This study was conducted to find out the analysis condition of selenium(Se) in oil refinery wastewater with a high concentration of Se using the atomic absorption spectrometry with hydride generation system (HG-AAS). From various experiments that reduced Se(VI) to Se(IV), the optimum pretreatment condition was determined to be a sample volume of 10 mL, HCl 10 mL, with a 30 min heating time in a water bath. In oil refinery wastewater, as the concentration of organics and constitution became higher, the recovery rates of Se decreased. Therefore, three acid digestion methods ($HNO_3/HClO_4$ digestion, $KMnO_4$ digestion, and microwave acid digestion) were tested on the recovery rates of Se in reference to the digestion of organics, petroleum and oxidation from organic Se(org.), Se(IV) to Se(VI). The experiment results showed that the average recovery rate of Se was the highest in microwave acid digestion, although all of the digestions were more than 90%. In consequence, the pretreatment procedure of microwave digestion followed by HCl addition was the most suitable for selenium analysis in oil refinery wastewater by using HG-AAS.
Journal of Korean Home Economics Education Association
/
v.3
no.1
/
pp.1-13
/
1991
The purpose of this study is to find out problems through looking into the actual condition of management and the extent of application in cooking practice in High School Home Economics Education, and as a practical subject, to present some basic materials to contribute to accomplishing the object of High School Home Economics Education through trying to find a direction to enhance educational value. The contents of this study are these : to study with a theoretical background character, object, and contents of Home Economics referring to related books and to investigate the actual condition of management, the extent of application to life of cooking practice unit, and standard of recognition of students and teachers about this subject and to find out rational and efficient method of management. 552 girl students and 72 home economics teachers in cities and counties in Kangwon-do were asked to answer the answer-sheet prepared. The result of this study is summerized as follows. 1. Most of the respondent regard the characters and objects of Home Economics as a matter of basic education, education for life, and education for the wholeman, but they neglect the aspect of education for a course of this subject. 2. Among the contents of Home Economics, students are much interested in the Unit of preparing table, especially in cooking. Most of the teachers teach the cooking unit with only explanation without practice because of the lack of material and human resources. 3. Students have desire to do cooking practice, but the extent of application of their real life appears to be low. 4. It appears to be necessary that boy students as well as girl students should learn Home Economics as an education for preparation for managing housework. 5. Home Economics teachers are mostly satisfied with their teaching profession. But teachers who have been teaching for 3 or 5 years appear not to be satisfied with it. 6. Although Home Economics teachers can teach Cooking practice Unit with confidence, they usually do it with theory rater than with practice, and they evaluate it after practicing, but most of them do not add the result to the student’s grade. 7. They use most of the cookers fixed on the standard list of High School Cooking Practice appliances, but they seldom use electric heating cookers.
Purpose: In protected crop production facilities such as greenhouse and plant factory, farmers should be present and/or visit frequently to the production site for maintaining optimum environmental conditions and better production, which is time and labor consuming. Monitoring of environmental condition is highly important for optimum control of the conditions, and the condition is not uniform within the facility. Objectives of the paper were to investigate spatial and vertical variability in ambient environmental variables and to provide useful information for sensing and control of the environments. Methods: Experiments were conducted in a strawberry-growing greenhouse (greenhouse 1) and a cherry tomato-growing greenhouse (greenhouse 2). Selected ambient environmental variables for experiment in greenhouse 1 were air temperature and humidity, and in greenhouse 2, they were air temperature, humidity, PPFD (Photosynthetic Photon Flux Density), and $CO_2$ concentration. Results: Considerable spatial, vertical, and temporal variability of the ambient environments were observed. In greenhouse 1, overall temperature increased from 12:00 to 14:00 and increased after that, while RH increased continuously during the experiments. Differences between the maximum and minimum temperature and RH values were greater when one of the side windows were open than those when both of the windows were closed. The location and height of the maximum and minimum measurements were also different. In greenhouse 2, differences between the maximum and minimum air temperatures at noon and sunset were greater when both windows were open. The maximum PPFD were observed at a 3-m height, close to the lighting source, and $CO_2$ concentration in the crop growing regions. Conclusions: In this study, spatial, vertical, and temporal variability of ambient crop growing conditions in greenhouses was evaluated. And also the variability was affected by operation conditions such as window opening and heating. Results of the study would provide information for optimum monitoring and control of ambient greenhouse environments.
Formaldehyde is defined as carcinogen causing leukaemia, lymphoma or nasopharyngeal carcinoma at high level of exposure. Furniture-manufacturing workers can be exposed to formaldehyde, which implies serious impact on health of the workers. The authors carried out ambient monitoring of formaldehyde in the field, and identified the source of formaldehyde generated during the working process by testing the condition in the laboratory settings. After sampling formaldehyde in the air with 2,4-DNPH (2,4-dinitrophenylhydrazine) coated silica gel, we extracted formaldehyde derivative with acetonitrile and analyzed the extract using HPLC with UV detector at 360 nm. Formaldehyde was separated by ACQUITY UPLC BEH $C_{18}$ column at a flow rate of 0.5 mL/min using 45% acetonitrile as mobile phase. The workers were exposed to higher level of formaldehyde than normal air. Formaldehyde up to 0.31 ppm was detected in the process of veneer attachment, which exceeded 0.3 ppm, the ceiling value of ACGIH standard. The laboratory test of measuring formaldehyde generated from the glue and veneer used in the attachment process resulted in more formaldehyde generation as the temperature increased, and more from the veneer. Heating the veneer to $100-150^{\circ}C$ following the real condition of the manufacturing site generated 1.14-2.70 ppm of formaldehyde from the sample, which was 2-5 times higher level than Korean limit of exposure (0.5 ppm). As the workers handling and processing the veneer which was produced by wet process had high possibility to be exposed to formaldehyde, urgent improvement and management of working environment of furniture manufacturer is demanded.
In this study, we set an optimum blanching condition as a pretreatment condition to freeze welsh onion (Allium fistulosum L.) for the purpose of preserving the cooking material for long-term usage. With higher blanching temperature and longer processing time, the Hunter color values and the hardness of welsh onion tended to decrease, which confirmed softening of the tissue. Compared to before blanching, total bacterial counts decreased to near 2 log scale, whereas coliforms were not detected or decreased to a 1-2 log scale. Blanching by heating at 100$^{\circ}C$ for 5 min decreased peroxidase inactivity to more than 94%, whereas only 47% of the inactivity was achieved at 80$^{\circ}C$ for 1 min. The sensory evaluation for the blanched and defrosted welsh onion showed that the group blanched at 80$^{\circ}C$ for 1 min was preferred significantly (p<0.05).
Reproductive cycle, the condition index, sex ratio of the Pacific oysters, Crassostrea gigas were investigated by histological and morphometric data. The specimens were collected in the two oyster farms of Geoje and Namhae, Gyeongsangnam-do, Korea, from November 1995 to October 1996. Growth of shell length in two regions was similar, but growth of total weight of the oyster in Namhae was faster than that in Geoje oyster farm. The spawning periods in female and male clams were from July to October in Geoje and from June to October in Namhae oyster farm. Ripe oocytes were approximately 50 m in diameter. The reproductive cycle of in females and males in Geoje and Namhae oyster farms can be divided into five successive stages: early developing, late developing, ripe, partially spawned and spent/inactive. Monthly changes in gonad developmental phases showed somewhat different patterns between female and male clams except for the spawning period. On the whole, however, monthly changes in the gonad developmental phases showed a similar pattern in the same sex. The sex ratios of females to males in Geoje and Namhae oyster farms were not significantly different from a 1:1 sex ratio ($x^2$ = 0.55 (p > 0.05) in Geoje and $x^2$ = 0.27 ( p > 0.05) in Namhae). Artificial induction of maturation by heating of adult oysters (two-year-old) was investigated from 17 January to 18 March in 1996. Maturity at the fixed water temperature group of $20^{\circ}C$ was 80%, it showed the highest maturity of experimental groups cultured for five weeks. The survival (%) of Crassostrea gigas in the raised water temperature experimental groups (15, 20, $25^{\circ}C$) were over 98.5%, as similar to the control group (100%). But, the survival of C. gigas in the fixed water temperature experimental groups (15, 20, 25, $30^{\circ}C$) were decreased with the increase of the water temperatures. In the fixed water temperature experimental group of $30^{\circ}C$, the survival was 51.1%. Base on these results, the fixed water temperature of $20^{\circ}C$ was the best condition for artificial induction of sexual maturation.
Solar assisted heat pump system uses solar thermal energy as a heat source of evaporator of heat pump. So, COP can be enhanced as well as collector efficiency. For improving performance of this system, some research about hybrid solar collector that has fin-and-tube heat exchanger has been conducted. This collector can get a thermal energy from ambient air for liquid heating, so heated liquid can be used as a heat source of evaporator in heat pump even the solar radiation is not enough. In this study, numerical analysis was conducted for confirming heat gain of liquid according to fin height and pitch of fin-and-tube heat exchanger in collector. As a result, higher heat gain was obtained on lower fin height and narrow fin pitch, but the pressure drop also increased with increment of heat gain. Thus the JF factor considering both heat transfer enhancement and pressure drop was investigated and the maximum value was shown when the fin height and pitch were 40mm and 45mm. So it is considered that this installation condition has a highest heat transfer improvement when comparing with pressure drop. However heat gain of liquid at this condition was less than the other installation conditions of fin pitch on same height. Then, after establishing a proper minimum heat gain of liquid, actual production and experiment of collector will be conducted with fin height and pitch showing maximum JF factor and satisfying selected minimum heat gain of liquid on the basis of results of this study.
It has been studded that combustion and the production of air pollution of anthracite - bituminous coal blend In a fluidized bed coal combustor, The objects of thIns study were to investigate mixing characteristics of the particles as well as the combustibility of the low grade domestic anthracite coal and Imported h19h calorific bltununous coal in the fluidized bed coal combustor. They were used as coal samples ; the domestic low grade anthracite coal with heating value of 2,010kca1/kg and the Imported high grade bituminous coal with beating value of 6,520kca1/kg. Also, the effects of air flow rate and anthracite fraction on the reaching time of steady state condition have been studied. The experimental results are presented as follows. The time of reaching to steady state was affected by the temperature variation. The steady state time was about 120 minute at 300sc1h which was the fastest. It has been found that $O^2$ and $CO^2$ concentration were reached steady state at about 100 minute. It has been found that $O^2$ concentration decreased and $CO^2$ concentration increased as the height of fluidlzed bed Increased. It was found that splash zone was mainly located from 25cm to 35cm above distributor. Also, as anthracite traction Increased, the mass of elutrlatlon particles Increased, and $CO^2$ concentration decreased. As gk flow rate Increased,$O^2$ concentration decreased and $CO^2$ concentration increased. Regardless of anthracite fraction and flow rate, the uncombustible weight percentage according to average diameter of elutriation particles were approldmately high In the case of One Particles. As anthracite traction and k now rate Increased, elutriation ratio Increased. As anthracite fraction was increased, exit combustible content over feeding combustible content was Increased. Regardless of anthracite fraction, size distribution of Ued material from discharge was almost constant. Over bed temperature 85$0^{\circ}C$ and excess air 20% , the difference of combution efficiencies were little. It is estimate that the combustion condition In anthracite-bituminous coal blend combustion is suitable at the velocity 0.3m/s, bed temperature 85$0^{\circ}C$, the excess air 20%.
Recently, the construction of onshore waste landfill sites has been studied due to the increase of waste and geosynthetics are widely utilized to enforce and protect waste landfill. Geosynthetics comprises the interface with soil and the seismic behavior and stability mostly depend on the dynamic shear behavior of the geosynthetic-soil interface. Therefore, the understanding of dynamic shear behavior and dynamic relative displacement of the interface is critical. The dynamic shear behavior of the interface is affected by surrounding conditions and loading and shows very complicated response, and, it is difficult to study theoretically. In this study, laboratory test to investigate dynamic relative displacement is performed under chemical condition. Dynamic interface apparatus is utilized and cyclic simple shear tests are conducted under short term (60 days of submerging period) and long term (840 days of submerging period) conditions. Consequently, relative displacement of the interface shows the largest values under acid condition, which means more severe damage of the interface.
PV/Thermal module is the combined system, which consist of a photovoltaic module and solar thermal collector that can obtain electrical power and thermal energy simultaneously. Thus the power generation can be increase by decreasing the temperature of photovoltaic module and thermal energy retrieved from module also can be used for heating system. In this study, Heat transfer performance of air type PV/Thermal module was confirmed with various bottom obstacles that can be installed easily to real photovoltaic module by CFD (computational fluid dynamics) analysis. Eight type obstacles were investigated according to the shape and arrangement. As a result, nusselt number represent heat transfer performance was increased about 86% compare with the basic type PV/Tthermal module that has no obstacle and triangle type obstacle had higher value than other types. But pressure drop was also increased with increment of heat transfer enhancement. Thus the performance factor considering both heat transfer and pressure drop was confirmed and V-fin type obstacle arranged in a row for Reynolds number below 9,600 and protrusion type obstacle arranged in zigzag for Reynolds number above 14,400 were shown higher performance factor than other types. From these results, V-fin type obstacle arranged in row and protrusion type obstacle arranged in zigzag were considered as a proper type for applying to real PV/thermal module according to operating condition. But the heat transfer performance can be changed by the geometric conditions of obstacle such as height, width, length and arrangement. Thus, it could also confirmed that the optimal condition and arrangement of this obstacle need to be found in further study.
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