• 제목/요약/키워드: Hexagonal

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다중강전자 상태를 가진 육방정계물질의 전자구조 계산 (The Electronic Structure Calculations for Hexagonal Multiferroic Materials)

  • 박기택
    • 한국자기학회지
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    • 제17권4호
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    • pp.152-155
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    • 2007
  • 다중강전자 상태의 $YMnO_3,\;ScMnO_3$의 전자구조와 자기구조를 국소스핀밀도근사(LSDA)를 이용하여 계산하였다. 강자성 상태이며 강유전 상태의 전자구조는 육방정계 구조로 인하여 Mn 3d 에너지띠가 분리되어 띠틈을 나타내었다. 이러한 에너지 띠틈과 작은 Y, Sc 이온의 반경으로 인하여 $YMnO_3,\;ScMnO_3$는 반강자성 강유전적 성질을 가지는 다중강전자 구조를 가지고 있음을 보았다. 또한 총에너지 계산을 통하여 반강자성, 강유전 상태가 가장 안정됨이 실험과 일치하였다.

Probing the Atomic Structures of Synthetic Monolayer and Bilayer Hexagonal Boron Nitride Using Electron Microscopy

  • Tay, Roland Yingjie;Lin, Jinjun;Tsang, Siu Hon;McCulloch, Dougal G.;Teo, Edwin Hang Tong
    • Applied Microscopy
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    • 제46권4호
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    • pp.217-226
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    • 2016
  • Monolayer hexagonal boron nitride (h-BN) is a phenomenal two-dimensional material; most of its physical properties rival those of graphene because of their structural similarities. This intriguing material has thus spurred scientists and researchers to develop novel synthetic methods to attain scalability for enabling its practical utilization. When probing the growth behaviors and structural characteristics of h-BN, the use of appropriate characterization techniques is important. In this review, we detail the use of scanning and transmission electron microscopies to investigate the atomic configurations of monolayer and bilayer h-BN grown via chemical vapor deposition. These advanced microscopy techniques have been demonstrated to provide intimate insights to the atomic structures of h-BN, which can be interpreted directly or indirectly using known growth mechanisms and existing theoretical calculations. This review provides a collective understanding of the structural characteristics and defects of synthetic h-BN films and facilitates a better perspective toward the development of new and improved synthesis techniques.

S/Zn의 몰비에 따른 중적외선 투과용 ZnS 세라믹스의 소결과 광학적 특성 (Optical Properties of Mid-infrared Transparent ZnS Ceramics with Different Molar Ratio of S/Zn)

  • 여서영;박범근;김창일;백종후
    • 센서학회지
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    • 제28권4호
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    • pp.256-261
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    • 2019
  • In this study, mid-infrared transparent zinc sulfide (ZnS) ceramics were fabricated through hydrothermal synthesis with different molar ratios of S/Zn (S/Zn = 0.8, 1.0, 1.2, 1.4, and 1.6). The ZnS ceramics were sintered at a relatively low temperature of $850^{\circ}C$ to prevent the occurrence of the hexagonal phase featuring optical anisotropy. The phase composition, microstructure, and optical properties of the ZnS ceramics were subsequently investigated by employing X-ray diffraction, scanning electron microscopy, and Fouriertransform infrared spectroscopy. The results obtained indicate that the ZnS nanoparticles feature the cubic phase, without the hexagonal phase. Moreover, with increasing S, the crystallinity and particle size of the ZnS nanoparticles increased. The crystallinity and density of the ZnS ceramics improved when the molar ratio of S was higher than the molar ratio of Zn, thereby enhancing the transmittance. Furthermore, the ZnS ceramic with an S/Zn value of 1.2 was found to exhibit the highest transmittance of approximately 69% owing to the reduced occurrence of the hexagonal phase and a high density of 99.8%.

인발성형 시스템 고도화를 위한 특수합금 육각봉의 압연특성 비교 해석 연구 (Comparative Study on Rolling Characteristics of Hexagonal Bar with Special Alloy for Advancing Drawing System)

  • 이영식;양영준
    • 한국기계가공학회지
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    • 제20권5호
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    • pp.96-102
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    • 2021
  • Hexagonal bolt, nut, fittings, and high-pressure valves with special alloy play an important role in many industrial products. Numerical analysis was conducted to obtain data for designing a new drawing system. This study aims to predict the rolling force of the new drawing system compared to that of the established drawing system. The rolling force of the new drawing system was predicted using numerical analysis by assuming that it is in proportion to deformation. The rolling forces of Mo, Ti, and W were approximately 1.4, 0.5, and 2.5 times those of SUS. Because the values of ultimate strength of special alloys were more close to numerical analysis, the values of ultimate strength could be used to predict the rolling force of the new drawing system without numerical analysis in field.

Steel hexagonal damper-brace system for efficient seismic protection of structures

  • Mohammad Mahdi, Javidan;Jinkoo, Kim
    • Steel and Composite Structures
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    • 제45권5호
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    • pp.683-695
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    • 2022
  • Conventional braces are often used to provide stiffness to structures; however due to buckling they cannot be used as seismic energy dissipating elements. In this study, a seismic energy dissipation device is proposed which is comprised of a bracing member and a steel hysteretic damper made of steel hexagonal plates. The hexagonal shaped designated fuse causes formation of plastic hinges under axial deformation of the brace. The main advantages of this damper compared to conventional metallic dampers and buckling-restrained braces are the stable and controlled energy dissipation capability with ease of manufacture. The mechanical behavior of the damper is formulated first and a design procedure is provided. Next, the theoretical formulation and the efficiency of the damper are verified using finite element (FE) analyses. An analytical model of the damper is established and its efficiency is further investigated by applying it to seismic retrofit of a case study structure. The seismic performance of the structure is evaluated before and after retrofit in terms of maximum interstory drift ratio, top story displacement, residual displacement, and energy dissipation of dampers. Overall, the median of maximum interstory drift ratios is reduced from 3.8% to 1.6% and the residual displacement decreased in the x-direction which corresponds to the predominant mode shape of the structure. The analysis results show that the developed damper can provide cost-effective seismic protection of structures.

Hexagon 타일 부배열 안테나 시스템 구조 최적화에 관한 연구 (A Study on Optimization of Structure for Hexagon Tile Sub-array Antenna System)

  • 정진우;표성민
    • 전기전자학회논문지
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    • 제26권1호
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    • pp.129-132
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    • 2022
  • 본 논문에서는 위상배열안테나의 부엽레벨을 최소화할 수 있는 부배열 시스템 구조의 최적화에 관한 기술을 제안하였다. 제안된 배열안테나 구조의 최적화는 6개의 육각배열을 한 개의 부배열과 육각 부배열의 육각형 배열 구조를 이용하여, 부배열의 배열간격과 부배열 사이의 배열 간격을 조절하여, 전체 위상배열안테나 시스템의 방사패턴을 최적화하였다. 제안된 기술은 2차원 평명배열안테나 시스템에 비하여, 24.3 dBi의 이득과 8.46도의 반치각은 변화없이 유지하며, 오직 x축과 y축 방향으로 각각 -3.4 dB와 -6.5 dB를 감소시켰다.

Nearly single crystal, few-layered hexagonal boron nitride films with centimeter size using reusable Ni(111)

  • Oh, Hongseok;Jo, Janghyun;Yoon, Hosang;Tchoe, Youngbin;Kim, Sung-Soo;Kim, Miyoung;Sohn, Byeong-Hyeok;Yi, Gyu-Chul
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.286-286
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    • 2016
  • Hexagonal boron nitride (hBN) is a dielectric insulator with a two-dimensional (2D) layered structure. It is an appealing substrate dielectric for many applications due to its favorable properties, such as a wide band gap energy, chemical inertness and high thermal conductivity[1]. Furthermore, its remarkable mechanical strength renders few-layered hBN a flexible and transparent substrate, ideal for next-generation electronics and optoelectronics in applications. However, the difficulty of preparing high quality large-area hBN films has hindered their widespread use. Generally, large-area hBN layers prepared by chemical vapor deposition (CVD) usually exhibit polycrystalline structures with a typical average grain size of several microns. It has been reported that grain boundaries or dislocations in hBN can degrade its electronic or mechanical properties. Accordingly, large-area single crystalline hBN layers are desired to fully realize the potential advantages of hBN in device applications. In this presentation, we report the growth and transfer of centimeter-sized, nearly single crystal hexagonal boron nitride (hBN) few-layer films using Ni(111) single crystal substrates. The hBN films were grown on Ni(111) substrates using atmospheric pressure chemical vapor deposition (APCVD). The grown films were transferred to arbitrary substrates via an electrochemical delamination technique, and remaining Ni(111) substrates were repeatedly re-used. The crystallinity of the grown films from the atomic to centimeter scale was confirmed based on transmission electron microscopy (TEM) and reflection high energy electron diffraction (RHEED). Careful study of the growth parameters was also carried out. Moreover, various characterizations confirmed that the grown films exhibited typical characteristics of hexagonal boron nitride layers over the entire area. Our results suggest that hBN can be widely used in various applications where large-area, high quality, and single crystalline 2D insulating layers are required.

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혼합 소스 HVPE 방법에 의한 4H-SiC 기판 위의 육각형 Si 에피층 성장 (Growth of hexagonal Si epilayer on 4H-SiC substrate by mixed-source HVPE method)

  • 김경화;박선우;문수현;안형수;이재학;양민;전영태;이삼녕;이원재;구상모;김석환
    • 한국결정성장학회지
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    • 제33권2호
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    • pp.45-53
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    • 2023
  • 4H-SiC 기판 위의 Si 성장은 전력 반도체, 바이폴라 접합 트랜지스터 및 광전자 공학에서 매우 유용한 재료로서 광범위한 응용 분야를 가지고 있다. 그러나 Si와 4H-SiC 사이에 약 20 %의 격자 불일치로 인해 4H-SiC에서 매우 양질의 결정 Si를 성장시키는 것은 상당히 어렵다. 본 논문에서는 혼합 소스 수소화물 기상 에피택시 방법을 이용하여 4H-SiC 기판에서 성장한 Al 관련 나노 구조체 클러스터에 의한 육각형 Si 에피층의 성장을 보고한다. 4H-SiC 기판 위에 육각형 Si 에피층을 성장시키기 위해 먼저 Al 관련 나노 구조체 클러스터가 형성되고 Si 원자를 흡수하여 육각형 Si 에피층이 형성되는 과정을 관찰하였다. Al 관련 나노 구조체 클러스터와 육각형 Si 에피층에 대하여 FE-SEM 및 라만 스펙트럼 결과로부터 육각형 Si 에피층은 일반적인 입방정계 Si 구조와 다른 특성을 가지는 것으로 판단된다.