• 제목/요약/키워드: Heat of Combustion

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A Study on the Isomerization Reactions of Tricyclopentadiene Derivatives Using Aluminum Chloride(AlCl3) Catalyst(I) (알루미늄클로라이드 촉매를 이용한 Tricyclopentadiene 유도체의 이성화 반응 연구(I))

  • Jo, Hyun-Hye;Kwon, Tae-Soo;Park, Chang-Sun;Han, Jeong-Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.16 no.2
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    • pp.17-24
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    • 2012
  • Tetrahydrotricyclopentadiene(below THTCPD) isomer is a good candidate materials for the high performance liquid fuel component because of its high density and heat of combustion value. The object of this study was to find out the proper reaction condition to improve the fluidity of THTCPD which is solid state at room temperature. Therefore, we have carried out isomerization reactions using aluminum chloride in the varying reaction condition such as reaction temperature and solvents. The results showed that when using aluminum chloride catalyst, THTCPD isomerization reaction was more active in the polar halogenated reaction media such as dichloromethane(methylene chloride: MC), 1,2-dichloroethane(ethylene chloride: EC) and chloroform than in non-polar hydrocarbon media such as n-Hexnae and toluene and was effected by reaction temperature variation.

A Study on a Comparison of Sky View Factors and a Correlation with Air Temperature in the City (하늘시계지수 비교 및 도시기온 상관성 연구: 강남 선정릉지역을 중심으로)

  • Yi, Chaeyeon;Shin, Yire;An, Seung Man
    • Atmosphere
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    • v.27 no.4
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    • pp.483-498
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    • 2017
  • Sky view factor can quantify the influence of complex obstructions. This study aims to evaluate the best available SVF method that represents an urban thermal condition with land cover in complex city of Korea and also to quantify a correlation between SVF and mean air temperature; the results are as follows. First, three SVF methods comparison result shows that urban thermal study should consider forest canopy induced effects because the forest canopy test (on/off) on SVF reveals significant difference range (0.8, between maximum value and minimum value) in comparison with the range (0.1~0.3) of SVFs (Fisheye, SOLWEIG and 3DPC) difference. The significance is bigger as a forest cover proportion become larger. Second, R-square between SVF methods and urban local mean air temperature seems more reliable at night than a day. And as the value of SVF increased, it showed a positive slope in summer day and a negative slope in winter night. In the SVF calculation method, Fisheye SVF, which is the observed value, is close to the 3DPC SVF, but the grid-based SWG SVF is higher in correlation with the temperature. However, both urban climate monitoring and model/analysis study need more development because of the different between SVF and mean air temperature correlation results in the summer night period, which imply other major factors such as cooling air by the forest canopy, warming air by anthropogenic heat emitted from fuel oil combustion and so forth.

Fire Performance Testing Method for Fire Retardant EPS Sandwich Panel Using X-ray Analysis (X-선 분석법을 이용한 난연 EPS 샌드위치 패널의 화재성능평가 방법에 관한 연구)

  • Shim, Ji-Hun;Cho, Nam-Wook
    • Fire Science and Engineering
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    • v.29 no.6
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    • pp.76-83
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    • 2015
  • EPS sandwich panel contains flame retardants that slow down ignition during fires,reduce the amount of heat generated, and block the spread of combustion. However, if a sandwich panel does not satisfy standards for fire-retardant performance, it may increase damage to property and human life. It is difficult to test the fire-retardant performance of a finishing material with the naked eye, so it is necessary to develop convenient and fast evaluation methods that are convenient and fast. In this study, a fire safety evaluation method for EPS sandwich panel was analyzed using X-ray to detect specific components related to the fire-retardant performance X-ray fluorescence analysis (XRF) indicated that suitable panel products contained more aluminum in comparison to unsuitable products. Gibbsite was identified as the main crystalline material of flame retardant EPS through X-ray diffraction analysis (XRD) and was included in both suitable products and unsuitable products, but there was a difference in crystalline structure. This study was verifies the possibility of evaluating fire-retardant performance using ultimate analysis and crystal analysis through these X-ray methods.

Available Technology and Integrated Management Plan for Energy-positive in the Sewage Treatment Plant (에너지 생산형 하수처리장을 위한 가용 기술과 통합관리 방안)

  • Song, Minsu;Kim, Hyoungho;Bae, Hyokwan
    • Journal of Korean Society on Water Environment
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    • v.36 no.1
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    • pp.55-68
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    • 2020
  • Because of the intensified environmental problems such as climate change and resource depletion, sewage treatment technology focused on energy management has recently attracted attention. The conversion of primary sludge from the primary sedimentation tank and excessive sludge from the secondary sedimentation tank into biogas is the key to energy-positive sewage treatment. In particular, the primary sedimentation tanks recover enriched biodegradable organic matter and anaerobic digestion process produces methane from the organic wastes for energy production. Such technologies for minimizing oxygen demand are leading the innovation regarding sewage treatment plants. However, sewage treatment facilities in Korea lack core technology and operational know-how. Actually, the energy potential of sewage is higher than sewage treatment energy consumption in the sewage treatment, but current processes are not adequately efficient in energy recovery. To improve this, it is possible to apply chemically enhanced primary treatment (CEPT), high-rate activated sludge (HRAS), and anaerobic membrane bioreactor (AnMBR) to the primary sedimentation tank. To maximize the methane production of sewage treatment plants, organic wastes such as food waste and livestock manure can be digested. Additionally, mechanical pretreatment, thermal hydrolysis, and chemical pretreatment would enhance the methane conversion of organic waste. Power generation systems based on internal combustion engines are susceptible to heat source losses, requiring breakthrough energy conversion systems such as fuel cells. To realize the energy positive sewage treatment plant, primary organic matter recovery from sewage, biogas pretreatment, and co-digestion should be optimized in the energy management system based on the knowledge-based operation.

A Study on the Fire Characteristics of Aluminum Composite Panel by Large Scale Calorimeter (라지스케일 칼로리미터에 의한 알루미늄 복합패널 외장재의 연소특성에 관한 연구)

  • Yun, Jung-Eun;Min, Se-Hong;Kim, Mi-Suck;Choi, Sung-Bok
    • Fire Science and Engineering
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    • v.24 no.2
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    • pp.89-96
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    • 2010
  • In this research, exterior material combustion experiment was really tested to evaluate fire risks of aluminium complex panel which is used a lot for building exterior material. As a result, We saw fast fire spreading of aluminium complex panel. The reason is polyethylene in aluminum complex panel combust spreading fast fire flame vertically. In this test, the highest heat release rate of aluminum complex panel was 1,144 kW and surface temperature which is measured by thermocouple went up to more than $903.3^{\circ}C$, that temperature is quite a higher than $660^{\circ}C$ which is aluminum melting temperature. So, fire of aluminum complex panel can be evaluated to give us severe damage both by fast fire spreading vertically and by fire spreading through openings internally. These results from real experiment will be able to use to predict fire spreading of aluminum complex panel by comparing to modeling materialization of aluminum complex panel in the future.

A Study on the isomerization reactions of Tricyclopentadiene Derivatives using aluminum chloride($AlCl_3$) catalyst(I) (알루미늄클로라이드 촉매를 이용한 Tricyclopentadiene 유도체의 이성화 반응 연구(I))

  • Joo, Hyun-Hye;Joo, Hyeong-Uk;Park, Chang-Sun;Han, Jeong-Sik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.800-803
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    • 2010
  • Tetrahydrotricyclopentadiene(below THTCPD) isomer is a good candidate for the high performance liquid fuel component because of high density and heat of combustion value. But it has bad fluidity. The object of this study was to find out the optimal reaction condition to improve the fluidity of THTCPD because initial reactant is solid state, So we have carried out isomerization reactions using aluminum chloride catalyst under varying the reaction condition such as reaction temperature and reaction solvents. The results showed that when using aluminum chloride catalyst, isomerization reaction was more active in dichloromethane(methylene chloride: MC), 1,2-dichloroethane(ethylene chloride: EC) and chloroform than n-hexnae and toluene and was effected by reaction temperature.

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A Study on the Confirmation of non-flammabikity of the Cast Resin Mold Transformer in Subway Substation (지하철 변전실용 진공주형형 몰드변압기의 난연성 확인에 관한 연구)

  • 정용기;장성규;곽희로
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.12 no.2
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    • pp.99-107
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    • 1998
  • This dissertationhas confirmed the non-flam mability of cast mold transformer that is increasingly used lately. As a research progress, the investigation has been performed on the installation status and each line of the subway system which have the most mold transformer accidents, and the impediment status of the transformer for rectifier and the high-voltage distribution transformer per each manufacturer. Then, a high voltage mold of the actual mold transformer has been installed in the horiwntal heating furnace and the heat has been applied by the standard heating temperature curve of KSF 2257(Fireproof testing meth od of the construction structures: 1993). Accordingly, the combustibility of the mold transformer based on the test results has been found that 78 minutes has been required for the complete burning per the KSF 2257 combustion test curve and that, after stopping the heat application of the horizontal furnace after ignition, the flame progress has not been made but shown as the self-extinguishing characteristics when the flame progress has been checked. Thus, the non-flammability and self-extinguishability of the mold transformer have been confirmed. The result of this dissertation has indicated that the accident involving mold transformer has been progressed and expanded by the dielectric breakdown or void due to the crack in the mold rather than a fire accident caused by a short-circuit or an overload.r an overload.

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A Study of Estimation of Greenhouse Gas Emission and Reduction by Municipal Solid Waste (MSW) Management (D시 생활폐기물 관리 방법과 온실가스 배출량과 감축량 산정 연구)

  • Yun, Hyunmyeong;Chang, Yun;Jang, Yong-Chul
    • Journal of Korea Society of Waste Management
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    • v.35 no.7
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    • pp.606-615
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    • 2018
  • Over the past two decades, the options for solid waste management have been changing from land disposal to recycling, waste-to-energy, and incineration due to growing attention for resource and energy recovery. In addition, the reduction of greenhouse gas (GHG) emission has become an issue of concern in the waste sector because such gases often released into the atmosphere during the waste management processes (e.g., biodegradation in landfills and combustion by incineration) can contribute to climate change. In this study, the emission and reduction rates of GHGs by the municipal solid waste (MSW) management options in D city have been studied for the years 1996-2016. The emissions and reduction rates were calculated according to the Intergovernmental Panel on Climate Change guidelines and the EU Prognos method, respectively. A dramatic decrease in the waste landfilled was observed between 1996 and 2004, after which its amount has been relatively constant. Waste recycling and incineration have been increased over the decades, leading to a peak in the GHG emissions from landfills of approximately $63,323tCO_2\;eq/yr$ in 2005, while the lowest value of $35,962tCO_2\;eq/yr$ was observed in 2016. In 2016, the estimated emission rate of GHGs from incineration was $59,199tCO_2\;eq/yr$. The reduction rate by material recycling was the highest ($-164,487tCO_2\;eq/yr$) in 2016, followed by the rates by heat recovery with incineration ($-59,242tCO_2\;eq/yr$) and landfill gas recovery ($-23,922tCO_2\;eq/yr$). Moreover, the cumulative GHG reduction rate between 1996 and 2016 was $-3.46MtCO_2\;eq$, implying a very positive impact on future $CO_2$ reduction achieved by waste recycling as well as heat recovery of incineration and landfill gas recovery. This study clearly demonstrates that improved MSW management systems are positive for GHGs reduction and energy savings. These results could help the waste management decision-makers supporting the MSW recycling and energy recovery policies as well as the climate change mitigation efforts at local government level.

A Heat Shock Simulation System for Testing Performance of EWP (EWP 성능 검사를 위한 열 충격 모사시스템)

  • Yoo, Nam-Hyun
    • The Journal of the Korea institute of electronic communication sciences
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    • v.14 no.3
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    • pp.553-558
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    • 2019
  • Global auto parts companies are making efforts to develop EWP(: Electric Water Pump) which is one of the core parts of environment friendly car. In eco-friendly automobiles, an independent cooling system is used rather than a cooling system that is linked to an internal combustion engine. Therefore, the research and development of the water pump operating separately from the engine and the related production system are being actively carried out. In order to overcome the shortcoming of EWP of PPS material suitable for injection system, G company which is a global parts company that researches and develops EWP around SUS and is in the process of developing robot-based production equipment for mass production. In this paper, a heat shock simulation system is designed and implemented that works with the robot-based production system to test the performance of the produced EWP. By using this system, it is possible to test the EWP in an virtual environment similar to the actual environment, thereby reducing the defect rate of the product. At the same time, all the data produced during the entire process for testing can be stored, which can be utilized in the future development of CPS(: Cyber Physical System) of EWP system based on big data.

Conjugate Simulation of Heat Transfer and Ablation in a Small Rocket Nozzle (소형 시험모터의 노즐 열전달 및 삭마 통합해석)

  • Bae, Ji-Yeul;Kim, Taehwan;Kim, Ji Hyuk;Ham, Heecheol;Cho, Hyung Hee
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.30 no.2
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    • pp.119-125
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    • 2017
  • Ablative material in a rocket nozzle is exposed to high temperature combustion gas, thus undergoes complicated thermal/chemical change in terms of chemical destruction of surface and thermal decomposition of inner material. Therefore, method for conjugate analysis of thermal response inside carbon/phenolic material including rocket nozzle flow, surface chemical reaction and thermal decomposition is developed in this research. CFD is used to simulate flow field inside nozzle and conduction in the ablative material. A change in material density and a heat absorption caused by the thermal decomposition is considered in solid energy equation. And algebraic equation under boundary layer assumption is used to deduce reaction rate on the surface and resulting destruction of the surface. In order to test the developed method, small rocket nozzle is solved numerically. Although the ablation of nozzle throat is deduced to be higher than the experiment, shape change and temperature distribution inside material is well predicted. Error in temperature with experimental results in rapid heating region is found to be within 100 K.