• Title/Summary/Keyword: Heterogeneous Soil

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계면활성제를 이용한 불균질 매질에서 유기오염물(NAPL)의 정화효율에 관한 실험 (Study of Surfactant Enhanced Remediation Methods for Organic Pollutant(NAPL) Distributed over the Heterogeneous Medium)

  • 서형기;이민희;정상용
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제6권4호
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    • pp.51-59
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    • 2001
  • 불균질 매질 내 분포하는 비 수용성 유기오염물(NAPL; non-aqueous phase liquid)을 계면활성제를 이용한 원위치 정화 방법으로 정화하는 칼럼 및 박스실험을 실시하였다. Ottawa 모래를 이용한 균질 칼럼실험을 통하여 NAPL에 대한 계면활성제용액의 정화 효율 증가를 검증하였고, 실제 오염지역의 토양을 이용한 칼럼실험을 통하여 불균질 토양에서의 정화 효율을 측정하였으며, 불균질 층리 구조와 단층구조를 모형화한 2차원 박스를 사용한 NAPL 정화 실험을 통하여 불균질 매질에서의 정화 효율을 규명하였다. LNAPL 오염원으로 o-xylene이, DNAPL 오염원으로 PCE(tetrachloroethylene)가 이용되었고, 계면활성제로는 비이온성 올리에마이드(oleamide)가, 매질로는 유류로 오염된 오염지역으로부터 채취한 실제토양과 Ottawa 모래가 실험에 사용되었다. 1% 계면활성제용액과 증류수를 주입하여 NAPL을 세정하였고 가스크로마토그래피(GC)를 이용하여 NAPL의 농도를 분석하였다. 균질 Ottawa 모래충진 칼럼의 경우 계면활성제를 주입할 경우가 증류수를 주입할 때보다 o-xylene의 최대유출농도가 약 460배, 불균질 토양의 경우 약 250배, 불균질 층상구조에서는 약 150배 증가를 나타내었다. 불균질 매질에서 계면활성제를 이용한 세정법(flushing method)으로 NAPL을 정화시, 균질 매질에서의 정화 효과보다는 정화 효율이 감소하나, 여전히 증류수만을 이용한 세정방법보다 훨씬 높은 정화 효과를 보이며, 빠른 시간 내에 NAPL이 정화되었음을 확인하였다. 본 실험을 통하여, 불균질 매질에서의 계면활성제를 이용한 토양세정방법의 효율성이 정량화 되었으며, 계면활성제를 이용한 채수주입법의 현장 적용가능성을 확인하였다.산이온의 탄소의 $\delta$$^{13}$C(PDB)값은 -6.2~0.0$\textperthousand$범위이며, 그 기원은 대수층인 지층내 탄산염암 또는 탄산염 광물의 용해에서 유래한 무기기원 탄소로 해석된다.다.으로 변화하였으며 치료 전에 반응하지 않던 항원에 새롭게 반응하는 항체가 나타나는 경우는 드물었다.ms of chlorophyll-a concentration estimation, however, the accuracy stays very similar compared to that of the CZCS-type algorithm. This is considered to be due to the nature of in-water algorithm which relies on spectral ratio of water-leaving radiances.ethanol의 혈중농도(血中濃度)가 높을수록 더 심(甚)한 혈압강하작용(血壓降下作用)을 나타내며, ethanol 로 인(因)한 이뇨작용(利尿作用)도 ethanol 량(量)이 증가(增加)함에 따라 뇨량(尿量)도 증가(增加)함을 보여 주었다.ults showed that the overall quality of Sullungtang significantly decreased as the parity increased for Hanwoo cows. The Sullungtang extracted from bones of heifer had the best sensory scores as well as nutritional quality when compared to those extracted from the cows with parity. Therefore,

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MASW FOR QUANTIFYING CHANGE IN SHEAR WAVE VELOCITY AFTER DEEP DYNAMIC COMPACTION AT A SOIL SITE

  • ChoonB.Park;RichardD.Miller
    • 지구물리
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    • 제6권4호
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    • pp.245-259
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    • 2003
  • Two multichannel analysis of surface wave (MASW) surveys were conducted over a soil site in Tacoma Water's Green River Facility, Washington, where construction of a chemical treatment facility had been planned. The purpose of the surveys was to compare soil stiffness characterized by shear-velocity (Vs) distribution before and after Deep Dynamic Compaction (DDC) operation that was designed to improve the soil stiffness. Site soil consisted of very heterogeneous gravel and cobbles in a sand-and-silt matrix. Results from each survey are represented by two 2-D Vs maps delineating Vs variation of soil below the surveyed lines. One map was constructed from those dispersion curves that were analyzed with a significant amount of subjective judgment involved, whereas the other map was constructed from those dispersion curves analyzed with as much objective information as possible. Comparison of 2-D Vs maps indicates that Vs actually decreased after the DDC operations, possibly due to the loss (or reduction) of cohesive bonding between soil particles caused by the compaction operations.

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하천 바닥 퇴적층의 투수성시험과 누수계수 추정

  • 하규철;고동찬
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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    • pp.371-374
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    • 2006
  • To quantify the hydraulic connection between river and aquifer, riverbed leakance values are required to be estimated. Silt, clay, and organic materials are often deposited in rivers resulting in the streambed having a lower hydraulic conductivity than the underlying alluvial aquifer The riverbed hydraulic conductivities are measured through vertical and oblique permeameter test. Anisotropic and heterogeneous properties of riverbed hydraulic conductivity were identified. Grain size analysis and flood wave response technique were checked along with the permeameter test for the riverbed hydraulic conductivity.

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제주도 화산회사인의 특성 및 생성에 관한 연구. I. 이화학 및 형태학적 특성 (Composition and Genesis of Volcanic Ash Soils in Jeju Island I. Physico-Chemical and Macro-Micromorphological Properties)

  • 신제성
    • 한국광물학회지
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    • 제1권1호
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    • pp.32-39
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    • 1988
  • The effect of soil forming factors on the pedogenesis of basaltic volcanic ash soils and the influence of allophane material on soil properties have been investigated on 5 chronosequence soils situated from at the near sea coast up to the foot slope of Mt. Halla in Jeju Island. Time seems to be the important soil forming factor which today differentiates soil of the Island. Songag and Donghong soils developed in lower elevations are older and somewhat less influenced by ash shower. However, soils developed at higher elevations, Pyeongdae and Heugag, are rather younger and strongly influence by the ash. It is also proved that the parent materials are very heterogeneous. They mainly are basaltic with some contamination of acidic volcanic ashes and continental aeolian deposits where a considerable amount of quartz encountered in most soils studied. Many physico-chemical properties of soil, such NaF pH, phosphate sorption power, pH and extractable acidity are parameters to differentiate andepts and non-andeptic soils.

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과황산나트륨과 제일철 촉매를 이용한 나프탈렌 산화 시 토양이 미치는 영향 평가 (Effect of the Presence of Soil on the Ferrous Catalyzed Sodium Persulfate Oxidation of Naphthalene)

  • 한대성;윤여복;고석오
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제15권1호
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    • pp.29-38
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    • 2010
  • Batch tests were carried out to examine the influence of the presence of soil and Fe(II) sorption capacity of soil on the ferrous catalyzed sodium persulfate oxidation for the destruction of organic pollutants in the application of in-situ chemical oxidation. Laboratory column tests were also conducted to investigate the transport of oxidant and catalyst in contaminated groundwater. Test results proved that Fe(II) was adsorbed on soil surface, and thus soil behaved as a heterogeneous catalyst, enhancing the naphthalene removal rate up to 50%. Column tests that were conducted with and without dissolved Fe(II) showed that naphthalene removal ratio were 24% and 25%, respectively. The removal efficiency was not enhanced with dissolved Fe(II), since the dissolved Fe(II) flew out of the column as the oxidant progressively injected into the column saturated with Fe(II). It indicates that the injected oxidant could not interact with dissolved Fe(II). But target organic pollutant was degraded in soil column system, implying that sulfate radical was produced by the reaction of dissolved persulfate with Fe(II) adsorbed on soil.

중진지역 건축물의 묻힌온통기초에 작용하는 토압과 말 뚝변위에 대한 지진해석 (Seismic Analyses of Soil Pressure against Embedded Mat Foundation and Pile Displacements for a Building in Moderate Seismic Area)

  • 김용석
    • 한국지진공학회논문집
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    • 제21권1호
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    • pp.69-76
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    • 2017
  • Seismic analyses of a pile under a large rigid basement foundation embedded in the homogeneous soil layer were performed practically by a response displacement method assuming a sinusoidal wave form. However, it is hard to take into account the characteristics of a large mat foundation and a heterogeneous soil layer with the response displacement method. The response displacement method is relevant to the 2D problems for longitudinal structures such as tunnel, underground cave structure, etc., but might not be relevant with isolated foundations for building structures. In this study, seismic pile analysis by a pseudo 3D finite element method was carried out to compare numerical results with results of the response displacement method considering 3D characteristics of a foundation-soil system which is important for the building foundation analyses. Study results show that seismic analyses results of a response displacement method are similar to those of a pseudo 3D numerical method for stiff and dense soil layers, but they are too conservative for a soft soil layer inducing large soil pressures on the foundation wall and large pile displacements due to ignored foundation rigidity and resistance.

이중 반응기 조건 및 비균일계 조건에서의 초음파 에너지 및 화학적 효과 평가 (Estimation of Ultrasonic Energy and Sonochemical Effects in Double-Bath-Type Systems and Heterogeneous Systems)

  • 이현재;손영규
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제22권5호
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    • pp.40-47
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    • 2017
  • The effects of ultrasound in heterogeneous system were investigated in three kinds of ultrasonic systems including a bath-type system (System #1), a double-bath-type system (System #2), and a double-bath-type system partly filled with glass beads (System #3). The ultrasound energy and its attenuation were quantified using calorimetry and the sound pressure measurement method. The sonochemical effects mainly involved in radical oxidation reactions were quantified using KI dosimetry. It was found that ultrasound energy was significantly attenuated in System #2 and #3 due to the presence of solid materials such as a submerged stainless steel reactor and glass beads. However, in spite of low ultrasound energy status, sonochemical oxidation reactions occurred more violently due to the presence of glass beads in System #3. In addition, calorimetry was more adequate to estimate the total energy status of ultrasound in sonoreactors compared to the sound pressure measurement method.

토양 세정법을 이용한 실제 유류 오염 토양 및 지하수 정화

  • 강현민;이민희;정상용;강동환
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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    • pp.418-421
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    • 2003
  • Surfactant enhanced in-situ soil flushing was peformed to remediate the soil and groundwater at an oil contaminated site, and the effluent solution was treated by the chemical treatment process including DAF(Dissolved Air Flotation). A section from the contaminated site(4.5m$\times$4.5m$\times$6.0m) was selected for the research, which was composed of heterogeneous sandy and silt-sandy soils with average Hydraulic conductivity of 2.0$\times$10$^{-4}$ cm/sec. Two percent of sorbitan monooleate(POE 20) and 0.07% of iso-prophyl alcohol were mixed for the surfactant solution and 3 pore volumes of surfactant solution were injected to remove oil from the contaminant section. Four injection wells and two extraction wells were built in the section to flush surfactant solution. Water samples taken from extraction wells and the storage tank were analyzed by GC(gas-chromatography) for TPH concentration with different time. Five pore volumes of solution were extracted while TPH concentration in soil and groundwater at the section were below the Waste Water Discharge Limit(WWDL). Total 18.5kg of oil (TPH) was removed from the section. The concentration of heavy metals in the effluent solution also increased with the increase of TPH concentration, suggesting that the surfactant enhanced in-situ flushing be available to remove not only oil but heavy metals from contaminated sites. Results suggest that in-situ soil flushing and chemical treatment process including DAF could be a successful process to remediate contaminated sites distributed in Korea.

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Investigation of Spudcan Penetration Resistance in Layered Soil Deposits

  • Jan, Muhammad Asad;Nizamani, Zubair Ahmed;Park, Duhee
    • 한국지반환경공학회 논문집
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    • 제22권1호
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    • pp.13-20
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    • 2021
  • A suite of 3D large deformation finite element (FE) analyses was performed to investigate the load transfer mechanism and penetration resistance of spudcan foundations in heterogeneous soil profile consisting of sand and clay. The Elasto-Plastic models following Mohr-Coulomb and Tresca failure criteria were adopted for sand and clay, respectively. The accuracy of the numerical model was validated against centrifuge test measurements. The dense sand behavior with dilation is modeled using the non-associated flow rule. An investigation study consisting of key parameters, which includes variation in soil stratigraphy (sand-clay, sand-clay-sand), strength parameters of sand and clay (��' and su) and normalized height ratio of the sand layer (Hs/D) was conducted to assess the penetration behavior of spudcan. Based on calculated outputs, it was demonstrated that these parameters have a significant influence on the penetration resistance of spudcan. The calculated penetration resistance profiles are compared with the published (sand overlying clay) analytical model. It is confirmed that for the case of two-layer soil, the available theoretical model provides an accurate estimate of peak penetration resistance (qpeak). In the case of three-layer soil, the presence of a third stiff layer affects the penetration resistance profile due to the squeezing of the soil.

방조제 이질층의 투수성이 제체 침투에 미치는 영향에 대한 모의 분석 (Simulation of Effects of Permeability on Seepage between Two Heterogeneous Layers of Sea-dike)

  • 이행우;장병욱;손영환;김성필
    • 한국농공학회논문집
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    • 제48권6호
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    • pp.79-85
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    • 2006
  • A simulation was done to analyze the seepage problems due to seawater intrusion through the embedded rock layers on heterogeneous layers of sea-dike. Numerical analysis with SAMTLE(developed by author) was done by taking various relative permeability $ratio(R_r/R_e)$. These results showed, when the sed-dike is newly designed, operated, and maintained considering the safety of sea-dike in seepage problems, these embankment materials are prudently chosen. The permeability of the soil materials, within the range of salinity management in freshwater, is comparatively high, however, the permeability of rock materials for bottom rock layer is low. Therefore, when the relative permeability $ratio(R_r/R_e)$ is bellow 10 it is safety in seepage problems of sea-dike.