• Title/Summary/Keyword: High Membrane Voltage

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Operating Method to Maximize Life Time of 5 kW High Temperature Polymer Exchange Membrane Fuel Cell Stack (5 kW 고온 고분자연료전지 스택 수명 극대화를 위한 운전 방법론)

  • KIM, JIHUN;KIM, MINJIN;SOHN, YOUNG-JUN;YU, SANGSEOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.2
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    • pp.144-154
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    • 2016
  • HT-PEMFC (high temperature polymer electrolyte membrane fuel cell) using PA (phosphoric acid) doped PBI (polybenzimidazole) membrane has been researched for extending the lifetime. However, the existing work on durability of HT-PEMFC focuses on identifying degradation causes of lab scale. The short life time of HT-PEMFC is still the problem for its commercialization. In this paper, an operating method to maximize life time of 5kW HT-PEMFC stack are proposed. The proposed method includes major steps such as minimization of OCV (Open Circuit Voltage) exposure, control of the proper stack temperature, and N2 purging for the stack. This long life operating method was based on the fragmentary results of degradation from previous research works. Experimentally, the 5 kW homemade HT-PEMFC stack was operated for a long time based on the proposed method and the stack successfully can operate within the desired degradation rate for the target life time.

Effects of the Methanol Concentration, Wind Velocity and Stack Temperature on the performance of Direct Methanol Fuel Cell (직접 메탄올 연료 전지의 성능에 대한 메탄올 농도, 풍속 및 스택 온도의 영향)

  • Kim, Yong-Ha;Kim, Seok-Il
    • Journal of Aerospace System Engineering
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    • v.1 no.2
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    • pp.21-26
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    • 2007
  • DMFC(Direct Methanol Fuel Cell) has been considered as an attractive option to produce electric power in many application. In this study, in order to estimate the effects of the methanol concentration, wind velocity and temperature on the performance of DMFC, a physical prototype of DMFC was designed and manufactured, and the stack voltage of DMFC was measured during the operation of DMFC. Expecially, the experimental results showed that a low stack temperature, a low wind velocity and an excess methanol concentration lead to the increase of the time to reach the maximum stack voltage.

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Elctrical Properties of DLPC Lipid Membrane Fabricated on the Silicon Wafer (실리콘 웨이퍼 위에 제작된 DLPC 지질막의 전기적특성)

  • 이우선;김충원;이강현;정용호;김남오;김상용
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.12
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    • pp.1115-1121
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    • 1998
  • MLS capacitor with lipid ultra thin films were deposited by Langmuir-Blodgett (LB) method on the silicon wafer. The current versus voltage and capacitance versus voltage relationships are depend on the applied voltage, electrode area and electrode materials. LB films deposited were made of L-$\alhpa$-DLPC, the 1 layer’s thickness of 35${\AA}$ was measured by ellipsometer. And MLS capacitor with different electrode materials, the work function of these materials was investigated to increase the leakage current. The result indicated the lower leakage current and very high saturation value of capacitance was reached within 700-800 pF when the two electrode was Ag. And $\varepsilon$1, $\varepsilon$2 versus photon energy showed good film formation.

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Membrane fouling control using the high voltage impulse system (고전압 임펄스 장치를 이용한 막오염 제어 연구)

  • Park Su-Ji;Lee Ju-Hun;Chang In-Soung;Kang Sung-Mi;Lee June-Ho
    • Proceedings of the KAIS Fall Conference
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    • 2005.05a
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    • pp.272-273
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    • 2005
  • 분리막 기술은 탁월한 처리효율뿐 아니라 안정적으로 용수를 생산할 수 있는 장점이 있기 때문에 용수의 생산을 전통적인 수처리 (Conventional water treatment) 공정에서 역삼투 공정(Reverse Osmosis) 및 나노여과 (Nanofiltration)와 같은 분리막 기술을 활용하는 공정으로 변환하는 추세에 있다. 그러나 분리막 공정은 항상 막오염 현상이 문제점으로 지목되고 있기 때문에 막오염 제어 기술의 확보가 시급한 실정이다. 따라서 본 연구에서는 화학물질의 사용에 따른 2차 환경오염 문제가 발생하는 화학약품이나 물리적인 세정이 아닌 고전압 임펄스 (HVI, High Voltage Impulse) 장치를 이용하여 막오염의 근본적인 문제를 제어하려 한다.

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A Fuel Cell Generation System of SEPIC-Flyback Converter using a Single Transformer (단일 변압기를 사용한 SEPIC-Flyback 컨버터의 연료전지 발전 시스템)

  • Kang, K.S.;Jang, S.J.;Lee, T.W.;Kim, S.S.;Won, C.Y.
    • Proceedings of the KIPE Conference
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    • 2005.07a
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    • pp.357-359
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    • 2005
  • In this paper, a new SEPIC-Flyback converter with a single transformer has been proposed, which is suitable for a fuel cell based power generation system. The proposed converter is superposition of sepic and flyback converter mode. It has outstanding high boosting output voltage, component utilization and high efficiency characteristics under the inherently severe low output voltage of the fuel cell generator. The proposed converter for a full cell generator is described and verified by simulation and experimental result that make used of the Polymer Electrolyte Membrane Fuel Cell(PEMFC) Generator.

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Optimal Design of a MEMS-type Piezoelectric Microphone (MEMS 구조 압전 마이크로폰의 최적구조 설계)

  • Kwon, Min-Hyeong;Ra, Yong-Ho;Jeon, Dae-Woo;Lee, Young-Jin
    • Journal of Sensor Science and Technology
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    • v.27 no.4
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    • pp.269-274
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    • 2018
  • High-sensitivity signal-to-noise ratio (SNR) microphones are essentially required for a broad range of automatic speech recognition applications. Piezoelectric microphones have several advantages compared to conventional capacitor microphones including high stiffness and high SNR. In this study, we designed a new piezoelectric membrane structure by using the finite elements method (FEM) and an optimization technique to improve the sensitivity of the transducer, which has a high-quality AlN piezoelectric thin film. The simulation demonstrated that the sensitivity critically depends on the inner radius of the top electrode, the outer radius of the membrane, and the thickness of the piezoelectric film in the microphone. The optimized piezoelectric transducer structure showed a much higher sensitivity than that of the conventional piezoelectric transducer structure. This study provides a visible path to realize micro-scale high-sensitivity piezoelectric microphones that have a simple manufacturing process, wide range of frequency and low DC bias voltage.

Acceleration Test of Membrane-Electrode Assembly in PEMFC (고분자연료전지의 전해질-전극 접합체의 열화 가속시험)

  • Lee, Jung-Hun;Yoon, Young-Gi;Jung, Eun-Ha;Lee, Won-Yong;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.93-96
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    • 2007
  • Recently, much attentions have been paid on the commercialization of PEMFC, especially for the applications of residential and portable. In order to achieve the early commercialization of PEMFC, thee are two hurdles to overcome. One is cost down and the other is improvement of durability of the system components. Numerous companies have tried to reduce the production cost and the main research topics have been changed from performance to durability improvement. In this work, acceleration test were performed to find and evaluate the main reason of degradation of the MEA(membrane-electrode assembly) which is one of the core component of the PEMFC system. Based upon the test results, a way to make durable MEA was suggested. Acceleration tests were made by applying high voltage of 1.2V to the several kinds of single cells to increase the growth of catalyst particles. Cell performance, ac-impedance and electrochemically active area measurements were made atfter every 8 hours of acceleration test. Degradations of catalyst and membrane were examined by SEM, TEM and XRD. Obtained results were discussed in terms of structural stability and loss of catalyt and ionomers in the electrode layer. In addition, the way to make highly durable MEA was suggested.

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The Effects of Different Membranes on the Performance of Aqueous Organic Redox Flow Battery Using Anthraquinone and TEMPO Redox Couple (안트라퀴논과 템포 활물질 기반 수계 유기 레독스 흐름 전지에서의 멤브레인 효과)

  • Lee, Wonmi;Kwon, Yongchai
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.695-700
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    • 2019
  • n this study, the evaluation of performance of AORFB using anthraquinone derivative and TEMPO derivative as active materials in neutral supporting electrolyte with various membrane types was performed. Both anthraquinone derivative and TEMPO derivative showed high electron transfer rate (the difference between anodic and cathodic peak potential was 0.068 V) and the cell voltage is 1.17 V. The single cell test of the AORFB using 0.1 M active materials in 1 M KCl solution with using Nafion 212 membrane, which is commercial cation exchange membrane was performed, and the charge efficiency (CE) was 97% and voltage efficiency (VE) was 59%. In addition, the discharge capacity was $0.93Ah{\cdot}L^{-1}$ which is 35% of theoretical capacity ($2.68Ah{\cdot}L^{-1}$) at $4^{th}$ cycle and the capacity loss rate was $0.018Ah{\cdot}L^{-1}/cycle$ during 10 cycles. The single cell tests were performed with using Nafion 117 membrane and SELEMION CSO membrane. However, the results were more not good because of increased resistance because of thicker thickness of membrane and increased cross-over of active materials, respectively.

Full-bridge Soft-Switching PS-PWM DC-DC Converter for Fuel Cell Generation System (연료전지 시스템을 위한 풀-브리지 소프트 위상 천이 PWM DC-DC 컨버터)

  • Mun, S.P.;Suh, K.Y.;Lee, H.W.;Nakaoko, M.;Shin, H.B.
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2005.11a
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    • pp.371-376
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    • 2005
  • In this paper, a new a new full-bridge soft-switching phase shift PWM DC-DC Converter has been proposed, which is suitable for fuel cell based power generation system. The proposed converter has outstanding advantage over the conventional DC-DC converter with respect to high efficiency, high power density, and hish component utilization. In special. the proposed converter has predominant high boosting output voltage and high efficiency characteristics under the inherently severs low output voltage of the fuel cell through the overall load conditions. Moreover, the developed converter has been experimentally tested with the help of a fuel cell simulator, and can generate the V-I characteristics of proton exchange membrane(PEM) fuel cell, so that the performance of the proposed converter could be effectively examined and the validity of the converter could be verified.

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A Study on the Fabrication and Electrical Characteristics of Hydraulic Pressure Sensors by Using Ceramics Materials (세라믹소재를 이용한 해수압센서 제작 및 전기적 특성 연구)

  • Park, Sung-Hyun;Kim, Eun-Sup;Jung, Jung-Kyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.6
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    • pp.384-389
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    • 2015
  • In this paper, we fabricated ceramic body and sapphire wafer in order to develop a hydraulic pressure sensor with high sensitivity and high temperature stability. The sapphire wafer was adopted with a membrane of capacitance ceramic pressure sensor. The capacitance value of the sensor for the finite element analysis(FEM) showed a linear pressure characteristics. Membrane was processed with a diameter of 32.4 mm and a thickness of 1 mm by using alumina powders. Ceramic body was processed with a diameter 32.4 mm and a thickness 5 mm. The capacitance pressure sensor was made with high heat treatment of the ceramic body and the sapphire wafer. Initially capacitance of the pressure sensor was 50 pF and a capacitance of 110 pF was measured from 5 bar pressure. Output voltage of 5 V was appeared at 5 bar pressure.