• 한국가시화정보학회지
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• 제13권3호
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• pp.20-23
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• 2015

In this experiment, a heterogeneous droplet consisted of de-ionized water and olive oil was made through two 31G injection needles. The injection flow rate was $50{\mu}{\ell}/min$ and the droplet size was 2 mm. The droplet was impinged onto a sapphire plate which was heated up to $300^{\circ}C$ by a heater. Two high speed cameras were used for visualization, and the frame rate was 20,000 fps. A 150W metal halite lamp was used for illumination. The dropping height was fixed to 20 mm and the corresponding Weber number was 10.6 based on water. Due to different boiling points of two liquids, partial boiling features of heterogeneous droplet was observed. At the Leidenfrost condition, micro explosion phenomenon has occurred.

• 한국결정학회지
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• 제5권1호
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• pp.33-38
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• 1994

Hen egg white Iysozyme과 equine serum albumin을 모델 단백질로 하여 'heterogeneous' vapor diffusion실험을 수행하였다. 즉, droplet과 reseroir용액에 각각 다른 침전제를 사용하여 vapor diffusion에 의하여 평형에 이르도록 하였다. 실험 결과는 NSI 혹은 ammonium sulfate 대신 polyethylene glycol이 reservoir 용액에 포함되므로써 droplet과 reservoir 용액 사이의 평형 속도가 감소되는 것을 보여 주었다. Heterogeneous vapor diffusion 법을 통하여 reservoir용액에 포함된 이온성 염과 비이온성 침전제의 양을 적절히 조절하여 평형속도를 조절할 수 있음을 보였다.

• 대한기계학회논문집B
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• 제22권6호
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• pp.813-822
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• 1998

The microexplosion of a slurry droplet was considered to be caused by the shell formation and the following pressure build-up in the shell which would be promoted by the suppression of evaporation, subsequent superheating and heterogeneous nucleation of liquid carrier. To closely investigate the pressure build-up and the heterogeneous nucleation, a numerical model was introduced by considering the internal temperature distributions with the shell formation, suppression of evaporation and pressure build-up inside. The microexplosion time was estimated by postulating the limit of superheat for heterogeneous nucleation. The simulation yielded a reasonably good agreement with experimental results for Al/n-heptane slurry droplets under various solid loadings.

• 한국분말재료학회지
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• 제1권1호
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• pp.85-94
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• 1994

In order to predict droplet velocity and temperature profiles and fractional solidification with flight distance during spray forming, the Newtonian heat transfer formulation has been coupled with the classical heterogeneous nucleation and the specific solidification process. It has been demonstrated that the thermal profile of the droplet in flight is significantly affected by process parameters such as droplet size, initial gas velocity, undercooling. As the droplet size and/or the initial gas velocity increase, the onset and completion of solidification are shifted to greater flight distances and the solidification process also extends over a wider range of flight distances. The amounts of solid fractions formed during recoalescence, segregated solidification and eutectic solidification are insensitive to droplet size and initial gas velocity whereas those are strongly affected by the degree of undercooling. There are good linear relations between the undercooling and the corresponding solid fractions generated during recoalesced, segregated and eutectic stages.

• 대한기계학회논문집B
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• 제21권12호
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• pp.1576-1585
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• 1997

The microexplosive combustion of a slurry droplet was investigated experimentally. The microexplosion has been approximately considered to be caused by pressure build-up in the shell and to be promoted by heterogeneous nucleation of liquid carrier, which is due to the suppression of evaporation and subsequent superheating of liquid carrier. To closely investigate the pressure build-up and the heterogeneous nucleation, the experiments were conducted in an electric combustor, of which temperature was controllable (400 K-900 K). And the effects of two aligned droplets on the interactive combustion and microexplosion were found in a hot post region of a flat flame burner. Transient internal temperature distributions for slurry droplets were measured. And the shell formation and the microexplosion of suspended A1/JP-8 and Al/n-heptane slurry droplets were examined with various surfactant concentrations (0.5-5 wt%) and solid loadings (10-50 wt.%). The microexplosion time of binary array of droplets was found to be less than that of the isolated droplet due to radiative interaction between droplets.

• 대한기계학회논문집B
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• 제38권3호
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• pp.263-270
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• 2014

유체이송 기술은 최근 마이크로 유체시스템 개발에서 핵심문제로 인식되고 있다. 본 논문에서는 외부동력을 사용하지 않고 액적을 이송시킬 수 있는 새로운 개념을 제안하고, 수치해석을 통해 증명하였다. 제안된 장치는 표면을 단순하게 친수성과 소수성 표면의 복합표면으로 구성하는 것이다. 새로운 개념을 입증하기 위한 수치해석은 보존적인 압력기반 유한체적방법에 기초한 비정렬 셀 중심 방법 및 VOF 방법에 체적포착법인 CICSAM을 채용하고 있는 자체개발 코드(PowerCFD)를 사용하였다. 연구결과 본 연구에서 제안된 개념이 마이크로 유체시스템에서 액적이송에 대해 우수한 성능을 나타내는 것으로 확인되었다.

• 대한기계학회논문집
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• 제18권9호
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• pp.2404-2412
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• 1994

A mathematical model has been developed for predicting kinematic, thermal, and solidification histories of atomized droplets during flight. Liquid droplet convective cooling, recalescence, equilibrium-state solidification, and solid-phase cooling were taken into account in the analysis of the solidification process. The spherical shell model was adopted where the heterogeneous nucleation is initiated from the whole surface of a droplet. The growth rate of the solid-liquid interface was determined from the theory of crystal growth kinetics with undercooling caused by the rapid solidification. The solid fraction after recalescence was obtained by using the integral method. The thermal responses of atomized droplets to gas velocity, particle size variation, and degree of undercooling were investigated through the parametric studies. It is possible to evaluate the solid fraction of the droplet according to flight distance and time in terms of a dimensionless parameter derived from the overall energy balance of the system. It is also found that the solid fraction at the end of recalescence is not dependent on the droplet size and nozzle exit velocity but on the degree of subcooling.

• Korean Chemical Engineering Research
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• 제50권6호
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• pp.1021-1026
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• 2012

단일 액적 시스템에서의 비정상상태 물질 전달에 대한 연구를 진행하였다. 단일 액적계를 위한 이성분계로는 옥탄올(연속상)-물(분산상) 시스템이 이용되었으며 동반되는 불균일 반응으로는 아민추출제(tri-n-octylamine,TOA)를 이용한 숙신산 추출 반응을 모델 시스템으로 선정하였다. 점도, 밀도, 용질의 분배계수, 연속상에서 하강하는 액적의 종말 속도, 용질과 추출제의 확산계수 등과 같은 시스템의 기본 특성을 파악하기 위한 실험과 이론적 계산들이 수행되었다. 액적의 종말 속도는 숙신산 농도에는 크게 영향을 받지 않는 것으로 보이나 TOA가 없을 때는 숙신산 농도에 따라 약간 증가하는 경향을 보였고, TOA 농도 증가와 함께 감소하였다. 액적의 낙하는 수직 낙하 경로를 기준으로 좌우로 진동하면서 움직이는 경향을 보였다. 낙하하는 액적에서의 물질 전달 관찰을 위해 물질 전달 셀을 제작하여 시간에 따른 액적 내의 평균 농도 변화를 관찰하였고, 그 결과를 무차원 변수를 이용하여 해석하였다. 50 g/L의 숙신산 농도 조건하에서 TOA 농도를 0.1과 0.5 mol/kg 으로 조절하였을 때, 전자의 경우에는 관찰 시간 범위 내에서 일정한 Sh 값을 유지하여 용질의 이동 방향으로의 농도 기울기가 감소함에 따라 훌럭스도 그에 비례하여 감소함을 알 수 있었지만, 후자의 경우에는 시간의 경과와 함께 Sh가 급격히 증가하는 현상을 보여 계면에서의 숙신산 훌럭스 감소에 비해 농도기울기 감소가 상대적으로 빠르게 일어남을 알 수 있다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.361.2-361.2
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• 2016

The manufacture of organic electronic circuits requires effective heterogeneous integration of different nanoscale organic materials with uniform morphology and crystallinity in a desired arrangement on a substrate. Herein, we present a new direct printing method, which enables monolithic integration of crystalline nanowire arrays with a diverse range of organic materials. In this method, we use a nanoscale patterned soft mold, which contains an assembly of simple nanoline patterns but, in combination with droplet of various organic inks, can produce a large-scale integration of various nanopatterns with multiple kinds of organic materials. The morphology of organic nanowires can controlled by nanoconfinement in nanoline of mold. And mutual alignment of nanopatterns can be controlled by adjusting the ink droplet size, number of droplets, ink deposition locations.

• 한국자원식물학회:학술대회논문집
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• 한국자원식물학회 2010년도 정기총회 및 춘계학술발표회
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• pp.12-12
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• 2010

We developed droplet-vitrification protocol, a combination of droplet-freezing and solution-based vitrification, and applied to germplasm collections of garlic, potato, lily as well as cell lines, including hairy roots, somatic embryos. To establish a garlic cryobank, four Korean garlic field collections at Danyang, Suwon, Mokpo and Namhae were cryopreserved last five years. The protocol applied consisted of preculture for 3-4 days at $10^{\circ}C$ on solid MS medium with 0.3M sucrose, loading for 40 min in liquid medium with 35% PVS3, dehydration with PVS3 for 150 min, cooling in $5{\mu}l$ droplets of PVS3 placed on aluminum foil strips by dipping these strips in liquid nitrogen, warming them by plunging the foil strips into pre-heated($40^{\circ}C$) 0.8M sucrose solution for 30s. A total of over 900 accessions of garlic were stored in liquid nitrogen for long-term conservation using unripe inflorescences, cloves or bulbils. Twelve alternative plant vitrification solutions were designed by modifying cryoprotectant concentrations from the original PVS2 and PVS3. The results suggest that PVS2-based vitrification solutions with increased glycerol and sucrose and/or decreased DMSO and EG concentrations can be applied for medium size explants which are tolerant to chemical toxicity and moderately sensitive to osmotic stress. PVS3 and variants can be used widely when samples are heterogeneous, of large size and/or very sensitive to chemical toxicity and tolerant to osmotic stress.