• 제목/요약/키워드: Heat of hydration Temperature

검색결과 350건 처리시간 0.027초

고로슬래그를 다량 함유한 고강도 콘크리트의 재료적 특성 (Material Characteristics of High-Strength Concrete Incorporating High Replacement Level of Blast-Furnace Slag)

  • 이회근;정재홍;김한준;이승훈
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
    • /
    • pp.291-292
    • /
    • 2010
  • 본 연구에서는 고로슬래그 미분말을 다량 사용한 고강도 콘크리트의 재료적 특성을 조사하기 위해 고로슬래그 미분말을 각각 50%와 70% 사용한 고강도 콘크리트에 대해 압축강도, 단열온도상승, 자기 수축 및 염소이온확산계수를 측정하였다. 실험결과, 슬래그 다량 치환 사용시 수화열 저감 및 염소이온확산계수 감소로 온도균열제어 및 고부식성 환경하 염해 저항성이 향상되는 것으로 나타났다.

  • PDF

Bonding of nano-modified concrete with steel under freezing temperatures using different protection methods

  • Yasien, A.M.;Bassuoni, M.T.
    • Computers and Concrete
    • /
    • 제26권3호
    • /
    • pp.257-273
    • /
    • 2020
  • Concrete bond strength with steel re-bars depends on multiple factors including concrete-steel interface and mechanical properties of concrete. However, the hydration development of cementitious paste, and in turn the mechanical properties of concrete, are negatively affected by cold weather. This study aimed at exploring the concrete-steel bonding behavior in concrete cast and cured under freezing temperatures. Three concrete mixtures were cast and cured at -10 and -20℃. The mixtures were protected using conventional insulation blankets and a hybrid system consisting of insulation blankets and phase change materials. The mixtures comprised General Use cement, fly ash (20%), nano-silica (6%) and calcium nitrate-nitrite as a cold weather admixture system. The mixtures were tested in terms of internal temperature, compressive, tensile strengths, and modulus of elasticity. In addition, the bond strength between concrete and steel re-bars were evaluated by a pull-out test, while the quality of the interface between concrete and steel was assessed by thermal and microscopy studies. In addition, the internal heat evolution and force-slip relationship were modeled based on energy conservation and stress-strain relationships, respectively using three-dimensional (3D) finite-element software. The results showed the reliability of the proposed models to accurately predict concrete heat evolution as well as bond strength relative to experimental data. The hybrid protection system and nano-modified concrete mixtures produced good quality concrete-steel interface with adequate bond strength, without need for heating operations before casting and during curing under freezing temperatures down to -20℃.

초지연제 혼입률에 따른 저발열 콘크리트의 양생온도별 기초물성평가 (Fundamental Properties of Low-Heat Concrete According to the Mixing Rate of Super Retarding Agent)

  • 박병주;최윤호;현승용;김종;한민철;한천구
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2020년도 봄 학술논문 발표대회
    • /
    • pp.90-91
    • /
    • 2020
  • As the construction site has become narrower recently, the importance of mass concrete is naturally being highlighted as skyscrapers become popular. However, it is not possible to install the entire volume per day if the mass concrete is installed due to the Remicon 8⦁5 system and the 52-hour workweek system. When the mass concrete base is divided into several days, cold joints occur because the consolidation of joints is not integrated due to different degree of hardening in the case of the previous layer and the next day. As a result, existing research has shown that if super retarding agent are mixed into Ready Mixed Concrete (hereinafter referred to as Remicon) using sugar as a raw material to delay the curing time of concrete, cold joints are inhibited and cracks are inhibited by reducing the initial hydration heat.

  • PDF

$YBa_2Cu_3O_{7-}\delta$, $Y_2BaCuO_5$ 및 Ba-Cu-O계 화합물의 수분과의 반응에 의한 열방출에 관한 연구 (Heat Liberation in the Reaction of $YBa_2Cu_3O_{7-}\delta$, $Y_2BaCuO_5$, and Binary Compounds in the Ba-Cu-O System with Water)

  • 김배연
    • 한국세라믹학회지
    • /
    • 제32권1호
    • /
    • pp.83-89
    • /
    • 1995
  • YBa2Cu3O7-$\delta$, Y2BaCuO5, and binary compounds in the Ba-Cu-O system with the nominal composition of Ba2CuO3, BaCuO2, Ba3Cu4O7, Ba3Cu5O8 were synthesized to investigate the heat evolutions and crystalline phases in the hydration reaction of orthorhombic YBa2Cu3O7-$\delta$ phase. The observed crystalline phases were YBa2Cu3O7-$\delta$, Y2BaCuO5, and BaCuO2, or Ba2Cu3O5+x, and some amount of noncrystalline phase in the Ba-Cu system comounds. In contact with distilled water, YBa2Cu3O7-$\delta$ and Y2BaCuO5 did not have considerable heat liberation, but in the binary compounds of the Ba-Cu-O system, the amount of total heat liberation was increased with respect to the Cu content. It might be that the reaction of high temperature superconductor YBa2Cu3O7-$\delta$ with water and/or moisture originated from the unusual oxidation state of Cu ion and the presence of amorphous Ba-Cu oxide compound. The degradation of high Tc superconductor by moisture and water could be controlled by restricting the heterogeneous distribution of Tc comlposition and the formation of second phase, such as stable Y2BaCuO5, and the resulting unstable Ba-Cu oxide compound.

  • PDF

라텍스함량 변화에 따른 VES-LMC의 자기수축 (Autogenous Shrinkage of Very-Early Strength Latex-Modified Concrete with Latex Contents)

  • 박원일;최판길;이봉학;윤경구
    • 한국산학기술학회논문지
    • /
    • 제11권3호
    • /
    • pp.1059-1065
    • /
    • 2010
  • 초속경 라텍스개질 콘크리트(VES-LMC)는 공용중 교량바닥판 콘크리트 긴급 덧씌우기를 목적으로 개발되었으며, 콘크리트타설 후 3시간 만에 교통개방이 가능하도록 작업성, 내구성 및 강도특성을 만족하도록 특성화된 콘크리트이다. VES-LMC 배합은 고유의 급속경화 특성으로 인해 콘크리트 타설 초기에 높은 수화열을 수반하고, 상대적으로 낮은 물시멘트비로 인해 자기수축에 민감하게 반응할 수 있다. 본 논문에서는 간이수화열과 초기수축 실험을 수행하여 동일슬럼프 조건과 서로 다른 슬럼프 조건에서 라텍스함량 변화가 VES-LMC의 자기수축에 미치는 영향을 평가하였다. 실험결과는 다음과 같다. 라텍스는 콘크리트 내구성 향상에만 기여할 뿐 수화열에 미치는 영향이 매우 작게 나타났다. 서로 다른 슬럼프 조건에서 자기수축은 라텍스함량 증가에 따라 증가하였고, 증가추세는 로그함수의 형태로 나타났다. 그러나 동일 슬럼프조건에서 라텍스함량 변화는 두 가지 실험변수가 동시에 변화하므로 자기수축 특성에 미치는 상관성이 작게 나타났다.

콘크리트 폐기물에서 분리된 페이스트를 활용한 고화재 기술개발 기초연구 (Recycling Waste Paste from Concrete for Solidifying Agent)

  • 문영범;최현국;김재영;이재형;정철우;김지현
    • 한국건축시공학회지
    • /
    • 제17권3호
    • /
    • pp.269-277
    • /
    • 2017
  • 본 연구에서는 원전 콘크리트로부터 분리된 페이스트 미분말을 이용 방사성폐기물 처분용 고화재로 활용하기 위하여 기초 특성을 검토하고자 하였다. 실험 결과 수화반응한 페이스트는 시멘트보다 비중이 낮고 수화회복을 위한 소성과정에서 온도증가에 따라 비중이 다르게 나타나 그에 따른 부피도 고려되어야 할 것으로 판단된다. 수화회복을 위한 소성온도에서 압축강도가 가장 우수한 온도조건은 $600^{\circ}C$로 나타났으며, $700^{\circ}C$ 이상에서는 CaO의 생성량이 과도하여 높은 수화열, 유동성 저하 및 낮은 강도가 발현되는 것을 확인하였다. 따라서 본 연구 범위 내에서 고화재로 활용 가능한 적정 수화회복 온도는 $600^{\circ}C$로 판단되며 폐콘크리트 페이스트가 적정한 열처리를 거치는 경우 방사성 폐기물 고화재료로서 활용될 수 있는 가능성을 보였다는 점에 의의를 둔다.

이중버블시트를 이용한 단열보온양생공법의 한중매스콘크리트 현장적용 (Field Application of the Mass Concrete Using Insulation Curing Method with Double Bubble Sheets Subject to Cold Weather)

  • 이동규;김종;김기훈;황인성;한민철;한천구
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2007년도 춘계학술논문 발표대회
    • /
    • pp.1-4
    • /
    • 2007
  • This study investigated the applicability of insulation curing method with double layer bubble sheets to the man concrete subjected to cold weather. Temperature history of the mass concrete indicated that the highest temperature of center section was exhibited at $34^{\circ}C$ while the that of surface section was $25^{\circ}C$. Difference between center and surface was shown to be less $10^{\circ}C$ when the temperature of center section was peak section, and thereby associated temperature cracking index was calculated 1.5, and occurrence probability of temperature cracking was 5%, so there was no temperature cracking caused by internal restraint. No temperature crack was observed by naked eye. It was clear that early frost demage and temperature cracking could be restrained due to reducing temperature difference between inner part and outside in the case double bubble sheets applied to insulation curing method in cold weather. The maturity of mass concrete is higher than outside about $72\sim89^{\circ}$ DD, so it was demonstrated to prevent early frost demage and ensure strength excellently. Insulation curing method with double bubble sheets was more economic than heating curing method.

  • PDF

상하부 배합을 달리함에 의한 기초 매트 매스콘크리트의 수화열 균열저감 (Reducing Thermal Cracking of Mat-foundation Mass Concrete Applying Different Mix Designs for Upper and Lower Placement Lifts)

  • 한천구;김민호
    • 한국건축시공학회지
    • /
    • 제17권1호
    • /
    • pp.39-46
    • /
    • 2017
  • 최근 건축물의 기초는 구조체의 안정성과 연관하여 두꺼운 매스콘크리트 형태가 설계되어지고 있다. 그런데, 이와 같은 매트 매스콘크리트는 800mm 이상의 두꺼운 부재로 설계되는 경우가 많아짐에 따라 수화열에 의한 균열이 문제점으로 제기 되고 있다. 이에, 본 연구에서는 상 하부를 구분하여 타설하는 실무조건을 고려하여, 컴퓨터 프로그램상으로 하부와 상부의 최적치를 도출한 다음, 실구조체에 적용 해석치와 실측치간을 비교하므로서 효율적인 수화열균열 저감방안을 제안하고자 하였다. 그 결과, 상 하부 타설 콘크리트간의 저발열 배합정도를 고려한 수화발열량차 적용은 침하균열 방지 및 수화열 균열제어에 효과적인 것으로 밝혀졌다.

고로슬래그 치환율 변화에 따른 고강도 콘크리트의 강도 및 수축 특성 (Properties of Shrinkage and Strength of Concrete Incorporating Blast-furnace Slag)

  • 손호정;노상균;김성환;한민철;백주현;한천구
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2008년도 춘계 학술논문 발표대회
    • /
    • pp.99-102
    • /
    • 2008
  • This study investigates the properties of the flow, air content, strength, hydration heat, and the autogenous shrinkage, and the results are summarized as following. As a properties of fresh concrete, the flow increased and the air content decreased as the replacement ratio of BS increased. The time of set delayed as the replacement ratio of BS increased by latent hydraulicity. The compressive strength of hardening concrete was smaller than OPC as the replacement ratio of BS increased at young concrete, however it was more than equal after 28th day and from then on. The rising temperature ratio which occurs by simplicity insulation decreased as the replacement ratio of BS increased, but it increased by latent hydraulicity reaction at the latter half. The length ratio of autogenous shrinkage of OPC was 319×10-6, however it was shorter when the replacement ratio was 40% as showing 290×10-6.

  • PDF

입도분급 미분 시멘트를 이용한 조강형 콘크리트의 현장실용화에 관한 연구 (A study on the Practical Application of High Early Strength Type Concrete Using Fine Particle Classifying Cement)

  • 최성용;노동현;김기훈;김경민;한민철;한천구
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2008년도 춘계 학술논문 발표대회
    • /
    • pp.117-121
    • /
    • 2008
  • This study investigates practical application of high early strength type concrete using fine particle classifying cement, and the results are summarized as following. The replacement use of FC 30% did not great influence on concrete mix, therefore mixing without additional SP and AE was available using equal mix with OPC. The ratio of increasing temperature by heat of hydration was similar with OPC, and the compressive strength was over then 5MPa at -28℃ outside temperature on 2nd day. Therefore, it is considering that the first purpose, the effect of shortening terms of work by early demolding, will be available. The rebound rate of type "P" schumidt hammer was relative with compressive strength, and the rebound rate for verifying 5MPa of compressive strength was estimated about 55 considering rate of safety. Therefore, assuming demolding date is available efficiently.

  • PDF