• Title/Summary/Keyword: High Polymer

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Capillary-driven Rigiflex Lithography for Fabricating High Aspect-Ratio Polymer Nanostructures (모세관 리소그라피를 이용한 고종횡비 나노구조 형성법)

  • Jeong, Hoon-Eui;Lee, Sung-Hoon;Kim, Pil-Nam;Suh, Kahp-Y.
    • Journal of the Korean Society of Visualization
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    • v.5 no.1
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    • pp.3-8
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    • 2007
  • We present simple methods for fabricating high aspect-ratio polymer nanostructures on a solid substrate by rigiflex lithography with tailored capillarity and adhesive force. In the first method, a thin, thermoplastic polymer film was prepared by spin coating on a substrate and the temperature was raised above the polymer's glass transition temperature ($T_g$) while in conformal contact with a poly(urethane acrylate) (PUA) mold having nano-cavities. Consequently, capillarity forces the polymer film to rise into the void space of the mold, resulting in nanostructures with an aspect ratio of ${\sim}4$. In the second method, very high aspect-ratio (>20) nanohairs were fabricated by elongating the pre-formed nanostructures upon removal of the mold with the aid of tailored capillarity and adhesive force at the mold/polymer interface. Finally, these two methods were further used to fabricate micro/nano hierarchical structures by sequential application of the molding process for mimicking nature's functional surfaces such as a lotus leaf and gecko foot hairs.

Shear Behavior of Polymer Cement High Strength Concrete Beams Mixed with Steel Fiber (강섬유 혼입 폴리머 시멘트 고강도 콘크리트 보의 전단거동)

  • 곽계환;박종건;곽경헌
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.44 no.1
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    • pp.93-102
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    • 2002
  • Steel fiber and polymer are used widely for reinforcement material of RC structures because of its excellences of the durability, serviceability as well as mechanical properties. The purpose of this study is to investigate the shear behavior of polymer cement high strength concrete beams mixed with steel fiber. The compressive strength of concrete was based on the 100$\times$200 mm cylinder specimens. The compressive strength of concrete are 320$kgf/cm^2$, 436 $kgf/cm^2$ and 520 $kgf/cm^2$ in the 28 days. The static test was carried out to measure the ultimate load, the initial load of flexural and diagonal cracking, crack patterns and fracture modes. Also, load-strain and load-deflection examined. During the test cracks were sketched against the load values according to the growth of crack. result are as follows; (1) The failure modes of the specimens are increased in rigidity and durability with mixing steel fiber and polymer. (2) The load of initial crack was similar a theory of shear-crack strength. (3) The deflection and strain at failure load of Polymer-steel fiber high strength concrete beams were increased, improving the brittleness of the high strength concrete.

The Study on Drag Reduction Rates and Degradation Effects in Synthetic Polymer Solution with Surfactant Additives (계면활성제를 이용한 합성고분자 수용액의 마찰저항감소 및 퇴화 특성 향상 연구)

  • 이동민;김남진;윤석만;김종보
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.3
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    • pp.194-199
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    • 2001
  • The turbulent flow resistance of water solution with polymer is reduced as compared with that of pure water. This effects is named th drag reduction and offers the significant reduction of the pumping power and the energy consumption. But the intense shear forces and the high temperature experienced by the polymer solution when passing through the pipes cause the degradation a loss of drag reduction effectiveness. Especially, the degradation behavior is found to be strongly dependent on temperature. This mechanical and thermal degradation can be avoided by adding materials such as surfactant to the polymer solution, which enhance the bonding force between molecules. In the present study, Copolymer and SDS were utilized and they were mixed in 10 different mixture ratios, while total concentration was fixed as 100wppm. Degradation of Copolymer-SDS mixture solutions was investigated experimentally in closed loop at the temperature of $10^{\circ}C\; and\; 80^{\circ}C$ with various flow average velocities of 1.5 m/sec, 3.0m/sec, and 4.5m/sec. Degradation characteristics of polymer solution without surfactant show a radical loss of drag reduction effectiveness at high temperature. Degradation alleviation ability of surfactant is especially effective at high temperature. Consequently, this results show that the addition of surfactant to the polymer solution can control unfavorable degradation phenomena for high temperature systems.

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The Effect of sGO Content in sPEEK/sGO Composite Membrane for Unitized Regenerative Fuel Cell (일체형 재생연료전지 적용을 위한 sGO 함량 변화에 따른 sGO/sPEEK 복합막의 특성 평가)

  • Jung, Ho-Young;Kim, Min-Woo;Lim, Ji-Hun;Choi, Jin H.;Roh, Sung-Hee
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.1
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    • pp.127-131
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    • 2016
  • Polymer electrolyte membrane for unitized regenerative fuel cells requires high proton conductivity, high dimensional stability, low permeability, and low cost. However, DuPont's Nafion which is a commercial polymer electrolyte membrane has high permeability, high cost, and decreasing proton conductivity and dimensional stability over $80^{\circ}C$. To address these problems, sulfonated poly ether ether ketone (sPEEK) which is a low cost hydrocarbon polymer is selected as matrix polymer for the preparation of polymer electrolyte membrane. In addition, composite membrane with improved proton conductivity and dimensional stability is prepared by introducing sulfonated graphene oxide (sGO). The fundamental properties of polymer electrolyte membranes are analyzed by investigating membrane's water content, dimensional stability, proton conductivity, and morphology. The cell test is conducted to consider the possibility of application of sPEEK/sGO composite membrane for an unitized regenerative fuel cell.

Contamination Characteristics of Polymer Insulator using High Frequency Current Transformer (HF-CT센서를 이용한 고분자애자의 오손특성)

  • Park, Jae-June
    • The Journal of Information Technology
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    • v.8 no.4
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    • pp.1-7
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    • 2005
  • Investigations of high frequency current transformer(HF-CT) waveform characteristics of the surface leakage on kaolin polluted EPDM polymer insulators have been performed. This work is part of a program aimed at examining the potential for HF-CT waveform characteristics analysis to provide information about the environment contaminants and environment condition of polymer insulators. The investigation reported examined the HF-CT waveform characteristics at high frequencies. The use of high frequency measurements for on-line applications reduces electrical inference. This work was peformed utilizing HF-CT to monitor of surface polluted discharge. It was found that HF-CT waveform frequency spectrum, magnitude depend on importantly the duration of the surface discharge activity.

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High Temperature Properties of Cement Mortar Using EVA, EVCL Redispersible Polymer Powder and Fly Ash (EVA, EVCL 분말수지와 플라이애시를 혼입한 시멘트 모르타르의 고온특성)

  • Song, Hun;Shin, Hyeonuk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.365-372
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    • 2018
  • 3D printing technology of construction field can be divided into structural materials, interior and exterior finishing materials, and is mainly done by extruding and adapting. Particularly when it is applied as an exterior materials, it is mainly applied to an unstructured exterior materials and high accuracy is required. The exterior materials can be used as a cement composite materials, it is suitable also for a additive type manufacturing, and the role of a redispersible polymer powder is important. But, high temperatures, redispersible polymer cement base material beget dehydration and micro crack of cement matrix. In this research, we developed a EVA, EVCL redispersible polymer cement base material applicable as a 3D printing exterior materials, confirmed density and strength characteristics for application as an exterior materials, a flame retardancy test for improving the fire resistance of buildings and confirmed its possibility. From the test result, developed EVCL redispersible polymer cement mortar showed good stability in high temperatures. These high temperature stability is caused by the ethylene-vinyl chloride binding. Thus, this result indicates that it is possible to fire resistant 3D printing interior and exterior finishing materials.

Drying Shrinkage and Strength Properties of High-Fluidity Polymer-Modified Mortar (고유동 폴리머시멘트모르타르의 건조수축 및 강도 특성)

  • Joo Myung-Ki;Lee Youn-Su;Jung In-Su
    • Journal of the Korea Concrete Institute
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    • v.16 no.5 s.83
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    • pp.651-657
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    • 2004
  • The effects of polymer-cement ratio, antifoamer content and shrinkage-reducing agent content on the air content, setting time, drying shrinkage and strength of high-fluidity polymer-modified mortars using redispersible polymer powder are examined. As a result, the air content of the polymer-modified mortars using redispersible polymer powder tends to decrease nth increasing polymer-cement ratio and antifoamer content. Regardless of the antifoamer content, the setting time of the polymer-modified mortars using redispersible polymer powder tends to delayed with increasing polymer-cement ratio. Irrespective of the antifoamer content, the drying shrinkage of the polymer-modified mortars using redispersible polymer powder tend to decrease with increasing polymer-cement ratio and shrinkage-reducing agent content. Regardless of the antifoamer content, the flexural and tensile strengths of the polymer-modified mortars using redispersible polymer powder tends to increase with increasing polymer-cement ratio, and tend to decrease with increasing shrinkage-reducing agent content. However, the compressive strength of the polymer-modified mortars using redispersible polymer powder decreases with increasing polymer-cement ratio and shrinkage-reducing agent content.

Linear and network structures of polymer electrolyte based on phosphate and polyether copolymers

  • Kim, Jun-Young;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.232-235
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    • 1998
  • ion conducting polymers have been extensively investigated because of their potential application as an electrolyte in solid state batteries [1]. Among the polymer electrolytes, solid polymer electrolytes (SPEs) composed of ion conducting polymer and alkali metal salt have many advantages such as high ionic conductivity, high energy density and light weight. This made them suitable replacement for liquid electrolytes. (omitted)

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The Design and Aging Test of Polymer Insulator for Power Transmission and Distribution (송배전용 고분자 애자의 설계와 열화시험)

  • Lee, Un-Yong;Cho, Han-Gu;Lim, Kee-Joe
    • Proceedings of the KIEE Conference
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    • 2000.11c
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    • pp.553-555
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    • 2000
  • Recently polymer insulators are being used for outdoor high voltage applications. Polymer insulators for transmission line have significant advantages over porcelain and glass insulators, especially for ultra-high voltage(UHV) transmission lines. In this paper, the design trend and method polymer insulator are investigated and Aging test method is analysed to know life time of insulator.

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The Design Analysis of Distribution Polymer Suspension Insulator (배전용 폴리머 현수애자의 설계해석)

  • Lee, Un-Yong;Cho, Han-Goo;Han, Dong-Hee;Lim, Kee-Jo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.66-68
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    • 2001
  • Recently polymer insulators are being used for outdoor high voltage applications. Polymer insulators for transmission and distribution line have significant advantages over porcelain and glass insulators, especially for ultra-high voltage(UHV) transmission lines. Their advantages are light weight, vandalism resistance and hydrophobicity. In this paper, distribution polymer suspension insulator has been designed and investigated electric field distribution by FEM.

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