치는 영향 분석)

  • Kim, Yoo-Keun;Jo, Young-Soon;Song, Sang-Keun;Kang, Yoon-Hee;Oh, In-Bo
    • Journal of Environmental Science International
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    • v.19 no.7
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    • pp.829-841
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    • 2010
  • The estimation of a biogenic volatile organic compound (BVOC, especially isoprene) and the influence of isoprene emissions on ozone concentrations in the Greater Busan Area (GBA) were carried out based on a numerical modeling approach during a high ozone episode. The BVOC emissions were estimated using a biogenic emission information system (BEIS v3.14) with vegetation data provided by the forest geographical information system (FGIS), land use data provided by the environmental geographical information system (EGIS), and meteorological data simulated by the MM5. Ozone simulation was performed by two sets of simulation scenarios: (1) without (CASE1) and (2) with isoprene emissions (CASE2). The isoprene emission (82 ton $day^{-1}$) in the GBA was estimated to be the most dominant BVOC followed by methanol (56) and carbon monoxide (28). Largest impacts of isoprene emissions on the ozone concentrations (CASE2-CASE1) were predicted to be about 4 ppb in inland locations where a high isoprene was emitted and to be about 2 ppb in the downwind and/or convergence regions of wind due to both the photochemical reaction of ozone precursors (e.g., high isoprene emissions) and meteorological conditions (e.g., local transport).

Fabrication of Ozone Bubble Cleaning System and its Application to Clean Silicon Wafers of a Solar Cell

  • Yoon, J.K.;Lee, Sang Heon
    • Journal of Electrical Engineering and Technology
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    • v.10 no.1
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    • pp.295-298
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    • 2015
  • Ozone micro-bubble cleaning system was designed, and made to develop a unique technique to clean wafers by using ozone micro-bubbles. The ozone micro-bubble cleaning system consisted of loading, cleaning, rinsing, drying and un-loading zones, respectively. In case of the cleaning the silicon wafers of a solar cell, more than 99 % of cleaning efficiency was obtained by dipping the wafers at 10 ppm of ozone for 10 minutes. Both of long cleaning time and high ozone concentration in the wet-solution with ozone micro-bubbles reduced cleaning efficiency because of the re-sorption of debris. The cleaning technique by ozone micro-bubbles can be also applied to various wafers for an ingot and LED as an eco-friendly method.

Analysis of Ozone Concentration by TD and Q-mass Method

  • Lee, Dong-Gyu;Lee, Joon-Ung
    • Transactions on Electrical and Electronic Materials
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    • v.5 no.4
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    • pp.161-165
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    • 2004
  • In order to get oxidizing power enough for growth of a superconductive thin film with oxide gas, concentrated ozone was used. As a method for concentrating ozone, a method for concentrating ozone by adsorbing ozone selectively into silica-gel beads is adopted, and this concentration is analyzed by the ultraviolet absorption method, the thermal decomposition method and the Q-mass analyzing method. Thermal decomposition method is most effective for measurement of a high concentration of ozone. Ozone as concentrated by the adsorption method got to have a concentration of 97 mol % at the maximum, and it was identified that the concentration of the ozone gas was stable for the time while a thin film was formed.

A Study on Ozone Oxidation of Algae (조류의 오존산화에 관한 연구)

  • 김은호;성낙창;최용락
    • Journal of Life Science
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    • v.9 no.5
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    • pp.590-595
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    • 1999
  • The objectives of this research were to estimate variation characteristics of TOC, UV-254 and NH4+-N, etc, if odorous generated algaes flowed into water treatment plant and they contacted with ozone known as typical advanced treatment. It was estimated that pH decreased from initial 7.4 to 2.1 after ozone contact 100min. pH declined to early 10min. suddenly and then pH drop did almost occur. TOC and UV-254 continued to decrease with passed time of ozone contact. NO3--N concentration was much higher than NH4+-N and NO2--N for whole test period. Because ozone oxidized organic matters as various kinds of ion material and ion intensity of sample was extended, conductivity showed high as passed time of ozone contact. Owing to ozone oxidation of algae, color did almost disappear after ozone contact 20min.

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불포화 토양내에서 가스상 오존 이동특성에 대한 Multiphase liquids의 영향

  • 정해룡;최희철
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.124-127
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    • 2003
  • Laboratory scale experiments on in-situ ozonation were carried out to delineate the effects of liquid phases, such as soil water and nonaqeous phase liquid (NAPL) on the transport of gaseous ozone in unsaturated soil. Soil water enhanced the transport of ozone due to water film effect, which prevent direct reaction between soil particles and gaseous ozone, and increased water content reduced the breakthrough time of ozone because of increased average linear velocity of ozone and decreased air-water interface area. Diesel fuel as NAPL also played a similar role with water film, so the breakthrough time of ozone in diesel-contaminated soil was significantly reduced compared with uncontaminated soil. However, ozone breakthrough time was retarded with increased diesel concentration, because of high reactivity of diesel fuel with ozone. In multiphase liquid system of unsaturated soil, the ozone transport was mainly Influenced by nonwetting fluid, diesel fuel in this study.

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Neuro-Fuzzy Approaches to Ozone Prediction System (뉴로-퍼지 기법에 의한 오존농도 예측모델)

  • 김태헌;김성신;김인택;이종범;김신도;김용국
    • Journal of the Korean Institute of Intelligent Systems
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    • v.10 no.6
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    • pp.616-628
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    • 2000
  • In this paper, we present the modeling of the ozone prediction system using Neuro-Fuzzy approaches. The mechanism of ozone concentration is highly complex, nonlinear, and nonstationary, the modeling of ozone prediction system has many problems and the results of prediction is not a good performance so far. The Dynamic Polynomial Neural Network(DPNN) which employs a typical algorithm of GMDH(Group Method of Data Handling) is a useful method for data analysis, identification of nonlinear complex system, and prediction of a dynamical system. The structure of the final model is compact and the computation speed to produce an output is faster than other modeling methods. In addition to DPNN, this paper also includes a Fuzzy Logic Method for modeling of ozone prediction system. The results of each modeling method and the performance of ozone prediction are presented. The proposed method shows that the prediction to the ozone concentration based upon Neuro-Fuzzy approaches gives us a good performance for ozone prediction in high and low ozone concentration with the ability of superior data approximation and self organization.

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A study on dissolved ozone in water (수중 오존의 분해에 관한 연구)

  • Kim, Young-Bae;Cho, Hook-Hee;Seo, Kil-Soo;Lee, Hyeong-Ho
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.2041-2043
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    • 2000
  • Ozone is widely used to sterilize food and tap water because ozone is a strong oxidizer. To date, it has been difficult to dissolve a high concentration of ozone gas in water because the large size of the bubbles limits the contact area between the ozone gas and liquid water. The measurements of dissolved ozone can be used to control water quality and ozone dosage. Therefore the dissolved ozone measurement of most interest is that of residual ozone at the discharge point of a particular treatment chamber.

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Tropospheric Ozone Retrieval Algorithm Based on the TOMS Scanning Geometry

  • Kim, Jae-Hwan;Na, Sun-Mi;Newchurch, M.J.
    • Korean Journal of Remote Sensing
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    • v.19 no.1
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    • pp.11-19
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    • 2003
  • This paper applies the Scan-Angle Method (SAM) to the Total Ozone Mapping Spectrometer (TOMS) aboard Earth Probe (EP) satellite for determining tropospheric ozone based on TOMS scan geometry. In the northern tropical Africa burning season, the distribution of the SAM-derived tropospheric ozone presents a tropospheric ozone enhancement related to biomass burning. This distribution is consistent with that of fire counts observed from Along Track Scanning Radiometer (ATSR) and that of carbon monoxide, the tropospheric ozone precursor, observed from Measurements of Pollution In The Troposphere (MOPITI). However, this feature is not shown in the distribution of tropospheric ozone derived from other TOMS-based algorithms for the northern burning season. In the high latitudes, the influence of pollution in the SAM results is seen over the northern continents in agreement with carbon monoxide for northern summer when the dynamical activity is weak in the northern hemisphere.

Tropospheric Ozone Patterns in the Metropolitan Seoul Area During 1990~1997 Using Two Ozone Indices of Accumulation over the Threshold Concentrations (한계농도 누적 오존지표로 본 1990~1997년의 수도권 오존농도 변화)

  • 윤성철;박은우;장영기
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.4
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    • pp.429-439
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    • 1999
  • In order to assess the chronic impact of tropospheric ozone on vegetation in the Seoul metropolitan area, it is necessary to quantify ozone exposure. Two ozone indices commonly used to relate ozone exposure to injury of vegetation were calculated. SUM06(SUM of hourly concentrations at or above 0.06 ppm) and AOT40(Accumulated exposure Over a Threshold of 40 ppb) which are widely used as ozone indices in the US and Europe were calculated based on hourly ozone concentrations in 5 areas of Seoul and 5 cities of Kyunggido during 1990~1997. Most SUM06 levels were 1~5ppm.hr, however several areas in Northern and Eastern Seoul reached about 5~7 ppm.hr in 1996~1997. AOT40 values were as high as 17~24 ppm.hr. Although measured SUM06 levels would not be expected to significantly impact vegetation, the overall ozone index, as well as annual average, 95th, and 99th percentile have increased continuously over the last 8 years. Often, ozone concentrations are lower in cities where there is a significant NOx concentration, than in outlying rural agricultural areas where NOx scrubbing is not as important. Concentrations greater than 40 ppb, which can cause chronic ozone toxicity to vegetation, were found mostly in the summer and constitutued about 5~15% of total hourly ozone cocentrations.

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A Comparative study on Ambient Air Quality Standard for Ozone (오존 대기 환경기준의 비교 연구)

  • 허정숙;김태오;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.2
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    • pp.159-173
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    • 1999
  • Based on air quality monitoring data('89~'97) operated by the Department of Environment, we provide various fundamental statistics for ground ozone. The purpose of this paper are to review the national ambient ozone standard, to study spatial distribution of ozone. Since we, in Korea, calculate average ozone level, to examine the occurrences of ozone level 3 times a day (1~8, 9~16, 17~24 hours), the method does not seem to be scientifically sound comparing to a running average method adapted by the USEPA. When we counted the number of cases with 8-h average O3 level exceeding 60ppb(8-h average standard in Korea)and 80 ppb (that in the U.S.A) and also when we calculated 8-hour average ozone level based on th US method, some regions were classified as non-attainment areas. Especially in Seoul, results of spatial distribution analysis showed that high level ozone over 80 ppb was observed at Kuui-Dong and Pangi-Dong in the eastern part and at Ssangmun-Dong in the northeastern part. Also, occurrences of ozone episode defined as number of days then ozone level exceeding 80 ppb for 3 consecutive hours were extensively reviewed in this paper.

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