• Transactions of the Korean hydrogen and new energy society
• /
• v.21 no.6
• /
• pp.507-512
• /
• 2010

The effect of catholyte to anolyte amount ratio on the electrodialysis cell performance for HI concentration was investigated. For this purpose, the electrodialysis cell was assembled with Nafion 117 as PEM membrane and activated carbon fiber cloth as electrodes. The initial amount of catholyte was 310 g and that of anolyte varied from 1 to 3 of amount ratio. The calculated electro motive force (EMF) increased with time and the increment enhanced as the amount ratio of catholyte to anolyte decreased. The mole ratios of HI to $H_2O$ (HI molarity) in catholyte were almost the same and exceeded pseudo-azeotropic composition for all amount ratios after 2 h operation. The HI molarity continuously increased with time for 10 h operation. The mole ratio of $I_2$ to HI decreased in catholyte but increased in anolyte. The increment of mole ratio of $I_2$ to HI in anolyte rose as the amount ratio of catholyte to anolyte decreased. In case of 1:1 amount ratio, the cell operation was stopped for the safety at approximately 6 h operation, since the mole ratio of $I_2$ to HI reached solubility limit. The cell voltage of the electrodialysis cell increased with time and the rate of increase was high at low amount ratio. This suggests that the amount ratio of catholyte to anolyte not only crucially influences the cell voltage, but also cell operation condition.

• Transactions of the Korean hydrogen and new energy society
• /
• v.17 no.2
• /
• pp.212-217
• /
• 2006

An experimental study on Electro-electrodialysis (EED) for IS (Iodine-Sulfur) process which is well known as hydrogen production system was carried out for the HI concentration from HIx (HI: $H_2O$ : $I_2$ = 1 : 5 : 1) solution. The polymer electrolyte membrane and the activated carbon cloth were adopted as a cation exchange membrane and electrode, respectively. In order to evaluate the temperature effect about HI concentration in fixed molar ratio, three case of temperature were selected to $60^{\circ}C$, $90^{\circ}C$ and $120^{\circ}C$. The electro-osmosis coefficient and transport number of proton have been changed from 1.95 to 1.21 (mol/Faraday) and 0.91 to 0.76, respectively as temperature increase from $60^{\circ}C$ to $120^{\circ}C$. It can be realized that the HI mole fraction in final stage of EED experiments already over the quasi-azeotrope composition.

• Proceedings of the Korean Magnestics Society Conference
• /
• 2008.12a
• /
• pp.163.1-163.1
• /
• 2008

• Journal of Microbiology and Biotechnology
• /
• v.15 no.6
• /
• pp.1388-1391
• /
• 2005

Temporal changes of cell growth pattern and intracellular content of $\beta$-D-glucans were investigated with off-gas data in Agaricus blazei culture where glucose was intermittently fed. It was observed that the time point of carbon source depletion coincided with the point of sudden drop in the carbon dioxide evolution rate (CER), and that the sole supplementation of glucose was not enough to maintain active cell growth and glucan content. On the other hand, when yeast extract, a typical nitrogen source, was supplemented together with glucose when the CER suddenly dropped because of carbon source depletion, an active cell growth could be maintained until the end of the culture and the glucan content did not decrease with culture time, significantly enhancing glucan productivity.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.7 no.1
• /
• pp.27-32
• /
• 2006

We separated semiconducting single-walled carbon nanotubes(sem-SWCNT) from the HiPco-SWCNTS by dispersion with octadecylamine(ODA). The mixture of acid-treated SWCWTS and ODA was heated at $120^{\circ}C$ for 120hours. ODA physisorbs selectively on the side-wall of sem-SWCNTS. The ODA-treated CNTs were dispersed in tetrahydrofuran(THF) via sonication. The ODA-physisorbed sem-SWCNT can be retained in the supernatant of THF, but met-SWCNT and unabsorbed sem-SWCNT were precipitated in THF. Raman spectra with 514 nm and 1074 nm were investigated. The amount of sem-SWCNT in the supernatant and precipitant was about 94 % and 50 %, respectively.

• Journal of the Korea Institute of Information and Communication Engineering
• /
• v.18 no.7
• /
• pp.1505-1510
• /
• 2014

High-Pass (ETC ; Electronic Toll Collection) system is one of the basic elements, which adopts a wireless communication method using 5.8 GHz and can realize a part of ITS (Intelligent Traffic System). On the other hand, communication errors occur frequently in Hi-Pass system due to signal erros, multi-path reflection, and/or system-to-system interferences. To solve these problems, an EM (Electro-Magnetic) wave absorber can be used. To solve these Problems, we fabricated some samples in the different composition ratios of Carbon, Sendust, and CPE, and it was confirmed that the optimum composition ratio of Carbon : Sendust : CPE is 10 : 40 : 50 wt.%. The complex relative permittivity and complex relative permeability were derived by using the measured data. In addition, the optimum design parameters for the absorber were determined by simulation. Then the absorption abilities were calculated by changing the thickness of the EM wave absorbers. As a result, the optimum thickness of the developed EM wave absorber was 2.85 mm with absorption ability over 22.4 dB at 5.8 GHz. Futhermore, the EM wave absorber was fabricated based on the simulated and designed values. The measured values agreed well with the simulated ones. Therefore, it was clearly shown that the developed EM wave absorber in this paper is to be applied in actual situations.

• Journal of Microbiology and Biotechnology
• /
• v.10 no.6
• /
• pp.829-835
• /
• 2000

The ptsH and ptsI genes of Lactococus lactis subsp. lactis ATCC 7962 (L. lactis 7962), encoding the general proteins of phosphotransferase system (PTS) components, HPr and enzyme I, respectively, were cloned and characterized. A 1.3 kb PCR product was obtained using a primer set that was hybridized to the internal region of the L. lactis 7962 pts HI genes and then subcloned into a low-copy number vector, pACYC184. The 5' upstream and 3' downstream region from the 1.3 kb fragment were subsequently clone using the chromosome walking method. The complete ptsHI operon was constructed and the nucleotide sequences determined. Two ORFs corresponding to HPr (88 amino acids) and enzyme I (575 amino acids) were located. The ptsHI genes of L. lactis 7962 showed a very high homology (84-90%) with those genes from other Gram-positive bacteria. A primer extension analysis showed that the transcription started at either one of two adjacent bases upstream of the start codon. Using a Northern analysis, two transcripts were detected; the first, a 0.3 kb transcript corresponding to ptsH and the second, a 2 kb transcript corresponding to ptsH and ptsI. The transcription level of ptsH was higher than that of ptsI. The concentration of the ptsH transcript in cells grown on glucose was similar to that in cells grown on lactose, yet higher than that in cells grown on galactose. The ptsI transcript was scarcely detected in cell grown on lactose or galactose. The ptsI transcript was scarcely detected in cells grown on lactose or galactose. The results of a sequence analysis and Northern blot confirmed that the ptsH and ptsI genes of L. lactis 7962 were arranged in an operon like other known ptsHI genes and the expression of the ptsHI genes was regulated at the transcriptional level in response to the carbon source.

• Korean Journal of Metals and Materials
• /
• v.47 no.2
• /
• pp.71-78
• /
• 2009

The precipitation behavior of solute carbon and nitrogen strongly affects the mechanical properties of low-carbon automotive panel. In the present study, the effects of aluminum and solute nitrogen on the bake hardenability and strain aging of extremely low-carbon steel with carbon content below 15 ppm has been investigated. The ferrite grain size and distribution of precipitates were varied with the amount of aluminum content of 0.003 to ~ 0.100 wt% in a constant solute carbon and nitrogen. With increasing the aluminum content, the ferrite grain size is increased and strain aging is delayed. The strain aging is also delayed by increasing the annealing temperature, although the ferrite grain size is not much changed.

• Journal of Korean Society on Water Environment
• /
• v.21 no.2
• /
• pp.125-131
• /
• 2005

Natural organic matter(NOM) is defined as the complex matrix of organic material and abundant in natural waters. It affects the performance of unit operations for water purification. Several kinds of analytical indicators such as DOC, specific ultraviolet absorbance(SUVA), apparent molecular weight (AMW), fractionation and high performance size exclusive chromatography(HPSEC) have been used to understand characteristics and variations of NOM. This study aims to evaluate the characteristics of NOM in the Geum River system comprising with stream flows and reservoirs. It was identified that SUVA denoting the portion of humic substance in water ranged within 1.60~3.36. Using resin adsorbents, dissolved organic carbon(DOC) was fractionated into three classes: hydrophobic bases(HOB), hydrophobic acids(HOA) and hydrophilic substances(HI). HI dominates in all samples, collectively accounting for more than 62% of the DOC. HOA was the second dominated fraction and it varied considerably but accounted for about 30% of the DOC. The distribution of high molecular weight(HMW) measured by HPSEC being used to determine the molecular weight distribution of aquatic humic substances was 40.1% and 38.7% in reservoir and stream flow, respectively. The distribution of low molecular weight(LMW) in stream flow was 13.2% higher than that in reservoir. And apparent molecular weight less than 1KDa, which include the molecular weight of hydrophilic organic matter, occupied with 69.2% and 68.2% in stream flow and reservoir, respectively. While the molecular weight of 1 to 100 KDa including humic substances ranged with 18.6% and 21.6% in stream flow and reservoir, respectively. Seasonal variation of refractory dissolved organic carbon was similar to that of SUVA.

• Applied Microscopy
• /
• v.47 no.3
• /
• pp.86-94
• /
• 2017

In this study, we will describe a new design of carbon nanotubes tip. Single-walled carbon nanotubes produced using high-pressure CO over Fe particles (HiPCO) at CNI, Houston, TX used in this study. These tips were manufactured by employing a drawing technique using glass puller. Field electron microscopies with tips (cathode) to screen (Anode) separation of ~10 mm was used to characterize the electron emitters. The system was evacuated down to base pressure of (${\sim}10^{-8}$ mbar) when baked at up to (${\sim}200^{\circ}C$) over night. An electron field emission patterns, as well as current versus voltage characteristics and Fowler-Nordheim plots, are discussed.