• 한국전산유체공학회:학술대회논문집
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• 2008.03a
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• pp.367-373
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• 2008

Spinning detonations propagating in a circular tube were numerically investigated with a one-step irreversible reaction model governed by Arrhenius kinetics. Activation energy is used as parameter as 10, 20, 27 and 35, and the specific heat ratio and the heat release are fixed as 1.2 and 50. The time evolution of the simulation results was utilized to reveal the propagation mechanism of single-headed spinning detonation. The track angle of soot record on the tube wall was numerically reproduced with various levels of activation energy, and the simulated unique angle was the same as that of the previous reports. The maximum pressure histories of the shock front on the tube wall showed stable pitch at Ea=10, periodical unstable pitch at Ea=20 and 27 and unstable pitch consisting of stable, periodical unstable and weak modes at Ea=35, respectively. In the weak mode, there is no Mach leg on the shock front, where the pressure level is much lower than the other modes. The shock front shapes and the pressure profiles on the tube wall clarified the mechanisms of these stable and unstable modes. In the stable pitch at Ea=10, the maximum pressure history on the tube wall remained nearly constant, and the steady single Mach leg on the shock front rotated at a constant speed. The high and low frequency pressure oscillations appeared in the periodical unstable pitch at Ea=20 and 27 of the maximum pressure history. The high frequency was one cycle of a self-induced oscillation by generation and decay in complex Mach interaction due to the variation in intensity of the transverse wave behind the shock front. Eventually, sequential high frequency oscillations formed the low frequency behavior because the frequency behavior was not always the same for each cycle. In unstable pitch at Ea=35, there are stable, periodical unstable and weak modes in one cycle of the low frequency oscillation in the maximum pressure history, and the pressure amplitude of low frequency was much larger than the others. The pressure peak appeared after weak mode, and the stable, periodical unstable and weak modes were sequentially observed with pressure decay. A series of simulations of spinning detonations clarified that the unsteady mechanism behind the shock front depending on the activation energy.

• 한국전산유체공학회:학술대회논문집
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• 2008.10a
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• pp.367-373
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• 2008

Spinning detonations propagating in a circular tube were numerically investigated with a one-step irreversible reaction model governed by Arrhenius kinetics. Activation energy is used as parameter as 10, 20, 27 and 35, and the specific heat ratio and the heat release are fixed as 1.2 and 50. The time evolution of the simulation results was utilized to reveal the propagation mechanism of single-headed spinning detonation. The track angle of soot record on the tube wall was numerically reproduced with various levels of activation energy, and the simulated unique angle was the same as that of the previous reports. The maximum pressure histories of the shock front on the tube wall showed stable pitch at Ea=10, periodical unstable pitch at Ea=20 and 27 and unstable pitch consisting of stable, periodical unstable and weak modes at Ea=35, respectively. In the weak mode, there is no Mach leg on the shock front, where the pressure level is much lower than the other modes. The shock front shapes and the pressure profiles on the tube wall clarified the mechanisms of these stable and unstable modes. In the stable pitch at Ea=10, the maximum pressure history on the tube wall remained nearly constant, and the steady single Mach leg on the shock front rotated at a constant speed. The high and low frequency pressure oscillations appeared in the periodical unstable pitch at Ea=20 and 27 of the maximum pressure history. The high frequency was one cycle of a self-induced oscillation by generation and decay in complex Mach interaction due to the variation in intensity of the transverse wave behind the shock front. Eventually, sequential high frequency oscillations formed the low frequency behavior because the frequency behavior was not always the same for each cycle. In unstable pitch at Ea=35, there are stable, periodical unstable and weak modes in one cycle of the low frequency oscillation in the maximum pressure history, and the pressure amplitude of low frequency was much larger than the others. The pressure peak appeared after weak mode, and the stable, periodical unstable and weak modes were sequentially observed with pressure decay. A series of simulations of spinning detonations clarified that the unsteady mechanism behind the shock front depending on the activation energy.

• Journal of the Korean Society for Heat Treatment
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• v.9 no.2
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• pp.121-129
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• 1996

The solubility of Ti in Al matrix was determined by X-ray diffraction method on two different mechanical alloying systems, i.e Al+$Al_3Ti$ and Al+Ti alloys. Starting powder compositions of two systems were chosen for final volume fraction of $Al_3Ti$ phase being 25%. The solubility of Ti in ${\alpha}$-Al was estimated by the lattice parameter measurement of Al. For Al+$Al_3Ti$ mixture, it appeared that some of $Al_3Ti$ particles decomposed during milling and maximum solubility of Ti in Al was about 0.99%. The majority of $Al_3Ti$ particles were dispersed uniformly in Al matrix, having approximate size of 100~200 nm. On the other hand, higher Ti solubility of 1.24 wt.% was found in Al+Ti system, with starting composition of Al+10 wt.%Ti. After 15 hours of milling, Ti phase was identified as 20 nm sized particles embedded in Al matrix. The annealing of mechanically alloyed powders from Al+$Al_3Ti$ and Al+10 wt.%Ti systems was followed in the temperature range of 200 to $600^{\circ}C$ to study thermal stability of supersaturated solution of Al(Ti). After annealing, the lattice parameter of Al reverted back to that of pure Al, and the peak intensity ratio of $Al_3Ti$/Al was increased more than the original value before annealing. These results suggest that Ti dissolve into alpha-Al solutions during milling, and by annealing, $Do_{22}-Al_3Ti$ phase forms from Al(Ti) solution.

• Journal of the Korean Ceramic Society
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• v.47 no.4
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• pp.343-352
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• 2010

A zirconia gel/polymer hybrid nanofiber was produced in a nonwoven fabric mode by electrospinning a sol derived from hydrolysis of zirconium butoxide with a polyvinyl butyral. Results indicated that the hydroxyl groups on the vinyl alcohol units in the backbone of the polymer were involved in the hydrolysis as well as grafting the hydrolyzed zirconium butoxide. In addition, use of acetic acid as a catalyst resulted in further hydrolysis and condensation in the sol, which led to the growth of -Zr-O-Zr- networks among the polymer chains. These networks gradually transformed into a crystalline zirconia structure upon heating. The as-spun fiber was smooth but partially wrinkled on the surface. The average fiber diameter was $690{\pm}110\;nm$. The fiber exhibited a strong but broad blue photoluminescence with its maximum intensity at a wavelength of ~410 nm at room temperature. When the fiber was heat-treated at $400^{\circ}C$, the fiber diameter shrunk to $250{\pm}60\;nm$. Nanocrystals which belonged to a tetragonal zirconia phase and were ~5 nm in size appeared. A strong white photoluminescence was observed in this fiber. This suggests that oxygen or carbon defects associated with the formation of the nanocrystals play a role in generating the photoluminescence. Further heating to $800^{\circ}C$ resulted in a monoclinic phase beginning to form In the heat-treated fibers, coloring occurred but varied depending on the heating temperature. Crystallization, coloring, and phase transition to the monoclinic structure influenced the photoluminescence. At $600^{\circ}C$, the fiber appeared to be fully crystallized to a tetragonal zirconia phase.

• Journal of Periodontal and Implant Science
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• v.47 no.3
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• pp.174-181
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• 2017

Purpose: Epitope spreading is a phenomenon in which distinct subdominant epitopes become major targets of the immune response. Heat shock protein (HSP) 60 from Porphyromonas gingivalis (PgHSP60) and peptide 19 from PgHSP60 (Pep19) are immunodominant epitopes in autoimmune disease patients, including those with periodontitis. It remains unclear whether Pep19 is a dominant epitope in subjects without periodontitis or autoimmune disease. The purpose of this study was to determine the epitope spreading pattern and verify Pep19 as an immunodominant epitope in healthy teenagers using dot immunoblot analysis. The patterns of epitope spreading in age-matched patients with type 1 diabetes mellitus (type 1 DM) and healthy 20- to 29-year old subjects were compared with those of healthy teenagers. Methods: Peptide from PgHSP60, Mycobacterium tuberculosis HSP60 (MtHSP60), and Chlamydia pneumoniae HSP60 (CpHSP60) was synthesized for comparative recognition by sera from healthy subjects and patients with autoimmune disease (type 1 DM). Dot immunoblot analysis against a panel of peptides of PgHSP60 and human HSP60 (HuHSP60) was performed to identify epitope spreading, and a densitometric image analysis was conducted. Results: Of the peptide from PgHSP60, MtHSP60, and CpHSP60, PgHSP60 was the predominant epitope and was most consistently recognized by the serum samples of healthy teenagers. Most sera from healthy subjects and patients with type 1 DM reacted more strongly with PgHSP60 and Pep19 than the other peptides. The relative intensity of antibody reactivity to Pep19 was higher in the type 1 DM group than in the healthy groups. Conclusions: Pep19 is an immunodominant epitope, not only in autoimmune disease patients, but also in healthy young subjects, as evidenced by their robust immunoreactivity. This result suggests that the Pep19-specific immune response may be an initiator that triggers autoimmune diseases.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.6
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• pp.734-743
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• 1999

The local Nusselt numbers have been measured for a round turbulent jet impinging on the concave surface with and without rib. Liquid crystal/transient method was used to determine the Nusselt number distributions along the surface. The temperature on the surface was measured using liquid crystal and a digital color image processing system. The experiments were made for the jet Reynolds number (Re) 23,000, the dimensionless nozzle-to-surface distance (L/d) from 4 to 10, the dimensionless surface curvature (d/D) 0.056, and the rib type (height ($d_1$) 0.2 cm, pitch (p) from 1.2 to 3.2 cm). It was founded that only when $L/d{\geq}6$, the average Nusselt numbers on the concave surface with rib are higher than those without rib, mainly due to an increase in the turbulent intensity caused by the effect of rib attached to the wall surface. It was realized that the rib attached to the concave surface may no longer enhance the heat transfer rate or even lowers it depending on the rib type and flow conditions. In addition, the results by the steady-state method using the gold-film Intrex were in good agreement with those by the transient shroud method.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.9
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• pp.799-805
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• 2013

An analytical study is conducted to assess the efficiency of a flat-plate solar collector using nanofluids. The nondimensionalized 2D heat diffusion equation is solved by assuming a wavelength-independent extinction coefficient and intensity to obtain the analytical solution of the temperature distribution in the flat-plate solar collector. The dimensionless temperature distribution is investigated as functions of the volume fraction of the nanofluids, magnitude of heat loss, and collector's depth based on the analytical solution when using water-based single-walled carbon nanohorn (SWCNH) nanofluids as a working fluid. Finally, the efficiency of the flat-plate solar collector using the nanofluids is predicted and compared with that of the conventional solar collector. The results indicate that the efficiency of the nanofluid solar collector is better than that of the conventional solar collector under specific geometrical conditions.

• Atmosphere
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• v.21 no.3
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• pp.257-271
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• 2011

The aim of this study is to examine weather modification by urbanization and human activities. The characteristics of the urban heat island (UHI) and precipitation in Seoul metropolitan area of Korea are investigated to demonstrate that cities can change or modify local and nearby weather and climate, and to confirm that cities can initiate convection, change the behavior of convective precipitation, and enhance downstream precipitation. The data used in this study are surface meteorological station data observed in Seoul and its nearby 5 cities for the period of 1960 to 2009, and 162 Automatic Weather System stations data observed in the Seoul metropolitan area from 1998 to 2009. Air temperature and precipitation amount tend to increase with time, and relative humidity decreases because of urbanization. Similar to previous studies for other cities, the average maximum UHI is weakest in summer and is strong in autumn and winter, and the maximum UHI intensity is more frequently observed in the nighttime than in the daytime, decreases with increasing wind speed, and is enhanced for clear skies. Relatively warm regions extend in the east-west direction and relatively cold regions are located near the northern and southern mountains inside Seoul. The satellite cities in the outskirts of Seoul have been rapidly built up in recent years, thus exhibiting increases in near-surface air temperature. The yearly precipitation amount during the last 50 years is increased with time but rainy days are decreased. The heavy rainfall events of more than $20mm\;hr^{-1}$ increases with time. The substantial changes observed in precipitation in Seoul seem to be linked with the accelerated increase in the urban sprawl in recent decades which in turn has induced an intensification of the UHI effect and enhanced downstream precipitation. We also found that the frequency of intense rain showers has increased in Seoul metropolitan area.

• Journal of Surface Science and Engineering
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• v.47 no.4
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• pp.192-197
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• 2014

Red-emitting nitride phosphors recently attracted considerable attention because of their high thermal stability and high color rendering index properties. For excellent phosphor of white light-emitting-diode, ternary nitride phosphor of $Sr/SmSi_5N_8:Eu^{2+}$ with different $Eu^{2+}$ ion concentration were synthesized by solid state reaction method. In this work, red-emitting nitride $Sr/SmSi_5N_8:Eu^{2+}$ phosphor was successfully synthesized by using multi-step high frequency induction heat treatment. The effects of molar ratio of component and experimental conditions on luminescence property of prepared phosphors have been investigated. The structure and luminescence properties of prepared $Sr/SmSi_5N_8:Eu^{2+}$ phosphors were investigated by XRD and photoluminescence spectroscopy. The excitation spectra of $Sr/SmSi_5N_8:Eu^{2+}$ phosphors indicated broad excitation wavelength range of 300 - 550 nm, namely from UV to visible area with distinct enhanced emission peaks. With an increase of $Eu^{2+}$ ion concentration, the peak position of emission in spectra was red-shifted from 613 to 671 nm. After via multi-step heat treatment, prepared phosphor showed excellent luminescence properties, such as high emission intensity and low thermal quenching, better than commercial phosphor of $Y_3Al_5O_{12}:Ce^{3+}$. Using $Eu_2O_3$ as a raw material for $Eu^{2+}$ dopant with nitrogen gas flowing instead of using commercial EuN chemical for $Sr/SmSi_5N_8:Eu^{2+}$ synthesis is one of characteristic of this work.

• Tunnel and Underground Space
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• v.23 no.6
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• pp.572-580
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• 2013

In this case study, I examined the microseismic safety management system of Deep Heat Mining Basel (DHMB) as EGS Geothermal Project which was conducted in Basel, Switzerland. EGS Geothermal Power projects which require induced seismic event by stimulation for creation of EGS geothermal reservoir have to be controlled pressure and flow rate of stimulation by establishment of microseismic safety management system. Traffic light system and Communication response procedure of DHMB project to respond step by step corresponding microseismic event intensity through continuous monitoring during stimulation period have been managed and established in advance of stimulation. However, the project was discontinued because of an earthquake to occur larger than expected one due to post-injection seismicity occurring in the geothermal reservoir after completion of injection for stimulation. The result of post analysis, Real-time traffic light system was verified to need a establishment of new microseismic safe management system to be considered post-injection seismicity phenomenon.