• Title/Summary/Keyword: High Polymer

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Electroluminescent Devices Using a Polymer of Regulated Conjugation Length and a Polymer Blend

  • Zyung, Tae-Hyoung;Jung, Sang-Don
    • ETRI Journal
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    • v.18 no.3
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    • pp.181-193
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    • 1996
  • A blue light emitting device has been successfully fabricated using a polymer with regulated conjugation length containing trimethylsilyl substituted phenylenevinylene units. Electroluminescence from the device has an emission maximum at 470 nm. The device shows typical diode characteristics with operating voltage of 20 V and the light becomes visible at a current density of less than $0.5;mA/cm^2$. The electroluminescence spectrum is virtually identical with the photoluminescence spectrum, indicating that the radiation mechanisms are the same for both. A light emitting device using the blend of a large band gap polymer and a small band gap polymer was also fabricated. Light emission from the small band gap polymer shows much improved quantum efficiency, but there is no light emission from the large band gap polymer. Quantum efficiency of the blend increases up to about two orders of magnitude greater than that of the small band gap polymer with increasing proportion of the large band gap polymer. The improvement in quantum efficiency is interpreted in terms of exciton transfer and the hole blocking behaviour of the large band gap polymer. Finally, we have fabricated a patterned flexible light emitting device using the high quantum efficiency polymer blend system.

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The Comparison of Absorption Characteristics between High Absorbent Polymers and Cellulose (고흡수성(高吸水性) Polymer와 Cellulose의 흡수특성(吸水特性) 비교(比較))

  • Yang, In;Ahn, Won-Yung
    • Journal of the Korean Wood Science and Technology
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    • v.18 no.2
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    • pp.36-48
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    • 1990
  • This experiment was carried out to improve the quality of high absorbent polymer which has excellent absorptivity and water retention compared to pulp and absorption sheet, through absorption characteristics-absorptive power, water retention, absorption rate, gel strength, pH, particle size, and moisture content. - of six polymers, namely, anionic polyacrylamide, cationic polyacrylamide, polyacrylic, acid polyvinyle alcohol 500, and 1500, and a-cellulose. and to examine the possibility of substitution of amide groups for carboxyl group and/or hydroxyl group which were commercial high absorbent polymer by comparing the absorption characteristics of the polymers. Polyacrylamide has high absorptive power and water retention, but has low gel strength and poor absorption rate. The rest of polymers were similiar to ${\alpha}$-cellulose in every respect. Thus, polyacrylamides could be replaced with polyacrylic acid and polyvinyl alcohol which are presently a high absorbent polymers. In comparing the absorption characteristics and the absorptive power of the polymers-anionic polyacrylamide, cationic polyacrylamide, polyacrylic acid, polyvinyle alcohol. a-cellulose-the absorptive power was in inverse proportion to the gel strength and absorption rates, affected by the particle size and pH change.

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Application of Sandwich Structure with Rigid Core for High Speed Machine Tool Bed (Rigid Core 샌드위치 구조의 초고속 공작기계 베드 적용에 관한 연구)

  • 서정도;이대길;김태형;박보선;최원선
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.113-116
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    • 2003
  • To maximize the productivity in machining molds and dies, machine tools should operate at high speeds. During the high speed operation of moving frames or spindles, vibration problems are apt to occur if the machine tool structures are made of conventional steel materials with inferior damping characteristics. However, self-excited vibration or chatter is bound to occur during high speed machining when cutting speed exceeds the stability limit of machine tool. Chatter is undesirable because of its adverse effect on surface finish, machining accuracy, and tool lift. Furthermore, chatter is a major cause of reducing production rate because, if no remedy can be found, metal removal rates have to be lowered until vibration-free performances is obtained. Also, the resonant vibration of machine tools frequently occurs when operating frequency approaches one of their natural frequencies because machine tools have several natural frequencies due to their many continuous structural elements. However, these vibration problems are closely related to damping characteristics of machine tool structures. This paper presents the use of polymer concrete and sandwich structures to overcome vibration problems. The polymer concrete has high potential for machine tool bed due to its good damping characteristics with moderate stiffness. In this study, a polymer concrete bed combined with welded steel structure i.e., a hybrid structure was designed and manufactured for a high-speed gantry-type milling. Also. its dynamic characteristics were measured by modal tests.

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Synthesis and Properties of High Voltage Silicone Rubber by Platinum-based Flame Retardant

  • Jung, Se-Young;Kim, Byung-Kyu
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.6
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    • pp.283-292
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    • 2006
  • So that high-strength and electrical properties apply by excellent high voltage insulator electricity material, ATH content and platinum-based flame retardant that influence in flame retardant and tracking characteristic among composite of silicone rubber studied mechanical strength and influence getting to electrical properties. Composition of ${\alpha}$, ${\omega}-vinyl$ poly (dimethyl-methylphenyl) siloxane(VPMPS) of a polymer quantity made doing mole of D4, $D3^{Me,Ph}$ and VMS by 1000:15:0.2 mole ratio and uses basic catalyst tetramethylammonium silanolate(TMAS) and do opening equilibrium polymerization to be used to main polymer for high voltage insulation insulator. Control ATH content and content of platinum-based flame retardant and made high voltage insulation silicone rubber. Measured mechanical strength of making silicone rubber using UTM, and tracking characteristic according to standard of IEC 60587, flame retardant test studied effect that flame retardant characteristic gets in tracking characteristic, measuring according to UL94V method of test.

Processing of Porous Ceramics with a Cellular Structure Using Polymer Beads

  • Ha, Jung-Soo;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1159-1164
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    • 2003
  • Two processing routes (i.e., the gel casting and polymer preform routes) using polymer beads were studied to fabricate porous ceramics with a cellular structure. The gel casting route, comprising the gel casting of a ceramic slurry mixed with polymer beads, was found to be inadequate to produce porous ceramic bodies with a interconnected pore structure, due to complete coating of the slurry on the polymer beads, which left just isolated pores in the final sintered bodies. The polymer preform route, involving the infiltration of a polymer beads preform with the ceramic slurry, successfully produced porous ceramics with a highly interconnected network of spherical pores. The pore size of 250-300 $\mu\textrm{m}$ was demonstrated and the porosity ranged from 82 to 86%. This process is advantageous to control the pore size because it is determined by the sizes of polymer beads used. Another feature is the avoidance of hollow skeleton, giving a high strength.

Field emission from non-conjugated polymers

  • Ionov, A.N.;Popov, E.O.;Svetlichnyi, V.M.;Nikolaeva, M.N.;Pashkevich, A.A.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.931-932
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    • 2004
  • We investigated a great number of polymer materials. The parameters affecting on its emission properties (namely, film thickness, temperature of polymer preparation. metal substrates and so on) were studied. We observed that emission distributed overfull polymer surface, with current densities up to several hundreds ${\mu}A/cm^2$. Some polymer samples have shown high current emission properties up to 50 ${\mu}A$ in DC and more then 1.5 mA in sinusoidal regimes.

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Development of Precast Channel Structure Using Polymer Concrete (폴리머 콘크리트를 이용한 조립식 수로구조물 표준도 개발)

  • Park, Kwang-Soo;Shin, Su-Gyun;Kim, Kwan-Ho;Lee, Meyong-Won;Lee, Joon-Gu
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2002.10a
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    • pp.157-160
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    • 2002
  • This study was developed high-quality a large size precast channel structure using polymer concrete to improve quality of the product as well as to enhance construction quality. Practical precast channel structure design and manufacture procedure for the high polymer concrete were described in this paper. Precast PC represent the fastest growing segment of the polymer concrete industry. The fast curing, high strength, and low impermeability permit thin section and rapid reuse of moulds. Precast channel structure will carry out structural experiment and analysis.

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Blends of semi-rigid substituted poly(p-phenylene) with BPA-polycarbonate

  • Dijkstra Dirk J.;Karbach Alexander;Malkovich Nick
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.364-364
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    • 2006
  • The rheological properties of Parmax 1200, a new semi-flexible substituted polyphenylene, were investigated. The reported high stiffness of the material was confirmed. The rheological measurements proved that, despite the very high stiffness of the molecules, Parmax showed shear thinning and that, although the viscosity is very high and the melt is highly elastic, the polymer can be extruded in the melt. A worm-like morphology was detected in AFM and TEM. This morphology could explain the reported mechanical and rheological behaviour. The compatibility with flexible chain polymers (e.g. polycarbonate) could also be explained by the worm-like morphology.

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Electric Field Distribution of High Voltage Polymer Bushing with Inner Field Shaper Designs (초고압 폴리머 부싱의 내부쉴드 형상에 따른 전계분포 특성)

  • Cho, Han-Goo;Yoo, Dae-Hoon;Kang, Hyung-Kyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.369-370
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    • 2008
  • This paper describes the electric field distribution of high voltage polymer bushing with inner field shaper designs. The field control can be achieved by means of the designs of such internal field shaper. But high electric stress occurred between field shaper and central conductor by the closely space. In accordance, the floating and ring shield designs was importance for electric stress grading at critical parts of the bushing. The bushing has a central conductor, and internal ring shield or floating shield, gaps are formed between field shaper and ring shield. Accordance equipotential lines extend through gaps. Maxwell 2D simulator based on the boundary element method was also introduced in order to verify the reliability of the polymer bushing.

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Development of Powder Utilization of Waste Rubber

  • Kim, Jin-Kuk;Lee, Sung-Hyo;Hwang, Sung-Hyuk
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.220-224
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    • 2001
  • Waste tires are a significant problem with the increasing in number of automobiles. Therefore, many researches have been studied on this field. Recycling is the one of the popular method aspect to environmental and economical in the treatment methods of the waste tire, which loads that the reuse of scrap tire rubber has been a challenge in the past. However, it is not easy method to melt down and mold into new products because the in rubber is a cross-linked polymer. Most difficulty in recycling is the recycled product is not economic. Therefore, the goal of this study is to develop the high valuable products for reused waste tires. In this paper, we try to make an economic recycled technology using scrapped waste tires. This technology may applied for manufacturing the end products such as a rubber block and a ballast mat for high-speed train.

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