• Title/Summary/Keyword: High Polymer

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Synthesis and Optical Properties of Poly(2-ethynylpyridinum bromide) Having Glycidyl Functionality

  • Gal, Yeong-Soon;Lee, Won-Chul;Lee, Sang-Seob;Bae, Jang-Soon;Kim, Bong-Shik;Jang, Sang-Hee;Jin, Sung-Ho;Park, Jong-Wook
    • Macromolecular Research
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    • v.8 no.3
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    • pp.131-136
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    • 2000
  • The synthesis of poly(2-ethynylpyridine) having glycidyl functionality was performed by the direct polymerization of 2-ethynylpyridine and epibromohydrin under mild reaction conditions without any initiator and catalysts. The polymerization proceeded well to give the resulting poly(2-ethynylpyridinium bromide) with a glycidyl functionality having relativity high molecular weight in high yields. The polymer structure was characterized by various instrumental methods to have the conjugated polymer backbone structure having glycidyl functionality. This ionic polymer was completely soluble in water, methanol, DMF, DMSO, and N,N-dimethylacetamide, but insoluble in THF, toluene, acetone, nitrobenzene, and n-hexane. This polymer system exhibited the UV-visible absorption around 300 and 520 nm and red photoluminescence spectrum around 725 nm.

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A Study on the Evaluation of Hydrodynamic Performance of Trileaflet Prosthetic Heart Valves (삼엽식 인공판막의 수력학적 성능평가에 관한 연구)

  • 김혁필;이계한
    • Journal of Biomedical Engineering Research
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    • v.18 no.2
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    • pp.147-156
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    • 1997
  • Various prosthetic heart valves have been developed and used clinically, but they have problems, such as thrombogenecity, hemoltsis, high cost and low durability. New types of trileaflet polymer heart valves have been developed in order to use them as inlet and outlet valves in a ventricular assist device. The aim of this study is to determine the hydrodynamic effectiveness of the newly designed trileaflet polymer valves and their feasibility for temporary use in the blood pumps. Trileaflet polymer valves are made of polyurethane, because of its good blood compatibility, high tonsil strength and good resistance to fatigue. An in vitro experimental investigation was perf'ormed in order to ev91ua1e hydrodynamic performance of the trileaflet polymer valves having different design and fabrication tech- niques. The St. Jude Medical valve (SJMV) and floating-type monoleaflet polymer valve (MLPV) were also tested The pressure drop across the valve, leakage volume, and the flow patterns mere investigated for valves. The result of comparative tests showed that the trileaflet polymer valves had a better hydrodynamic performance than the others. TPV which has two stable membrane shape showed the lowest back flow. The pressure hops of TPVs were lower than that of MLPV, but slightly higher than SJMV. The hydrodynamic performance of valves under the pulastile flow showed the similar results as steady flow. The velocity profiles and turbulent intensities were measured at the distal sites of valves using a hot-film anemometer. Central flow was maintained in trileaflet polymer valves, and the maximum turbulent intensities were lower in TPVs comparing to MLPV.

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Preparation and Properties of Green Environment-Friendly Drilling Polymer Mud

  • Zhang, Feng-Jun;Sun, Xian-Yang;Li, Xuan;Kong, Cui;Liu, Jin;Chen, Qian-Bao;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.29 no.11
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    • pp.664-669
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    • 2019
  • In this paper, a water-based green polymer mud is synthesized by simple compounding method. Effects of different kinds of tackifiers, their molecular weight on the viscosity of polymer mud and the effects of different fluid loss additives on mud fluid loss are studied. The results show that when polystyrene and anionic polyacrylamide with molecular weight of 8 ~ 10 million are used as the main thickening ingredient, polymer mud with high viscosity and high stability can be obtained. When the prepared polymer mud is formulated as NPAM: PEO: Hydroxypropyl cellulose(HPC) : Water = 42:10:10:100000 (unit: kg), the viscosity can reach 20.6 s, the filtration loss in 7.5 min is 24 mL, and the sand content is only 0.1 %. Compared with traditional bentonite mud, the green environment-friendly polymer mud has the advantages of small amount of waste, low environmental pollution, and low pulping cost, and can meet the construction needs for most topography and geomorphology drilling engineering.

Yttrium-doped and Conductive Polymer-Coated High Nickel Layered Cathode Material with Enhanced Structural Stability

  • Shin, Ji-Woong;Lee, Seon-Jin;Nam, Yun-Chae;Son, Jong-Tae
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.272-278
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    • 2021
  • In this study, high nickel layered LiNi0.8Co0.1Mn0.1O2 cathode materials for lithium-ion batteries were modified by yttrium doping and poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) coating. The effects of yttrium doping and PEDOT:PSS coating on the structural and electrochemical properties of the LiNi0.8Co0.1Mn0.1O2 cathode material were investigated and compared. The substitution of nickel with an electrochemically inert yttrium was confirmed to be successful in stabilizing the layered structure framework. Moreover, coating the surfaces of the LiNi0.8Co0.1Mn0.1O2 particles with a conductive polymer, PEDOT:PSS, improved the capacity retention, thermal stability, and impedance of the cathode material by increasing its ionic and electric conductivities.

Distribution of the Equivalent Rectangular Stress Block for High-Strength Polymer Concrete Beams (고강도 폴리머 콘크리트보의 등가직사각형 응력분포)

  • 김관호;연규석;김남길;조규우
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.915-920
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    • 2001
  • This study was conducted to analysis the distribution of the rectangular stress block for high-strength polymer concrete beam. C-shaped specimens were produced and tested to compute parameters of the rectangular stress block. They were $\kappa_{1}$ = 0.73, $\kappa_{3}$ = 0.94 and $\gamma$= 0.845, respectively. Experimental value of flexural strength of beam was same to be compared with theoretical value. But there is desirable to need many experimental data in order to exact design of polymer concrete structure.

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Development of precast channel structure using polymer concrete (폴리머 콘크리트를 이용한 프리캐스트 수로구조물 개발)

  • 김관호;조태열;박광수;신수균;연규석
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.135-140
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    • 2001
  • This study was developed high-quality a large size precast channel structure using polymer concrete to improve quality of the product as well as to enhance construction quality. Precast PC represent the fastest growing segment of the polymer concrete industry. The fast curing, high strength, and low impermeability permit thin section and rapid reuse of moulds. Developed precast channel structure will be structural experiment and analysis. Also, through an example to construct will be develop the most suitable section survey and make practicable.

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Radical Polymers and Organic Radical Battery

  • Nishide, Hiroyuki
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.62-62
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    • 2006
  • Based on the redox couples of a nitroxide radical, organic radical polymers were utilized as the electrode-active or charge-storage component for a secondary battery. We call a battery composed of the radical polymer electrode as "organic radical battery". Organic radical battery has several advantages: high capacity, high power-rate performance, long cycle ability, and environmentally-benign features. Synthesis and electrochemical studies of nitroxide polymers are described. Battery fabrication and cell performance are also reported.

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Downscaling of self-aligned inkjet printed polymer thin film transistors

  • Noh, Yong-Young;Sirringhaus, Henning
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1564-1567
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    • 2008
  • We demonstrate here a self-aligned printing approach that allows downscaling of printed organic thin-film transistors to channel lengths of 100 - 400 nm. A perfected down-scaled polymer transistors (L= 200 nm) showing high transition frequency over 1.5 Mhz were realized with thin polymer dielectrics, controlling contact resistance, and minimizing overlap capacitance via self-aligned gate configuration.

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Magnetostrictive Properties of Polymer-Bonded Fe-Co Based Alloy Composites

  • S. M. Na;S. J. Suh;K. H. Shin;Lee, Y. S.;S. H. Lim
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.138-139
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    • 2002
  • Polymer-bonded magnetostrictive composites have some distinct advantages over conventional type materials in being cost effective and suitable for high frequency applications due to high electrical resistivity. Composites of rare earth based alloys were reported to show good magnetostrictive characteristics both in static and dynamic conditions [1]. It was originally thought that the application of the polymer-bonding technique to transition metal alloys is straightforward. (omitted)

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Effect of Porcelain/Polymer Interface on the Microstructure, Insulation Characteristics and Electrical Field Distribution of Hybrid Insulators (자기재/폴리머 계면이 하이브리드 애자의 미세구조, 절연특성과 전계분포에 미치는 영향)

  • Cho, Jun-Young;Kim, Woo-Seok;An, Ho-Sung;An, Hee-Sung;Kim, Tae-wan;Lim, Yun-Seog;Bae, Sung-Hwan;Park, Chan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.9
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    • pp.558-565
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    • 2017
  • Hybrid insulators that have the advantages of both porcelain (high mechanical strength and chemical stability) as well as polymer (light weight and high resistance to pollution) insulators, can be used in place of individual porcelain and polymer insulators that are used for both mechanical support as well as electrical insulation of overhead power transmission lines. The most significant feature of hybrid insulators is the presence of porcelain/polymer interfaces where the porcelain and polymer are physically bonded. Individual porcelain and polymer insulators do not have such porcelain/polymer interfaces. Although the interface is expected to affect the mechanical/electrical properties of the hybrid insulator, systematic studies of the adhesion properties at the porcelain/polymer interface and the effect of the interface on the insulation characteristics and electric field distribution of the hybrid insulator have not been reported. In this study, we fabricated small hybrid insulator specimens with various types of interfaces and investigated the effect of the porcelain/polymer interface on the microstructure, insulating characteristics, and electric field distribution of the hybrid insulators. It was observed that the porcelain/polymer interface of the hybrid insulator does not have a significant effect on the insulating characteristics and electric field distribution, and the hybrid insulator can exhibit electrical insulating properties that are similar or superior to those of individual porcelain and polymer insulators.