• 한국환경과학회지
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• 제10권6호
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• pp.437-444
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• 2001

The characteristic features of surface ozone concentration and the forecasting procedure of high ozone days have been studied. The ozone concentration was continuously measured during 3 years (1997~1999) at air quality monitoring stations in five major cities in Korea. The diurnal variation of surface ozone concentration on high ozone days is characterized by low ozone concentration at night. The ozone concentration Increases continuously after sunrise, In reach a peak at 1500~1600 LST. Thereafter it decreases steadily to a low concentration at sunset. The diurnal and annual maximum of the surface ozone concentration at Seoul were observed in May and June, respectively. The favorable synoptic condition for the high ozone day is divided into 4 different synoptic weather patterns: a high-pressure system from the Sea of Okhotsk, the Pacific subtropical high extending westward, a moving high-pressure system covering the Korean peninsula. and a synoptic system In front of a typhoon. Most of high ozone days occur under the high pressure system in Korea.

• 한국대기환경학회지
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• 제15권6호
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• pp.747-755
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• 1999

Effects of precipitation and cloud cover on high ozone days are examined by investigating the precipitation and average cloud cover before the ozone peak time within a day. High ozone days above 100 ppb in the Greater Seoul Area(GSA) for the ozone season from May to September are chosen for the analyses in terms of the surface meteorological data during 1990~1997. The result shows that the effect of precipitation on the rise of ozone concentration is definitely negative so that ozone concentration could not rise above 100ppb immediately after precipitation. But, the effect of cloud cover is associated with the variations of other meteorological parameters. The number of high ozone days with "zero" cloud cover is rather less than that with cloud cover of 1 to 4 since temperature is usually lower in "zero" cloud cover days. Furthermore, ozone concentration can rise above 100ppb even with full cloud cover when the wind is weak and the temperature is high.temperature is high.

• 한국환경과학회지
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• 제9권4호
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• pp.295-302
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• 2000

This study was conducted to investigate the characteristics of surface ozone concentration and occurrence of high ozone concentration using hourly ozone, nitrogen dioxide and meteorological data for 1997~1998 in Pusan coastal area. Monthly mean ozone concentration was the highest at Dongsamdong in Spring(35.4ppb), at Kwangbokdong in Fall(25.1ppb) and the lowest Dongsamdong(22.2ppb) and Kwangbokdong(16.0ppb) in Winter. Relative standard deviation indicating clearness of observation site was 0.42 at Dongsamdong and 0.49 at Kwangbokdong that is similar to urban area. The diurnal variation of ozone concentration of Dongsamdong and Kwangbokdong showed maximum at 1500~1600LST and minimum 0700~0800LST that typical pattern of ozone concentration. In ozone episode period(Sept. 10~15, 1998), diurnal change of ozone concentration was very high, and ozone concentration was related to meteorological parameters such as temperature, relative humidity, wind speed, cloud amount and radiation on a horizontal surface. During the episode days peak ozone concentrations are much higher than the normal values, wind speeds are always lower, and solar radiation is high with the exception of the September episode.

• 한국환경과학회지
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• 제8권3호
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• pp.287-292
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• 1999

This study was performed to investigate the characteristics of nocturnal maxiumu ozone occurrence and the meteorological relevance using to hourly ozone data and meteorological data for 1995~1996 in Pusan coastal area. Kwangbokdong showed the highest occurrence of nocturnal maximum ozone as 36.9%, and Deokcheondong showed the lowest occurrence(9.2%) for research period in Pusan. The occurrence rates of nocturnal maximum ozone concentration were decreased toward land area. The low maximum temperature, high minimum temperature, low diurnal range, high relative humidity, high wind speed, high could amount, low sunshine and low radiation were closely related to the main meteorological characteristics occuring the nocturnal maximum concnetration of ozone. It was shown that normal daily variation of ozone concentration by strong photochemical reaction at the before day of nocturnal maximum ozone. The concnetration of nocturnal maximum ozone were occured by entrainment of ozone from the upper layer of developed mixing layer. There are no ozone sources near the ground at night, so that the nighttime ozone should be entrained from the upper layer by forced convection.

• KIEAE Journal
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• 제12권6호
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• pp.93-98
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• 2012

The concerns on high ozone concentration phenomenon is significantly growing in Seoul metropolitan area including the industry complex area, like Shiwha Banwol area. The aims of this research is the analysis of relationship between high concentrations of $O_3$ and solar radiation parameters in atmosphere. The understanding of the effects of solar radiation intensity, humidity, high air temperature on ozone concentration in a day is very useful to provide a direction for reducing of the high ozone concentration to a local government or a metropolitan government. The correlation analysis between maximum ozone concentration and various meteorological parameters in 2009 - 2011 carried out using IBM's SPSS program. The results showed that the mean correlations coefficient (R) between daily Ozone maximum and solar radiation resulted R = 0.64 during 2011. May - September in 10 air pollution stations. In case of correlations between daily ozone maximum and relative humidity showed negative correlation R = -0.61. The correlation analysis with mean air temperature during 1-3 PM resulted R = 0.29. This low correlation coefficient could be corrected by using of categorized data of ozone concentration. The daily maximum ozone concentration is more dependent on peak solar radiation and high air temperature during 1-3 PM than its simple daily maximum values. The results of this research would be used to develop the high ozone alert system around Seoul metropolitan area. This correlation analysis could be partially integrated to prediction of ozone peak concentration in connection with other methods like classification and regression tree(CART).

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2003년도 ICCAS
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• pp.49-52
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• 2003

Two types of ozone monitors using UV absorption method were tried in consideration of cost of the monitor and precision in measuring. The high concentration ozone monitor for high concentration real time ozone monitoring from ozone generator was composed of a low pressure mercury lamp as UV source, a photo multiplier tube as UV detector and signal processing unit for the most part. This structure could be very useful for low price high concentration ozone monitor due to simple system structure and fairly good monitoring characteristics. The developed system showed good linear output characteristics to ozone in the measuring concentration range of 0.05 and 2 wt.%. For accuracy ambient ozone monitoring in ambient in ppm level, the system composed of a high power pulsed xenon lamp as UV source, an optical spectrometer with a high sensitivity linear CCD array as UV detector and signal processing unit in brief speaking was proposed our study for the first time in the world. The developed system showed good linearity and sensitivity in relative low measuring range between 10ppm and 10,000ppm, and showed some feasibility of high resolution ozone monitor using CCD array as photodetector.

• 한국대기환경학회지
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• 제15권3호
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• pp.267-280
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• 1999

To investigate the characteristics of high-ozone occurrences in the Greater Seoul Area(GSA), three high-ozone episodes were selected, for which the ozone warning for concentration above 120 ppb might be issued. The selection was on the basis of morning wind directions and speeds, and daily maximum ozone concentrations measured between 1990 and 1997. The episodes chosen to meet selection criteria were seven days in July 1992, nine days in July 1994, and three days in August 1994, as respectively characterized by southwesterly, easterly, and calm winds in the morning. However, more than 80% of high-ozone days in the GSA were associated with calm winds and the concomitant accumulation of local emission in the morning, rather than being due to transport of ozone or its precursors. This is believed to be the primary reason why ozone concentrations in the GSA varied in a completely different manner even between adjacent monitoring stations. Several premises for initiating research studies for resolving these local variations of ozone concentrations in the GSA are also discussed.

• 한국환경과학회지
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• 제11권12호
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• pp.1253-1259
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• 2002

This study analyzes the surface ozone, NO and $NO_2$ concentration data from 1997 to 1999 in Daegu. It investigates effect on precursor during high-ozone episode days. The high-ozone episode is defined when a daily maximum ozone concentration is higher than 100 ppb(ambient air quality standard of Korea) in at least one station among six air quality monitoring stations. The frequency of episodes is 13 days(33 hours). The frequency is the highest in May and September, and the area with the highest frequency is Nowondong and Manchondong. The average value of daily maximum ozone concentration with high ozone episode is 81.6 ppb, and that of 8-hour average ozone concentration is 58.6 ppb. It means that ozone pollution is continuous and wide-ranging in Daegu. The daily variation of NO, $NO_2$ and $O_3$ in high-ozone episodes are inversely proportional one another. Nowondong an industrial area, is affected by pollutants that are emitted from the primary sources, while Manchondong a residential area, is affected by the advection of $O_3$ or by the primary pollutants like VOCs.

• 한국환경보건학회지
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• 제41권2호
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• pp.71-81
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• 2015

Objectives: Photochemical ozone pollution is associated with increased mortality risk. This study aims to assess the population exposure to ozone according to population characteristics for high ozone days in the Busan metropolitan region (BMR). Methods: The ozone exposure assessment in this study was performed using the WRF-CMAQ simulated ozone concentrations and the population data in the BMR. The settled and daytime population and their activity were considered to conduct the static and dynamic ozone exposure assessment. Results: Applying a static exposure assessment, in case that high ozone occurred throughout Busan area, the highest exposure levels were evaluated in urban neighborhoods. In case of ozone pollution in outer Busan, because sensitive groups have been relatively higher exposure, this case was also evaluated as part of that should not be overlooked. The dynamic exposure was higher than static exposure because the number of population exposed to ozone of high concentration is increased. This approach is important in a regard consider that daytime population distribution when high ozone occur. Conclusion: This study shows the different population exposure according to various ozone distributions for each episode day. Considering demographic characteristic such as population density and activity should be important to understanding the population exposure assessment when ozone pollution occurs.

• 한국대기환경학회지
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• 제20권3호
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• pp.345-360
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• 2004

The late sea-breeze and its impacts on ozone distributions were investigated during April to September from 1998 to 2002, in the Busan metropolitan area (including surrounding areas) using the surface ozone concentrations (obtained at 9 monitoring sites), local meteorological variables (obtained near the shore), together with synoptic data. The urban scale ozone concentration was also simulated using the MM5/UAM-V to better understand the role of late sea-breeze in Busan. The results from observation study showed that most of the late sea-breeze occurred when weak offshore synoptic flow (northwesterly) suppressed development of sea - breeze, and the ozone concentration level and frequencies exceeding ozone standard increased with the onset time of sea breeze. We also found that the late sea-breeze clearly induces relatively weak wind speed and high temperature during the daytime As a result it enhances the photochemical ozone accumulation and delays the occurrence time of the averaged maximum ozone concentrations. The results of simulation for high ozone episode (24 August, 2001) by MM5/UAM -V revealed that the late sea-breeze interacted with weak offshore synoptic wind can contribute significantly to high ozone concentration in the coastal urban area. The simulated horizontal and vertical distribution of ozone concentration indicated that ozone can be accumulated over the sea under stagnant condition and return to the land in the late afternoon with the sea breeze, suggesting both the relationship between late sea-breeze and recirculation and the importance of late sea -breeze effects influencing severe ozone pollution in Busan.