• 한국수소및신에너지학회논문집
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• 제13권3호
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• pp.242-248
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• 2002

SnCo alloy powder prepared by high energy ball milling is examined as an anode material for lithium-ion batteries. As the ball-milling time increased, the crystallinity of SnCo decreased. XRD and TEM SADP showed that nanocrystalline and amorphous phase coexisted after 16 h ball-milling. As the crystallinity decreased, the cycleability increased. At first cycle, there are 4 plateau potentials. The observation of voltage plateau at about 0.68 V confirms the formation of Sn-Li alloy and Co metal. It is considered that The plateau potentials below 0.68 V were reaction between Li and Sn. The change of chemical diffusion coefficient showed that the structure of SnCo alloy abruptly changed at first cycle, and maintained after 2nd cycle.

• 한국분말재료학회지
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• 제23권4호
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• pp.276-281
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• 2016

Carbonyl iron (CI) is successfully incorporated as an additive into a polystyrene (PS) matrix via a highenergy ball milling method, under an n-hexane medium with volume fractions between 1% and 5% for electromagnetic interference shielding applications by the combination of magnetic CI and an insulating PS matrix. The morphology and the dispersion of CI are investigated by field emission scanning electron microscopy, which indicates a uniform distribution of CI in the PS matrix after 2 h of milling. The thermal behavior results indicate no significant degradation of the PS when there is a slight increase in the onset temperature with the addition of CI powder, when compared to the as-received PS pellet. After milling, there are no interactions between the CI and the PS matrix, as confirmed by Fourier transformed infrared spectroscopy. In this study, the milled CI-PS powder is extruded to make filaments, and can have potential applications in the 3-D printing industry.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.491-492
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• 2006

The horizontal high energy rotor ball mill ($Simoloyer^{(R)}$) is used to break and activate dry solids. It is used for dry-milling and in the vertical mount for wet-milling in leaching processes. Technical electric arc furnace (EAF) dust with high contents of zinc oxide, zinc ferrite and magnetite is efficiently separated by ambient temperature leaching. The process shows promise for industrial application

• 한국분말재료학회지
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• 제24권5호
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• pp.406-413
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• 2017

A Nanosized $WO_3$ and CuO powder mixture is prepared using novel high-energy ball milling in a bead mill to obtain a W-Cu nanocomposite powder, and the effect of milling time on the structural characteristics of $WO_3-CuO$ powder mixtures is investigated. The results show that the ball-milled $WO_3-CuO$ powder mixture reaches at steady state after 10 h milling, characterized by the uniform and narrow particle size distribution with primary crystalline sizes below 50 nm, a specific surface area of $37m^2/g$, and powder mean particle size ($D_{50}$) of $0.57{\mu}m$. The $WO_3-CuO$ powder mixtures milled for 10 h are heat-treated at different temperatures in $H_2$ atmosphere to produce W-Cu powder. The XRD results shows that both the $WO_3$ and CuO phases can be reduced to W and Cu phases at temperatures over $700^{\circ}C$. The reduced W-Cu nanocomposite powder exhibits excellent sinterability, and the ultrafine W-Cu composite can be obtained by the Cu liquid phase sintering process.

• 한국분말재료학회지
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• 제20권2호
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• pp.107-113
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• 2013

In this study, the microstructure and valuable metals dissolution properties of PDP waste panel powders were investigated as a function of milling parameters such as ball diameter size, milling time, and rotational speed during high-energy milling process. The complete refinement of powder could achieved at the ball diameter size of 5 mm due to sufficient impact energy and the number of collisions. With increasing milling time, the average particle size was rapidly decreased until the first 30 seconds, then decreased gradually about $3{\mu}m$ at 3 minutes and finally, increased with presence of agglomerated particles of $35{\mu}m$ at 5 minutes. Although there was no significant difference on the size of the particle according to the rotational speed from 900 to 1,100 rpm, the total valuable metals dissolution amount was most excellent at 1,100 rpm. As a result, the best milling conditions for maximum dissolving amount of valuable metals (Mg: 375 ppm, Ag 135 ppm, In: 17 ppm) in this research were achieved with 5 mm of ball diameter size, 3min of milling time, and 1,100 rpm of rotational speed.

• 한국분말재료학회지
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• 제17권5호
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• pp.404-408
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• 2010

The effects of high energy ball-milling (HEBM) on the sintering behavior and piezoelectric properties of 0.1 wt% $Li_2CO_3$ doped 0.8Pb($Mg_{1/3}Nb_{2/3}$)$O_3$-0.2Pb($Zr_{0.475}Ti_{0.525}$)$O_3$ (PMN-PZT) ceramics were investigated. It was found that HEBM treatment was quite effective to reduce the average particle size down to 300 nm, leading to increased density as well as enhanced piezoelectric properties of a sintered specimen even though prolonged HEBM resulted in unwanted secondary phases that caused a degradation of piezoelectric properties. The dielectric constant ($\varepsilon_r$), piezoelectric coupling factor ($k_p$) and piezoelectric constant $d_{33}$ of 0.1 wt% $Li_2CO_3$ doped PMN-PZT ceramics prepared via HEBM for 10 h reached 2040, 0.68 and 554 pC/N, respectively.

• 한국분말재료학회지
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• 제12권5호
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• pp.362-368
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• 2005

The structural and magnetic properties of nanostructued Fe-20 ;wt.%Si alloy powders were investigated. Commercial Fe-20 wt.%Si alloy powders (Hoeganaes Co., USA) with 99.9% purities were used to fabricate the nanostructure Fe-Si alloy powders through a high-energy ball milling process. The alloy powders were fabricated at 400 rpm for 50 h, resulting in an average grain size of 16 nm. The nanostructured powder was characterized by fcc $Fe_{3}Si$ and hcp $Fe_{5}Si_3$ phases and exhibited a minimum coercivity of approximately 50 Oe.

• 한국수소및신에너지학회논문집
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• 제10권1호
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• pp.49-57
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• 1999

In order to study the effect of high energy ball milling on the $Mg_2Ni+Ni$, $Mg_2Ni+0.5Ni+0.5Al$ powders, we have investigated on the discharge properties, microstructures. The powder size of samples decreased as ball milling time. From the XRD results, the crystal structure of $Mg_2Ni+Ni$ mixed powders were changed to amorphous or nano-structure after 60hr ball milling. The discharge capacities of both $Mg_2Ni+Ni$ and $Mg_2Ni+0.5Ni+0.5Al$ powders increased, with increasing ballmilling time, the maximum capacity(342mAh/g) was shown for the 60 hrs ballmilled $Mg_2Ni+Ni$ sample. The capacity decreased drastically after a few charge-discharge cycles.

• 한국수소및신에너지학회논문집
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• 제8권1호
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• pp.43-47
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• 1997

A new type of anode materials in form of nanocrystalline composite powders has been developed that offers the potential for dramatically improved discharge capacity and initial activation rate. The composites are synthesized by ball milling of two components - a major component (basic component) having high hydrogen capacity and a minor component (surface activator) with good electrocatalytic activity. The capacity increase observed by ball milling with surface activator. The ball-milled composite materials are easier to activate than the non ball-milled basic component.

• 한국분말재료학회지
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• 제19권3호
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• pp.226-231
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• 2012

In this research, the coating behavior of Mg and Fe desulfurization powder fabricated by low energy and conventional planetary mill equipment was investigated as a function of milling time, which produces uniform Fe coated powders due to milling energy. Since high energy ball milling results in breaking the Fe coated Mg powders into coarse particles, low energy ball milling was considered appropriate for this study, and can be implemented in desulfurization industry widely. XRD and FE-SEM analyses were carried out to investigate the microstructure and distribution of the coating material. The thickness of the Fe coating layer reaches a maximum of 14 ${\mu}m$ at 20 milling hours. The BCC structures of Fe particles are deformed due to the slip system of Fe coated Mg particles.