• Title/Summary/Keyword: High Energy Density

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Lithium Air Battery: Alternate Energy Resource for the Future

  • Zahoor, Awan;Christy, Maria;Hwang, Yun-Ju;Nahm, Kee-Suk
    • Journal of Electrochemical Science and Technology
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    • v.3 no.1
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    • pp.14-23
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    • 2012
  • Increasing demand of energy, the depletion of fossil fuel reserves, energy security and the climate change have forced us to look upon alternate energy resources. For today's electric vehicles that run on lithium-ion batteries, one of the biggest downsides is the limited range between recharging. Over the past several years, researchers have been working on lithium-air battery. These batteries could significantly increase the range of electric vehicles due to their high energy density, which could theoretically be equal to the energy density of gasoline. Li-air batteries are potentially viable ultra-high energy density chemical power sources, which could potentially offer specific energies up to 3000 $Whkg^{-1}$ being rechargeable. This paper provides a review on Lithium air battery as alternate energy resource for the future.

Surface Functionalization of Carbon Fiber for High-Performance Fibrous Supercapacitor (고성능 섬유형 슈퍼커패시터를 위한 탄소섬유의 표면 기능화)

  • Lee, Young-Geun;An, Geon-Hyoung
    • Korean Journal of Materials Research
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    • v.32 no.2
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    • pp.107-113
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    • 2022
  • Fibrous supercapacitors (FSs), owing to their high power density, good safety characteristic, and high flexibility, have recently been in the spotlight as energy storage devices for wearable electronics. However, despite these advantages, FCs face many challenges related to their active material of carbon fiber (CF). CF has low surface area and poor wettability between electrode and electrolyte, which result in low capacitance and poor long-term stability at high current densities. To overcome these limits, fibrous supercapacitors made using surface-activated CF (FS-SACF) are here suggested; these materials have improved specific surface area and better wettability, obtained by introducing porous structure and oxygen-containing functional groups on the CF surface, respectively, through surface engineering. The FS-SACF shows an improved ion diffusion coefficient and better electrochemical performance, including high specific capacity of 223.6 mF cm-2 at current density of 10 ㎂ cm-2, high-rate performance of 171.2 mF cm-2 at current density of 50.0 ㎂ cm-2, and remarkable, ultrafast cycling stability (96.2 % after 1,000 cycles at current density of 250.0 ㎂ cm-2). The excellent electrochemical performance is definitely due to the effects of surface functionalization on CF, leading to improved specific surface area and superior ion diffusion capability.

Pulse Density Modulation Controlled Series Load Resonant Zero Current Soft Switching High Frequency Inverter for Induction-Heated Fixing Roller

  • Sugimura, Hisayuki;Kang, Ju-Sung;Saha, Bishwajit;Lee, Hyun-Woo;Nakaoka, Mutsuo
    • Proceedings of the KIEE Conference
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    • 2006.04b
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    • pp.226-228
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    • 2006
  • This paper presents the two lossless auxiliary inducors-assisted voltage source type half bridge(single ended push pull:SEPP) series resonant high frequency inverter for induction heated fixing roller in copy and printing machines. The simple high-frequency inverter treated here can completely achieve stable zero current soft switching (ZCS) commutation forwide its output power regulation ranges and load variations under constant high frequency pulse density modulation (PDM) scheme. Its transient and steady state operatprinciple is originally described and discussed for a constant high-frequency PDM control strategy under a stable ZCS operation commutation, together with its output effective power regulation charactertics-based on the high frequency PDM strategy. The experimenoperating performances of this voltage source SEPP ZCS-PDM series resonant high frequency inverter using IGBTs are illustrated as compared with computer simulation results and experimenones. Its power losses analysis and actual efficiency are evaluated and discussed on the basis of simulation and experimental results. The feasible effectiveness of this high frequency inverter appliimplemented here is proved from the practical point of view.

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A Study for Development of Compact Powerpack used Hydrogen (수소를 연료로 하는 소형 파워팩 개발에 관한 연구(I))

  • Kim, Nam-Yuer;Kim, Gang-Chul;Lim, Ock-Taeck
    • Journal of Hydrogen and New Energy
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    • v.21 no.4
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    • pp.321-327
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    • 2010
  • Current rechargeable battery cannot provide high energy density and the operational durations required. But linear engine/generators provide high energy density for portable power applications because fuel is more high density. In this paper, we suggest that basic design of powerpack using linear engine for assisting power output. Efficiency is relatively high because linear engine don't have crank mechanism compared with rotary engine. We made prototype engine and had experiments to know moving characteristic about the Linear Engine. It was possible to operate velocity at 50 Hz at the firing and pressure in cylinder was 16bar.

Composited Conductive Materials for Enhancing the Ultrafast Performance for Anode in Lithium-Ion Battery (리튬이온전지 음극의 고속 성능 향상을 위한 도전재 복합화)

  • Ki-Wook, Sung;Hyo-Jin, Ahn
    • Korean Journal of Materials Research
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    • v.32 no.11
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    • pp.474-480
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    • 2022
  • Lithium-ion batteries (LIBs) are powerful energy storage devices with several advantages, including high energy density, large voltage window, high cycling stability, and eco-friendliness. However, demand for ultrafast charge/discharge performance is increasing, and many improvements are needed in the electrode which contains the carbon-based active material. Among LIB electrode components, the conductive additive plays an important role, connecting the active materials and enhancing charge transfer within the electrode. This impacts electrical and ionic conductivity, electrical resistance, and the density of the electrode. Therefore, to increase ultrafast cycling performance by enhancing the electrical conductivity and density of the electrode, we complexed Ketjen black and graphene and applied conductive agents. This electrode, with the composite conductive additives, exhibited high electrical conductivity (12.11 S/cm), excellent high-rate performance (28.6 mAh/g at current density of 3,000 mA/g), and great long-term cycling stability at high current density (88.7 % after 500 cycles at current density of 3,000 mA/g). This excellent high-rate performance with cycling stability is attributed to the increased electrical conductivity, due to the increased amount of graphene, which has high intrinsic electrical conductivity, and the high density of the electrode.

Hybrid Capacitors Using Organic Electrolytes

  • Morimoto, T.;Che, Y.;Tsushima, M.
    • Journal of the Korean Electrochemical Society
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    • v.6 no.3
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    • pp.174-177
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    • 2003
  • Electric double-layer capacitors based on charge storage at the interface between a high surface area activated carbon electrode and an electrolyte solution are characterized by their long cycle-life and high power density in comparison with batteries. However, energy density of electric double-layer capacitors obtained at present is about 6 Wh/kg at a power density of 500W/kg which is smaller as compared with that of batteries and limits the wide spread use of the capacitors. Therefore, a new capacitor that shows larger energy density than that of electric double-layer capacitors is proposed. The new capacitor is the hybrid capacitor consisting of activated carbon cathode, carbonaceous anode and an organic electrolyte. Maximum voltage applicable to the cell is over 4.2V that is larger than that of the electric double-layer capacitor. As a result, discharged energy density on the basis of stacked volume of electrode, current collector and separator is more than 18Wh/l at a power density of 500W/l.

A Compilation and Evaluation of Thermal and Mechanical Properties of Bentonite-based Buffer Materials for a High- level Waste Repository

  • Cho, Won-Jin;Lee, Jae-Owan;Kang, Chul-Hyung
    • Nuclear Engineering and Technology
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    • v.34 no.1
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    • pp.90-103
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    • 2002
  • The thermal and mechanical properties of compacted bentonite and bentonite-sand mixture were collected from the literatures and compiled. The thermal conductivity of bentonite is found to increase almost linearly with increasing dry density and water content of the bentonite. The specific heat can also be expressed as a function of water ontent, and the coefficient of thermal expansion is almost independent on the dry density. The logarithm of unconfined compressive strength and Young’s modulus of elasticity increase linearly with increasing dry density, and in the case of constant dry density, it can be fitted to a second order polynomial of water content. Also the unconfined compressive strength and Young’s modulus of elasticity of the bentonite-sand mixture decreases with increasing sand content. The Poisson’s ratio remains constant at the dry density higher than 1.6 Mg/m$_3$, and the shear strength increases with increasing dry density.

Design of A High Energy Density Pulse Transformer (고 에너지 밀도 펄스 변압기 설계)

  • Nam, S.H.;Park, S.S.;Ha, K.M.
    • Proceedings of the KIEE Conference
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    • 1999.07e
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    • pp.2186-2188
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    • 1999
  • A high frequency and energy density pulse transformer is a critical component of a high voltage power supply in a traveling wave tube (TWT) amplifier system. In this paper, processes of design, manufacturing, and test of the transformer are discussed. Primary voltage of the transformer is 240 V. The transformer secondary have two outputs which are 4100 V (Helix) and 2050 V (Collector). Total output power is 860 W. Normal operating frequency of the transformer is 10 kHz. In high energy density pulse transformers, temperature rise is a main problem during its operation. From our study, it was found that resonant current due to leakage inductance and stray capacitance was the main cause of temperature rise. This happens because of the inherently high turn-ratio in high voltage transformers. Solutions to reduce stray components are presented.

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Effects of Sputtering Pressure on the Properties of BaTiO3 Films for High Energy Density Capacitors

  • Park, Sangshik
    • Korean Journal of Materials Research
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    • v.24 no.4
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    • pp.207-213
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    • 2014
  • Flexible $BaTiO_3$ films as dielectric materials for high energy density capacitors were deposited on polyethylene terephthalate (PET) substrates by r.f. magnetron sputtering. The growth behavior, microstructure and electrical properties of the flexible $BaTiO_3$ films were dependent on the sputtering pressure during sputtering. The RMS roughness and crystallite size of the $BaTiO_3$ increased with increasing sputtering pressure. All $BaTiO_3$ films had an amorphous structure, regardless of the sputtering pressures, due to the low PET substrate temperature. The composition of films showed an atomic ratio (Ba:Ti:O) of 0.9:1.1:3. The electrical properties of the $BaTiO_3$ films were affected by the microstructure and roughness. The $BaTiO_3$ films prepared at 100 mTorr exhibited a dielectric constant of ~80 at 1 kHz and a leakage current of $10^{-8}A$ at 400 kV/cm. Also, films showed polarization of $8{\mu}C/cm^2$ at 100 kV/cm and remnant polarization ($P_r$) of $2{\mu}C/cm^2$. This suggests that sputter deposited flexible $BaTiO_3$ films are a promising dielectric that can be used in high energy density capacitors owing to their high dielectric constant, low leakage current and stable preparation by sputtering.

Recent Progress of Alloy-Based All-Solid-State Li-Ion Battery Anodes (전고체 리튬 이차전지용 합금계 음극 소재의 연구 동향)

  • Jeong-Myeong Yoon;Cheol-Min Park
    • Corrosion Science and Technology
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    • v.22 no.6
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    • pp.466-477
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    • 2023
  • The increasing demand for high-performance energy storage systems has highlighted the limitations of conventional Li-ion batteries (LIBs), particularly regarding safety and energy density. All-solid-state batteries (ASSBs) have emerged as a promising next-generation energy storage system, offering the potential to address these issues. By employing nonflammable solid electrolytes and utilizing high-capacity electrode materials, ASSBs have demonstrated improved safety and energy density. Automotive and energy storage industries, in particular, have recognized the significance of advancing ASSB technology. Although the use of Li metal as ASSB anode is promising due to its high theoretical capacity and the expectation that Li dendrites will not form in solid electrolytes, persistent problems with Li dendrite formation during cycling remain. Therefore, the exploration of novel high-performance anode materials for ASSBs is highly important. Recent research has focused extensively on alloy-based anodes for ASSBs, owing to their advantages of no dendrite formation and high-energy density. This study provides a comprehensive review of the latest advancements and challenges associated with alloy-based anodes for ASSBs.