Journal of Hydrogen and New Energy (한국수소및신에너지학회논문집)

The Korean Hydrogen and New Energy Society (한국수소및신에너지학회)
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Electrochemical Properties of SnCo for Anode Material of Li Ion Batteries

리튬 이온 전지 음극 재료용 SnCo의 전기화학적 특성

  • Kim, Ki-Tae (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology) ;
  • Kim, Yong-Mook (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology) ;
  • Lee, Yong-Ju (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology) ;
  • Lee, Ki-Young (Batteriy Research Center, LG Chemical Ltd.) ;
  • Lee, Jai-Young (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology)
  • 김기태 (한국과학기술원 재료공학과) ;
  • 강용묵 (한국과학기술원 재료공학과) ;
  • 이용주 (한국과학기술원 재료공학과) ;
  • 이기영 (LG 화학 배터리 연구센터) ;
  • 이재영 (한국과학기술원 재료공학과)
  • Published : 2002.09.15
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Abstract

SnCo alloy powder prepared by high energy ball milling is examined as an anode material for lithium-ion batteries. As the ball-milling time increased, the crystallinity of SnCo decreased. XRD and TEM SADP showed that nanocrystalline and amorphous phase coexisted after 16 h ball-milling. As the crystallinity decreased, the cycleability increased. At first cycle, there are 4 plateau potentials. The observation of voltage plateau at about 0.68 V confirms the formation of Sn-Li alloy and Co metal. It is considered that The plateau potentials below 0.68 V were reaction between Li and Sn. The change of chemical diffusion coefficient showed that the structure of SnCo alloy abruptly changed at first cycle, and maintained after 2nd cycle.

Keywords

References

  1. W. S. Harris, Electrochemical studies in cylic esters, thesis No. UCRL-8381, University of California, 1958
  2. M. Winter, J. O. Besenhard. J. H. Albering, J. Yang, M. Wachtler, Progress in Batteries and Battery Materials 17. 1998, pp. 208
  3. J. O. Besenhard, M. Winter, J. Yang, M. Wachtler, R. Andreaus, W. Sitte, I. Rom, 49th Annual Meeting of ISE, Kitakyushu, September 13-18, 1998
  4. J. Yang, M. Wachtler, P. Warbichler, M. Winter, J. O. Besenhard, Meeting "Batteries" of the Division of Applied Electrochemistry der Gesellschaft Deutscher Chemiker (GDCh), Poster S. 98, Vienna, September 24-26, 1997 (in Gennan)
  5. D. K. Kim, H. Kim, K. -J. Sohn, and T. Kang : "Nanosized Sn-Cu-B alloy anode prepared by chemical reduction for secondary lithium batteries" Joumal of Power Sources, Vol. 104, 2002, P 221 https://doi.org/10.1016/S0378-7753(01)00918-1
  6. L. Fang, and B. V. R. Chowdari : "Sn-Ca amorphous alloy as anode for lithium ion battery", Journal of Power Sources, Vol. 97-98, 2002, p 181