• Title/Summary/Keyword: High Polymer

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Transmission Mode of HPDLC Based on Rubbery Polymers

  • Kim, Eun-Hee;Woo, Ju-Yeon;Kim, Byung-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.520-523
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    • 2003
  • We used three types of reactive diluents with different chemical structures, N-vinyl-pyrrollidone(NVP), ethyl hexyl acrylate(EHA) and hydroxyehtyl methacrylate(HEMA). It was founded that N-vinylpyrrollidone(NVP) and ethyl hexyl acrylate(EHA) based PUA with low molecular weight polypropylene glycol(PPG) at low oligomer content give high diffraction efficiency. The morphology of the resultant gratings was analyzed by using scanning electron microscopy(SEM) and Tg of the polymer matrix by dynamic mechanical thermal analysis(DMTA).

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Measurement of Gas Solubility and Mechanical Property for Bumper Polymer (범퍼용 수지의 gas용해도 및 물성 측정)

  • 이정주;차성운;이경수
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1366-1369
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    • 2003
  • Today, the industries use polymer material for many purpose. Specially, it is important in automobile industry because tile costs of polymer hold high proportion of the overall cost. If we reduce the weight of automobile, fuel efficiency of car is raised and cost of bumper is lower. Therefore there are many efforts to reduce of car currently. The purpose of this paper is to reduce polymer used in car bumper.

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An Improved Procedure for 2-amino-5-nitro-4,6-diarylcyclohex-1-ene-1,3,3-tricar Bonitriles; Carbonate on Polymer Support as Mild and Reusable Catalyst

  • Prasanna, T.S.R.;Raju, K. Mohana
    • Journal of the Korean Chemical Society
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    • v.55 no.5
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    • pp.808-811
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    • 2011
  • A new catalytic system has been developed in the synthesis of 2-amino-5-nitro-4,6-diarylcyclohex-1-ene-1,3,3-tricarbonitriles using carbonate on polymer support (Amberlyst A-26 $NaCO_3{^-}$). Short reaction time, simplicity of isolation, safe catalyst and high yields of product are the features.

Effect of associating polymer on the dispersion stability and rheology of suspensions

  • Otsubo, Yasufumi;Horigome, Misao
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.27-33
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    • 2003
  • Associating polymers are hydrophilic long-chain molecules to which a small amount of hydrophobic groups (hydrophobes) is incorporated. In aqueous solution, the association interactions result in the formation of three-dimensional network through flowerlike micelles at high concentrations. In colloidal suspensions, the associating polymers act as flocculated by bridging mechanism. The rheological properties of suspensions flocculated by associating polymers end-capped with hydrophobes are studied in relation to the bridging conformation. At low polymer concentrations, the polymer chains effectively form bridges between particles by multichain association. The suspensions are highly flocculated and show typical viscoelastic responses. When the polymer concentration is increased above the absorbance at saturation, the excess polymer chains remaining in the solution phase build up three-dimensional network by associating interactions. Since the presence of particles does not significantly influence the network structures in the medium, the relative viscosity, which gives a measure of the degree of flocculation is decreased with increasing polymer concentration. The bridging conformation and flocculation level vary strongly depending on the polymer concentrations.

A review of the preparation and properties of carbon nanotubes-reinforced polymer compositess

  • Jin, Fan-Long;Park, Soo-Jin
    • Carbon letters
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    • v.12 no.2
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    • pp.57-69
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    • 2011
  • Carbon nanotubes (CNTs) have high Young's modulus, low density, and excellent electrical and thermal properties, which make them ideal fillers for polymer composites. Homogeneous dispersion of CNTs in a polymer matrix plays a crucial role in the preparation of polymer composites based on interfacial interactions between CNTs and the polymer matrix. The addition of a small amount of CNTs strongly improves the electrical, thermal, and mechanical properties of the composites. This paper aims to review the processing technology and improvement of properties of CNT-reinforced polymer composites.

Fabrication of Polymer Laser Device by Two-Photon Induced Photopolymerization Technique

  • Yokoyama, Shiyoshi;Nakahama, Tatsuo;Miki, Hideki
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.231-231
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    • 2006
  • We fabricated a polymer sub-microstructure for optical device application by two-photon-induced laser lithography technique. Polymer pattern could be minimized as small as ${\sim}100\;nm$. The photopolymerization resin contains laser-dye, thus promising a high level of the optical gain. We utilized the lithography technique to the photonic crystal application, where the template of the two-dimensional photonic crystal was modified by polymer gain medium as defect-shape and line-shape orientations. Photonic band gap effect from polymer-doped photonic crystals is expected to exploit the application such as organic solid-state laser device.

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Synthesis and characterization of new liquid crystalline polymer for in-cell retardation film

  • Wang, Lei;Lim, Yeong-Jin;Kang, Hoon;Choi, Min-Oh;Lee, Seung-Hee;Lee, Myong-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1409-1411
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    • 2006
  • A new rod-like liquid crystalline monomer having divinyl terminal groups was synthesized and polymerized by using thiol-ene UV polymerization technique. High quality thin film with good retardation value was prepared on a rubbed alignment layer without the inert gas purging. The retardation value of the resulting film was controlled by experimental conditions such as spin speed, concentration, and spin time. From the retardation value and thickness measurement, ${\bigtriangleup}n$ was calculated to be 0.169 for the resulting film having thickness of 815.1 nm.

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Fluorescence Spectroscopic and Atomic Force Microscopic Studies on the Microstructure of Polyimide/Silica-Titania Ternary Hybrid Composites

  • Park, Hae-Dong;Ahn, Ki-Youl;Mohammad A. Wahab;Jo, Nam-Ju;Kim, Il;Kim, Gyuhyun;Lee, Won-Ki;Ha, Chang-Sik
    • Macromolecular Research
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    • v.11 no.3
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    • pp.172-177
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    • 2003
  • Biphenyltetracarboximide-phenylene diamine polyimide/silica-titania ternary hybrid composites were Prepared by thermal imidization and sol-gel reaction. Fluorescence spectroscopic, scanning electron microscopy, and atomic force microscopy studies revealed that the addition of small amount of titania showed profound effects on the microstructure and photophysical behaviors of polyimide/silica hybrid composites, when the content of silica-titania mixture was small or when the ratio of silica to titania in the mixture was high.