• Asian Journal of Atmospheric Environment
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• 제9권4호
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• pp.237-246
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• 2015

We conducted intensive observations of ozone, CO, $NO_x$ (=NO and $NO_2$), $NO_y$ (total odd nitrogen species including particulate nitrate) and total nitrate (the sum of gaseous $HNO_3$ and particulate nitrate) at Cape Hedo, Okinawa, Japan, from 19 March to 3 April, 2009, to investigate ozone production during long-range transport from the Asian continent. Ozone production efficiency (OPE) was used to evaluate photochemical ozone production. OPE is defined as the number of molecules of ozone produced photochemically during the lifetime of a $NO_x$ molecule. OPE is calculated by the ratio of the concentration increase of ozone to that of $NO_z$ ($=NO_y-NO_x$). Average OPE during observation was estimated to be $12.6{\pm}0.5$, but concentrations of ozone increased nonlinearly with those of $NO_z$. This non-linearity suggests that OPE depends on air mass origin and $NO_z$ concentrations. There were very different values of OPE for the same air mass origin, so that only the air mass origin alone does not control OPE. OPE was low when $NO_z$ concentration was high. We examined the correlation between $NO_z$ and $CO/NO_y$ ratios, which we used instead of the ratio of non-methane hydrocarbons (NMHCs) to $NO_x$. The $CO/NO_y$ ratios decreased with increasing $NO_z$ concentrations. These results indicate that competition reactions of OH with NMHCs and $NO_2$ are the rate determining steps of photochemical ozone production during long-range transport from the Asian continent to Cape Hedo, for high concentrations of nitrogen oxides.

• 한국대기환경학회지
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• 제17권1호
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• pp.1-17
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• 2001

The high-ozone episode in the Greater Seoul Area for the period of July 27 to August 1 1997 was modeled by the CIT(California Institute of Technology) three-dimensional photochemical model. Emission data were prepared by scaling the NIER(1994) data through and optimization method using VOC measurements in August 1997 and EKMA(Empirical Kinetic Modeling Approach). Two sets of meteorological data were prepared by the diagnostic routine. a part of the CIT model : one only utilized observations from the surface weather stations and the other also utilized observations from the automatic weather stations that were more densely distributed than those from the surface weather stations. The results showed that utilizing observations from the automatic weather stations could represent fine variations in the sind field such as those caused by topography. A better wind field gave better peak ozones and a more reasonable spatial distribution of ozone concentrations. Nevertheless, there were still many differences between predictions and observations particularly for primary pollutant such as NOx and CO. This was probably due to the inaccuracy of emission data that could not resolve both temporal and spatial variations.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2001년도 Proceedings ICPE 01 2001 International Conference on Power Electronics
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• pp.89-92
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• 2001

Silent gas discharge method has been widely applied for ozone production, ultraviolet light and UV laser generation. Since ozone and ultraviolet applications have tendency to spread widely in industry, the development of efficient and low-cost power supply for such systems is a task of great impotency. This paper introduces high-frequency inverter type mode power supply designed for ozone generation tube and ultraviolet generation excimer lamp and considerations on this inverter and pulse density modulation control strategy applied in it.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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• pp.31-34
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• 2004

Feasibility of electrokinetic(EK)-Fenton process and Ozone chemical oxidation were investigated for tile removal of organic contaminants and heavy metals from the contaminated soil. In EK-Fenton process, accumulated electroosmotic flow(EOF) was 80 L for 26 days. Removal efficiency of TPH, As, and Ni were 61%, 36%, and 47%, respectively. The concentration of As was high near the anode due to the transport of anionic As toward the anode, while the concentration of Ni was high near the cathode by the movement of cationic Ni to the cathode. Field scale application of in-situ ozonation was carried out for removal of TPH in 3-D test cell (3 m$\times$2 m$\times$2 m). After 25 days of ozone injection, more than 80% of removal rate was observed through the test cell.

• 한국대기환경학회지
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• 제12권1호
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• pp.55-66
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• 1996

One-hour average concentrations of ground-level ozone from around 80 monitoring stations in Korea during 1991 to 1993 were analyzed to examine characteristics of the ozone concentration variations. Two types of variations were observed: one was for the Capital area typified by Kwanghwmun, and the other was for the south and east seashore region typified by Tongkwangyang. In the Capital area including Seoul, Inchon, Kyonggi-do and Chunchon, mean daily 1-hout maximum was the highest in June following high monthly averages in spring. But frequent precipitation prevented further rise of daily maximum in July and August even though there were frequent episodes of high concentration exceeding 100ppb. In the south and east seashore region, average concentration was the highest throughout the year, and daily maximum and minimum simultaneously changed owing to small contributions from photochemical reactions. The typical annual variation was spring peak, summer down, and fall rise. Spring peak accompanied an usual observations of background variations at remote sites in the Northern Hemisphere. Riess of average and daily maximum with lower daily minimum in fall were attributable to photochemical reactions.

• 한국안전학회지
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• 제15권2호
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• pp.92-96
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• 2000

In this experiment, we studied about concentration characteristics of $NO_x$ and generation of ozone in the reactor of corona discharge type by using mixed gas of $NO/N_2$ and $N_2/O_2$. In the case of the initial NO concentration increased, decrease rate of NO concentration was weakened and discharge input power of minimum NO concentration became high. When NO concentration was high, NO decomposition limit was appeared. And NO reduction rate was decreased, when initial NO concentration and discharge input power increased. When discharge input power was 5W, we could know the most proper energy value for treatment of NO. When the concentration of initial NO increased, generation of ozone decreased and in the case of same concentration of NO, according to discharge input power increase, generation of ozone increased.

• International Journal of Safety
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• 제9권1호
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• pp.35-42
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• 2010

We measured the concentrations of air pollutants at several residential sites, roadside sites and industrial sites in Iwate Prefecture, Japan. And the concentration distributions of air pollutants were estimated by atmospheric dispersion model using air emissions data. Based on those results, we calculated environmental risk of air pollutants emitted in Iwate Prefecture. As a result, it was found that the surround of factories with high emissions and highly toxic chemicals and the roadsides were high risk area, benzo(a)pyrene, formaldehyde and ozone exceeded the $10^{-5}$ risk level. Moreover, we tried to use "Loss of life expectancy: LLE" for an index to explain those risk to general public intelligibly. The total LLE of the carcinogenic chemicals was about 8.6 hours. Moreover, LLE of ozone was about 9.2 hours. Ozone has a big influence compared with the carcinogenic chemicals.

• Journal of Power Electronics
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• 제2권3호
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• pp.206-211
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• 2002

Silent gas discharge method has been widely applied fur ozone production, ultraviolet light and UV laser generation. Since ozone and ultraviolet applications have tendency to spread widely in industry, the development of efficient and low - cost power supply for such systems is an important task at present. This paper introduces high-frequency inverter type mode power supply designed fur ozone generation tube and ultraviolet generation excimer lamp and considerations on the design of the inverter and pulse density modulation control strategy applied in it.

• 한국환경과학회지
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• 제6권4호
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• pp.335-350
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• 1997

Numerical simulations of photochemical air pollution (CBM: Carbon-Bond Mechanisms under a theoretical three-dimensional local wind system are carried to clarify the fundamental characteristics of the effects of local wind on photochemical air pollution. According to the AWS data of Pusan coastal area and KMA, the surface wind of Pusan during summertime showed a very remarkable land and sea breeze circulation. The ozone concentration distribution using local wind model showed that high ozone concentration zone near coastal area moved toward inland In the afternoon. This change implies a sea breeze Increases the ozone concentration, but a land breeze decreases it in Pusan coastal area.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 추계학술대회 논문집 학회본부 C
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• pp.906-908
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• 1999

The application of ozone solid polymer electrolyte or Membrel water electrolysis cells with $PbO_2$ anodes for anodic generation of ozone in electrolyte-free water is reported. Maximum yields were obtained at a temperature of $25^{\circ}C-30^{\circ}C$ and current density of about 1A/$cm^2$. The current efficiency was not found to depend on ozone concentration in the feed water. exclusive transference of electric current by protons absence of convection in the electrolyte and high oxygen oversaturatation in the vicinity of electrode