• Title/Summary/Keyword: Heavy metal effects

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A Clinical Experience of Dermatitis suspected Chronic Arsenic Intoxication (만성 비소 중독으로 의심되는 피부염 치험 1례)

  • Kang, Byung-Soo;Choi, Jeong-Hwa;Park, Soo-Yeon;Jung, Min-Yeong;Kim, Jong-Han
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.30 no.3
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    • pp.201-210
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    • 2017
  • Objectives : To report the patient suspected chronic arsenic intoxication after Korean medicine treatment. Methods : One patient with highly suspected chronic arsenic intoxication was selected. He was suspected to be chronic arsenic intoxication because symptoms and hair heavy metals test. Acupuncture was applied for twice a day and herbal medicine(Pyeonghyeol-eum) was administered in 28 days. Evaluation method applied to xeroderma, pruritus, psoriasis were overall dry skin score(ODS), visual analogue scale(VAS), pruritus grading system(PGS). Results : Pyeonghyeol-eum, acupuncture and the other Korean medicine treatments improved xeroderma, pruritis, psoriasis after 28 days of treatment. ODS decreased from 3 to 2. VAS of Pruritus decreased from 8 to 1. PGS decreased from 15 to 4. Adverse effects were not reported. Conclusions : This study shows that the Korean medicine treatment was effective in impoving symptoms of chronic arsenic intoxication. But the additional study will be conducted for revealing dermatitis caused by chronic arsenic intoxication.

Quilitative certificational plan of mudanpi (목단피(牧丹皮)의 품질인증(品質認證) 방안(方案))

  • Lim, Joong-Keun;Roh, Seong-Soo;Kil, Ki-Jeong;Seo, Bu-il;Seo, Young-Bae
    • Journal of Haehwa Medicine
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    • v.13 no.2
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    • pp.169-178
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    • 2004
  • Now many sustitution and false articles is used in korea instead of mudanpi. To use mudanpi correctly, we will make a quilitative certificational plan of mudanpi to investigate all of lieraturea, records and documents. And we could reach conclusions as folloews. 1. Source Source of mudanpi is cortex of Paeonia suffruticosa Andrews(Family:Ranunculaceae) in korea and china. It needs an attention to distinguish into because there is a substitute and a rank in china. 2. process We have to work before harvesting fresh roots is dry perfectly. If outer skin dried moisture a little, cut off outer skin vertically at sunny day, remove a heart and sever, immedietly dry. When working, we have to take care of because of easy discoloration with moisture. 3. Quality (1) Functional standards A diameter is large, it do not exist a heart of wood, a bark is thick and powdery. Section surface is light white color and rich odor with many light crystals. (2) Physicochemical stamdards We think that it needs to raise a contant of paeonol at all kinds of testing standards. A contant of paeonol is at least more than 2.5%. A part of wood indicate a heart of wood which has no medical effects, but is a relatively heavy part. So a standart of wood must be lowered sifnificantly less than 1.0%. It must be content of ash is less than 6.0%, Content of acid-nonsoluble ash is less than 1.0%. A fixed quantity of paeonol is more than 2.5%. Contens of heavy metal has to detect less than 30 ppm and there is no reminding agriculural medince.

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A Study on Co-precipitation of Indium Hydroxide (In(OH)3) for the Recovery and Determination of Trace Heavy Metals (인듐 수산화물(In(OH)3)의 공동침전을 이용한 미량의 중금속 회수 및 분석방법 연구)

  • Kwon, Seul-woo;Son, Seong-Hun;Lee, Man Seung;Nam, Sang-Ho
    • Resources Recycling
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    • v.26 no.4
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    • pp.50-55
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    • 2017
  • Determination of trace elements in a sample including complicated matrix is very difficult due to the interference by the matrix. Therefore, if the trace elements can be separated from the complex sample matrix and determined, the interference effects can be reduced, and it is very helpful for the overall analysis. In this study, the analytes of trace elements were separated from the sample matrix by co-precipitation with trace elements using indium hydroxide ($In(OH)_3$), then detected by inductively coupled plasma-atomic emission spectrometer (ICP-AES). Above all, the optimal conditions for the co-precipitation of elements with indium hydroxide were experimentally established. At last, salt was analyzed by the developed analytical method. No heavy metals were not found in Shinan Jeungdo salt, but trace amounts of several heavy metals except for cadmium were found in Cheonnam Yongkwang salt.

The Effects of pH Control on the Leaching Behavior of Heavy Metals within Tailings and Contaminated Soils : Seobo and Cheongyang Tungsten Mine Areas (광미와 오염토양 내 중금속 용출특성에 미치는 pH영향 : 청양과 서보중석광산)

  • 이평구;강민주;박성원;염승준
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.469-480
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    • 2003
  • Laboratory leaching experiment study carried out to estimate a extent of heavy metals that could be leached out when acid rain(pH 5.0-3.0) and strong acidic solution(pH 2.5-1.0) reacted with tailings and contaminated soils from abandoned metal mines. In slightly to moderately acid conditions(pH 5.0-3.0), As, Pb and Zn dissolutions became significantly increased with decreased pH in tailing, while dissolution of these elements was very limited in contaminated soil. These results suggested that moderately acid rainwater leaches Pb, As and Zn from the tailings, while these elements would remain fixed in contaminated soil. In the pH range of 2.5-1.0(strongly acid condition), Zn, Cd and Cu concentrations of leachate rapidly increased with decreased pH in contaminated soil, while Pb, As and Co dissolutions became importantly increased in tailings. The experimental solubility of Zn. Cd and Cu was very low even at very low pH values(up to pH 1), except for CY4(Cheongyang mine). These can result from an incomplete dissolution or the presence of less soluble mineral phases. So, the solubility of heavy metals depends not only on the pH values of leachate but also on the speciation of metals associated with contaminated soils and tailings. The relative mobility of each element within failings at the pH 5.0-3.0 of the reaction solution was in the order of Pb>Zn>Cd>Co=Cu>As. In case of pH 2.5-1.0 of the reaction solution, the relative mobility of each element within contaminated soils and tailings were in the order of Zn>Cd>Cu>Co>Pb=As for contaminated soils, and Pb>Zn>Cd>hs>Co>Cu for tailings. The obtained results could be useful for assessing the environmental effects and setting up the restoration plan in the areas.

Effects of High Current and Welding Wire Diameter on the Magnesium Vaporization and Mechanical Properties of Al5083 Arc Welds (대전류 및 용가재 직경에 따른 Al5083 아크 용접부 마그네슘 기화 및 기계적 성질)

  • Kwon, Heimi;Park, Chul-Ho;Hong, In-Pyo;Kang, Namhyun
    • Journal of Welding and Joining
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    • v.31 no.6
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    • pp.84-89
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    • 2013
  • The demand of LNG tank and the constituting material, i.e., the Al5083 thick plate, increased due to the rapid growth LNG market. To weld the Al5083 thick plate, the gas metal arc welding (GMAW) of high current is necessary to increase manufacturing productivity incurred by the multi pass welding. However, the arc welding vaporizes the volatile element such as magnesium (Mg). This phenomenon changes the Mg composition of the weld metal and the mechanical properties. The study investigated the weldability of Al5083 alloys after conducting high current GMAW. The Al5083 alloy was welded by using different size of welding wires and high current (800-950A). As the arc current increased from 800A to 950A, the mechanical strength decreased and the secondary dendrite arm spacing (SDAS) increased. Even though the arc current increased SDAS, the mechanical strength decreased due to the Mg loss in the weldment. The large diameter of welding wire decreased the dilution of the weld, therefore increasing the Mg content and the strength of the weld. For the reason, the content of Mg in welds was a major parameter to determine the mechanical property for the high current GMAW. For the arc current between 800A and 950A, the yield strength of the weldments showed a relationship with the weight percent of Mg content ($X_{Mg}$): Y.S = 27.9($X_{Mg}$)-11.

Bioassessment of Heavy Metals, Nanoparticles, and Soils Contaminated with Metals using Various Bioassays (다양한 독성법을 이용한 중금속, 나노입자 및 금속오염 토양 평가)

  • Kong, In Chul;Shi, Yu Tal;Lee, Min Kyung;Kang, Il Mo
    • Economic and Environmental Geology
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    • v.48 no.3
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    • pp.261-271
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    • 2015
  • Toxicity results of metals, nanoparticles (NPs), and soils contaminated with metals were introduced on this review. Following methods were used: seed germination, bioluminescence, enzyme activity, and mutation. In general, different sensitivities were observed, depending on types of bioassays and pollutants. Among tested seeds, sensitivities of Lactucus and Raphanus were greater than others. Of single metal exposure, effect by As(III) was greater than others, and high revertant mutation ratio (5.1) was observed at 1 mg/L arsenite, indicating high mutagenicity. No general pattern was observed on the effect of metal mixture, but synergistic effect was observed with seeds. In case of soils, no correlation was observed between total metal contents and toxicity. Toxicity of NPs was observed as follows: CuO > ZnO > NiO > $TiO_2$, $Fe_2O_3$, $Co_3O_4$. Especially, no considerable effects were observed by $TiO_2$, $Fe_2O_3$, and $Co_3O_4$ under tested concentration (max. 1,000 mg/L). The evaluation results of interactive toxic effects using various bioassays may comprise a useful tool for the bioassessment of various environmental pollutants.

Effects of Lime and Humic Acid on the Cadmium Availability and its Uptake by Rice in Paddy Soils (논토양중 카드뮴 유효도와 수도의 흡수이행에 미치는 석회 및 Humic acid 시용효과)

  • Kim, Min-Kyeong;Kim, Won-Il;Jung, Goo-Bok;Park, Kwang-Lai;Yun, Sun-Gang;Eom, Ki-Cheol
    • Korean Journal of Environmental Agriculture
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    • v.23 no.1
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    • pp.28-33
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    • 2004
  • This study was conducted to how the effect of lime and humic acid on cadmium availability and ie uptake by plant grown in contaminated paddy soils with heavy metal. The treatment levels of lime were 2.5 and 5.0 ton/ha and that of humic acid were 1 and 2%. The contents of 0.1N HCl extractable Cd were reduced with lime and humic acid and were negatively correlated with CEC as well as soil pH. The sequential extraction procedure was used to fractionate the heavy metals in soils into the designated from exchangeable (0.5 M $KNO_3$) water soluble ($H_2O$), organically bound (0.5 M NaOH), carbonate (0.05 M $Na_{2-}$ EDTA) and sulfide/residual (4 M $HNO_3$). In soil amended with 2.5 ton/ha lime and 1% humic acia che- mical forms of Cd at tillering stage were predominant exchangeable + water soluble extractable Cd, whereas that at harvesting stage were predominant carbonate + sulfide/residual extractable Cd. The exchangeable forms of Cd in soil with lime and humic acid were negatively correlated with soil pH during the harvesting period. Total absorbed Cd of paddy rice tended to occur in the order of root > stem > leaf > brown rice. Cd contents of brown rice with lime and humic acid treatment were 0.09 and 0.08 mg/kg, respectively. That were lower than control, 0.20 mg/kg. It could be that treatment of lime and humic acid in polluted soil by heavy metals would reduce the uptake of heavy metals by piano and be a temporary method of reclamation at the highly heavy Metal contaminated soils.

A Comparison of Electrical Stimulation for Electrodic and EDTA-Enhanced Phytoremediation of Lead using Indian Mustard (Brassica juncea)

  • Lim, Jae-Min;Jin, Biao;Butcher, David J.
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2737-2740
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    • 2012
  • The use of plants to remove toxic metals from soil (phytoremediation) is emerging as a cost-effective alternative to conventional methods for the removal of heavy metals from contaminated soil. Indian mustard (Brassica juncea) was used as the plant to accumulate high tissue concentrations of lead when grown in contaminated soil. For this study, the application of an electric field combined effectively with EDTA-enhanced phytoremediation. A stimulation of direct and alternating electric potential was compared and EDTA-enhanced phytoremediation of lead using Indian mustard has been performed. The effects of experimental parameters such as operating voltage with different concentration of EDTA, the number of graphite electrodes, and cultivation period on the removal of toxic metal were studied. Shoot lead accumulations in Indian mustard increased as the concentration of EDTA and dc electric potential was increased. Two to four folds was increased when EDTA plus a dc electric potential was applied, compared to an ac electric potential. The maximum lead accumulation in the shoots was achieved by applying EDTA plus dc electric potential with 6 graphite electrodes.

Study on the production of the ceramic by the mineral-Oriental medicine and the property of the clean active water depositting on the ceramic stone (광물성 한약재 세라믹 조성 및 세라믹 침적 청정활성수 특성에 대한 연구)

  • Kim Gyeong Cheol
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.18 no.4
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    • pp.1159-1162
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    • 2004
  • We studied on the production of the ceramic by the mineral-Oriental medicine and the property of the clean active water depositting on the ceramic stone. The results are as follows: We properly mixed of maifanshi, mica, ochre, and added to a small amount cinnabar, and therefore formed the ceramic stone. By the plasticity process and the irradiating magnetic force recovered the disappeared a part of constitutent elements. The recovered effects were become higher the freshness, maintenance, deodoriztion, clean water. As well as having the ability on capture of the notoxious heavy metal on human. The ceramic powder were mixed proper dose maifanshi, mica. And the powder had ionization, absorption, adhesion by the plasticity process and magnetic force. The clean active water of depositting on the ceramic stone during 24hours were observed significant the content of micro element, dissolved oxygen, abstraction on Herbs.

Effects of Coal Fly Ash as a Bulking Agent under Co-composting with Swine Manure and Saw Dust

  • Lee, Chang Hoon;Park, Seong Jin;Kim, Myung Sook;Yun, Sun Kang;Sonn, Yeon Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.5
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    • pp.356-361
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    • 2014
  • The coal fly ash (CFA) may be utilized as an extender for organic waste composting at the same time fully expected to solve all industrial waste disposal and sawdust tribe. The main objective in this study was to evaluate the effect of CFA addition as a bulking agent for swine manure composting. To determine the suitable addition rate of CFA as a bulking agent, 0, 10, 20 and 30% of saw dust were mixed with 30, 20, 10 and 0% of coal fly ash, respectively. Compost quality for swine manure composting was to evaluate temperature, pH, C/N ratio, and phytotoxicity as germination index. Stability of compost increased with increasing levels of CFA as bulking agent during swine manure composting due to the high alkaline materials including CFA. C to N ratio in treatment added CFA was higher than that of the control without CFA. After finishing composting, germination index of lettuce and cabbage in swine manure compost added 10% of CFA was similar to the control, all the heavy metal contents were far below the stipulated standard for organic farming. These results indicated tahr coal fly ash as bulking agents might be alternative materials to save saw dust and apply industrial products for swine manure composting.