• Title/Summary/Keyword: Heating Condition

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Identification of process generating formaldehyde in a furniture manufacturer (특정 가구 제조 공장의 포름알데히드 발생 공정 노출 평가)

  • Yoo, Kye-Mook;Lee, Mi-Young
    • Analytical Science and Technology
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    • v.27 no.5
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    • pp.243-247
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    • 2014
  • Formaldehyde is defined as carcinogen causing leukaemia, lymphoma or nasopharyngeal carcinoma at high level of exposure. Furniture-manufacturing workers can be exposed to formaldehyde, which implies serious impact on health of the workers. The authors carried out ambient monitoring of formaldehyde in the field, and identified the source of formaldehyde generated during the working process by testing the condition in the laboratory settings. After sampling formaldehyde in the air with 2,4-DNPH (2,4-dinitrophenylhydrazine) coated silica gel, we extracted formaldehyde derivative with acetonitrile and analyzed the extract using HPLC with UV detector at 360 nm. Formaldehyde was separated by ACQUITY UPLC BEH $C_{18}$ column at a flow rate of 0.5 mL/min using 45% acetonitrile as mobile phase. The workers were exposed to higher level of formaldehyde than normal air. Formaldehyde up to 0.31 ppm was detected in the process of veneer attachment, which exceeded 0.3 ppm, the ceiling value of ACGIH standard. The laboratory test of measuring formaldehyde generated from the glue and veneer used in the attachment process resulted in more formaldehyde generation as the temperature increased, and more from the veneer. Heating the veneer to $100-150^{\circ}C$ following the real condition of the manufacturing site generated 1.14-2.70 ppm of formaldehyde from the sample, which was 2-5 times higher level than Korean limit of exposure (0.5 ppm). As the workers handling and processing the veneer which was produced by wet process had high possibility to be exposed to formaldehyde, urgent improvement and management of working environment of furniture manufacturer is demanded.

Quality Characteristics of Frozen Welsh Onion (Allium fistulosum L.) according to Various Blanching Treatment Conditions (Blanching 처리 조건에 따른 동결 대파의 품질 특성)

  • Lee, Hye-Ok;Lee, Young-Joo;Kim, Ji-Young;Yoon, Doo-Hyun;Kim, Byeong-Sam
    • Korean Journal of Food Science and Technology
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    • v.43 no.4
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    • pp.426-431
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    • 2011
  • In this study, we set an optimum blanching condition as a pretreatment condition to freeze welsh onion (Allium fistulosum L.) for the purpose of preserving the cooking material for long-term usage. With higher blanching temperature and longer processing time, the Hunter color values and the hardness of welsh onion tended to decrease, which confirmed softening of the tissue. Compared to before blanching, total bacterial counts decreased to near 2 log scale, whereas coliforms were not detected or decreased to a 1-2 log scale. Blanching by heating at 100$^{\circ}C$ for 5 min decreased peroxidase inactivity to more than 94%, whereas only 47% of the inactivity was achieved at 80$^{\circ}C$ for 1 min. The sensory evaluation for the blanched and defrosted welsh onion showed that the group blanched at 80$^{\circ}C$ for 1 min was preferred significantly (p<0.05).

Reproductive Cycle and Induced Sexual Maturation of the Pacific Oyster, Crassostrea gigas (참굴, Crassostrea gigas의 생식주기와 성 성숙 유도)

  • Min, Kwang-Sik;Kim, Bong-Seok;Kim, Tae-Ik;Hur, Young-Baek;Chung, Ee-Yung
    • The Korean Journal of Malacology
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    • v.20 no.1
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    • pp.75-84
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    • 2004
  • Reproductive cycle, the condition index, sex ratio of the Pacific oysters, Crassostrea gigas were investigated by histological and morphometric data. The specimens were collected in the two oyster farms of Geoje and Namhae, Gyeongsangnam-do, Korea, from November 1995 to October 1996. Growth of shell length in two regions was similar, but growth of total weight of the oyster in Namhae was faster than that in Geoje oyster farm. The spawning periods in female and male clams were from July to October in Geoje and from June to October in Namhae oyster farm. Ripe oocytes were approximately 50 m in diameter. The reproductive cycle of in females and males in Geoje and Namhae oyster farms can be divided into five successive stages: early developing, late developing, ripe, partially spawned and spent/inactive. Monthly changes in gonad developmental phases showed somewhat different patterns between female and male clams except for the spawning period. On the whole, however, monthly changes in the gonad developmental phases showed a similar pattern in the same sex. The sex ratios of females to males in Geoje and Namhae oyster farms were not significantly different from a 1:1 sex ratio ($x^2$ = 0.55 (p > 0.05) in Geoje and $x^2$ = 0.27 ( p > 0.05) in Namhae). Artificial induction of maturation by heating of adult oysters (two-year-old) was investigated from 17 January to 18 March in 1996. Maturity at the fixed water temperature group of $20^{\circ}C$ was 80%, it showed the highest maturity of experimental groups cultured for five weeks. The survival (%) of Crassostrea gigas in the raised water temperature experimental groups (15, 20, $25^{\circ}C$) were over 98.5%, as similar to the control group (100%). But, the survival of C. gigas in the fixed water temperature experimental groups (15, 20, 25, $30^{\circ}C$) were decreased with the increase of the water temperatures. In the fixed water temperature experimental group of $30^{\circ}C$, the survival was 51.1%. Base on these results, the fixed water temperature of $20^{\circ}C$ was the best condition for artificial induction of sexual maturation.

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Numerical Analysis on Heat Gain of Liquid from Ambient Air with Various Fin Heights and Pitches of Fin-and-Tube Heat Exchanger in Hybrid Solar Collector (핀-튜브 열교환 구조를 갖는 복합집열기에서 핀 높이 및 간격에 따른 공기열 이용 액체 가열 성능에 관한 수치해석 연구)

  • Choi, Hwi-Ung;Fatkhur, Rokhman;Lyu, Nam-Jin;Yoon, Jung-In;Son, Chang-Hyo;Choi, Kwang-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.36 no.3
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    • pp.53-61
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    • 2016
  • Solar assisted heat pump system uses solar thermal energy as a heat source of evaporator of heat pump. So, COP can be enhanced as well as collector efficiency. For improving performance of this system, some research about hybrid solar collector that has fin-and-tube heat exchanger has been conducted. This collector can get a thermal energy from ambient air for liquid heating, so heated liquid can be used as a heat source of evaporator in heat pump even the solar radiation is not enough. In this study, numerical analysis was conducted for confirming heat gain of liquid according to fin height and pitch of fin-and-tube heat exchanger in collector. As a result, higher heat gain was obtained on lower fin height and narrow fin pitch, but the pressure drop also increased with increment of heat gain. Thus the JF factor considering both heat transfer enhancement and pressure drop was investigated and the maximum value was shown when the fin height and pitch were 40mm and 45mm. So it is considered that this installation condition has a highest heat transfer improvement when comparing with pressure drop. However heat gain of liquid at this condition was less than the other installation conditions of fin pitch on same height. Then, after establishing a proper minimum heat gain of liquid, actual production and experiment of collector will be conducted with fin height and pitch showing maximum JF factor and satisfying selected minimum heat gain of liquid on the basis of results of this study.

A Study on the Use of Low-Grade Domestic Anthracite by Anthracite - Bituminous Coal Blend Combustion in a Fluidized Bed Combustor (유동층 연소로에서 유.무연탄 혼합 연소법을 이용한 국내산 저질 무연탄의 활용에 관한 연구)

  • 정종현;조상원
    • Journal of Environmental Science International
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    • v.6 no.3
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    • pp.267-276
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    • 1997
  • It has been studded that combustion and the production of air pollution of anthracite - bituminous coal blend In a fluidized bed coal combustor, The objects of thIns study were to investigate mixing characteristics of the particles as well as the combustibility of the low grade domestic anthracite coal and Imported h19h calorific bltununous coal in the fluidized bed coal combustor. They were used as coal samples ; the domestic low grade anthracite coal with heating value of 2,010kca1/kg and the Imported high grade bituminous coal with beating value of 6,520kca1/kg. Also, the effects of air flow rate and anthracite fraction on the reaching time of steady state condition have been studied. The experimental results are presented as follows. The time of reaching to steady state was affected by the temperature variation. The steady state time was about 120 minute at 300sc1h which was the fastest. It has been found that $O^2$ and $CO^2$ concentration were reached steady state at about 100 minute. It has been found that $O^2$ concentration decreased and $CO^2$ concentration increased as the height of fluidlzed bed Increased. It was found that splash zone was mainly located from 25cm to 35cm above distributor. Also, as anthracite traction Increased, the mass of elutrlatlon particles Increased, and $CO^2$ concentration decreased. As gk flow rate Increased,$O^2$ concentration decreased and $CO^2$ concentration increased. Regardless of anthracite fraction and flow rate, the uncombustible weight percentage according to average diameter of elutriation particles were approldmately high In the case of One Particles. As anthracite traction and k now rate Increased, elutriation ratio Increased. As anthracite fraction was increased, exit combustible content over feeding combustible content was Increased. Regardless of anthracite fraction, size distribution of Ued material from discharge was almost constant. Over bed temperature 85$0^{\circ}C$ and excess air 20% , the difference of combution efficiencies were little. It is estimate that the combustion condition In anthracite-bituminous coal blend combustion is suitable at the velocity 0.3m/s, bed temperature 85$0^{\circ}C$, the excess air 20%.

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Dynamic Relative Displacement of Geosynthetic-Soil Interface Considering Chemical Effect (화학적 영향을 고려한 토목섬유-지반 접촉면의 동적상대변위)

  • Kwak, Chang-Won;Oh, Myoung-Hak;Jang, Dong-In;Park, Inn-Joon
    • Journal of the Korean Geotechnical Society
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    • v.32 no.11
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    • pp.73-81
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    • 2016
  • Recently, the construction of onshore waste landfill sites has been studied due to the increase of waste and geosynthetics are widely utilized to enforce and protect waste landfill. Geosynthetics comprises the interface with soil and the seismic behavior and stability mostly depend on the dynamic shear behavior of the geosynthetic-soil interface. Therefore, the understanding of dynamic shear behavior and dynamic relative displacement of the interface is critical. The dynamic shear behavior of the interface is affected by surrounding conditions and loading and shows very complicated response, and, it is difficult to study theoretically. In this study, laboratory test to investigate dynamic relative displacement is performed under chemical condition. Dynamic interface apparatus is utilized and cyclic simple shear tests are conducted under short term (60 days of submerging period) and long term (840 days of submerging period) conditions. Consequently, relative displacement of the interface shows the largest values under acid condition, which means more severe damage of the interface.

CFD Analysis on the Heat Transfer Performance with Various Obstacles in Air Channel of Air-Type PV/Thermal Module (공기식 태양광/열 시스템 공기채널 내 여러 저항체 설치에 따른 전열성능에 관한 CFD 해석)

  • Choi, Hwi-Ung;Fatkhur, Rokhman;Kim, Young-Bok;Yoon, Jung-In;Son, Chang-Hyo;Choi, Kwang-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.38 no.2
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    • pp.33-43
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    • 2018
  • PV/Thermal module is the combined system, which consist of a photovoltaic module and solar thermal collector that can obtain electrical power and thermal energy simultaneously. Thus the power generation can be increase by decreasing the temperature of photovoltaic module and thermal energy retrieved from module also can be used for heating system. In this study, Heat transfer performance of air type PV/Thermal module was confirmed with various bottom obstacles that can be installed easily to real photovoltaic module by CFD (computational fluid dynamics) analysis. Eight type obstacles were investigated according to the shape and arrangement. As a result, nusselt number represent heat transfer performance was increased about 86% compare with the basic type PV/Tthermal module that has no obstacle and triangle type obstacle had higher value than other types. But pressure drop was also increased with increment of heat transfer enhancement. Thus the performance factor considering both heat transfer and pressure drop was confirmed and V-fin type obstacle arranged in a row for Reynolds number below 9,600 and protrusion type obstacle arranged in zigzag for Reynolds number above 14,400 were shown higher performance factor than other types. From these results, V-fin type obstacle arranged in row and protrusion type obstacle arranged in zigzag were considered as a proper type for applying to real PV/thermal module according to operating condition. But the heat transfer performance can be changed by the geometric conditions of obstacle such as height, width, length and arrangement. Thus, it could also confirmed that the optimal condition and arrangement of this obstacle need to be found in further study.

A Development and Validation of Cosmetic Container Based on L-Ascorbic Acid Oxidation Property (L-Ascorbic Acid의 산화특성에 따른 화장품 용기 개발 및 유효성 분석)

  • Yoon, Sungwook
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.39 no.2
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    • pp.149-158
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    • 2013
  • L-ascorbic acid, the representative antioxidants, has a great effect on skin whitening, collagen synthesis, and anti-aging, but has low oxidative stability during storage. Therefore, in this study, thermal and oxidation properties of L-ascorbic acid under various storage conditions (powder, aqueous phase, changes of temperature, UV-irradiation, and inflow of external air etc.) were investigated. And the storage stability of ingredient was validated in the double-spaced pouch by analysing oxidation properties under each storage conditions (powder phase and blended with essence). In oder to analyze the thermal properties, TGA, DSC, and FT-IR analysis were carried out and UV-visible spectrophotometer & redox titration were used in parallel for oxidation property analyses. From the result of experiment, L-ascorbic acid was oxidized fast when it contained lots of metallic ion, hydroxy ion in aqueous solution under high temperature, UV-irradiation & inflow external air, whereas it was not oxidized for a long time when it was stored as pure powder although it has same condition as heating up, UV-irradiation & inflow external air. Based on this result, retention period of cosmetics which is using L-ascorbic acid, less stable material in oxidation can be innovatively increased when using double-spaced pouch that is designed and produced for separating storage of active ingredients.

Study on Condition of Fabrication Processing for R. F. High-power Unit Capacitor and Electrical Characteristics According to Addition of ZrO2 (고주파용 대용량 단위 유전체 제조공정과 ZrO2 첨가에 따른 전기적 특성 연구)

  • Ahn, Young-Soo;Kim, Joon-Soo;Park, Joo-Seok;Kim, Hong-Soo;Han, Moon-Hee;No, Kwang-Soo
    • Journal of the Korean Ceramic Society
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    • v.39 no.9
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    • pp.822-828
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    • 2002
  • Fabrication and electrical characterization of R. F. High-power unit capacitors were investigated to study on condition of fabrication processing for R. F. High-power unit capacitor and electrical characteristics according to addition of $ZrO_2$. The unit capacitors were fabricated using tape casting. The optimum mixture ratio of dielectrics and mixing binder for the slurry fabrication was 57.5∼60.0: 42.5∼40.0 wt%. The slurry viscosity was 4000∼5000 cps and casting state of green tape fabricated using these slurry was excellent. Optimum stacking was made by 200 kg/$cm^2$ pressure with 80$^{\circ}C$ heating. $ZrO_2$ was added to improve the electrical characteristics of unit capacitor, especially breakdown characteristics. The dielectric constant and loss factor of the unit condenser having different $ZrO_2$ amounts was not changed in the addition range of 1 to 5 wt%. Also, dielectric constant was not changed in the frequency range of 10 to 500 kHz. It was found that characteristics of resistance voltage was improved through the formation of $CaZrO_3$ and the reduction of particle size as about 3wt% $ZrO_2$ was added.

The Fire Resistant Performance of RC Column with Confined Lateral Reinforcement According to Fire Exposure Condition (횡방향 철근으로 구속된 철근콘크리트 기둥의 화재 노출조건에 따른 내화성능)

  • Choi, Kwang Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.311-318
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    • 2018
  • When reinforced concrete structures are exposed to fire, their mechanical properties such as compressive strength, elasticity coefficient and rebar yield strength, are degraded. Therefore, the structure's damage assessment is essential in determining whether to dismantle or augment the structure after a fire. In this study, the confinement effect of lateral reinforcement of RC column according to the numbers of fire exposure face and stirrup was verified by fire resistant test with the heating temperatures of $400^{\circ}C$, $600^{\circ}C$ and $800^{\circ}C$. The test results showed that the peak stress decreases and peak strain increases as the temperature is getting higher, also transverse ties are helpful in improving the compressive resistance of concrete subjected to high temperature. Based on the results of this study, the residual stress of confined concrete under thermal damage is higher at the condition of more lateral reinforcement ratio and less fire exposure faces. The decreasing ratio of elastic modulus of more confined and less exposure faces from the relationship of load and displacement was also smaller than that of opposite conditions.