• Title/Summary/Keyword: Heat Cycle

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Effect of Calcination Temperatures on the Structure and Electrochemical Characterization of Li(Ni0.5Mn0.3Co0.2)O2 as Cathode Material by Supercritical Hydrothermal Synthesis Method (초임계 수열법으로 합성한 Li(Ni0.5Mn0.3Co0.2)O2 양극 활물질의 소성 온도영향에 따른 구조 및 전기화학적 특성)

  • Choo, Soyeon;Beom, YunGyeong;Kim, Sungsu;Han, Kyooseung
    • Journal of the Korean Electrochemical Society
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    • v.16 no.3
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    • pp.151-156
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    • 2013
  • As the cathode material for li-ion battery, $LiNi_{0.5}Mn_{0.3}Co_{0.2}O_2$ were synthesized by supercritical hydrothermal method and calcined $850^{\circ}C$ and $900^{\circ}C$ for 10hrs in air. The effect of temperature in the heat treatment on the powder and its performance were studied of xray diffraction pattern, SEM-image, physical properties and electrochemical behaviors. As a result, calcined at $900^{\circ}C$ material particle size more increase than calcined at $850^{\circ}C$ material, especially shows excellent electrochemical performance with initial reversible specific capacity of 163.84 mAh/g (0.1C/2.0-4.3V), 186.87 mAh/g (0.1C/2.0-4.5V) and good capacity retention of 91.49% (0.2C/2.0-4.3V) and 90.36% (0.2C/2.0-4.5V) after 50th charge/discharge cycle.

Effect of Ozone Treatment for Safety Improvement of Fresh Vegetable Juice (녹즙의 위생화를 위한 오존처리의 효과)

  • Cho, Jae-Min;Kwon, Sang-Chul;Tu, Gi;Jeong, Jae-Hyun;Lee, Kyung-Haeng
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.38 no.5
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    • pp.612-617
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    • 2009
  • Fresh vegetable juice is a non-heat treated product and the only step to reduce microbial growth is washing. Therefore, the materials for fresh vegetable juice including Angelica keiskei, Brassica loeracea var. acephala, and Daucus carota L. were treated by ozone after the first washing process and investigated for microbial and chemical changes. The number of the total aerobic bacteria in materials after selection step were $8.2{\times}10^5{\sim}5.0{\times}10^6\;CFU/g$, which was a higher contamination level than the limit of Korea food code ($10^5\;CFU/g$). However, after the 1st washing process and ozone treatment, the total aerobic bacterial number was reduced to $4.7{\times}10^4{\sim}6.7{\times}10^4\;CFU/g$, which showed 2 log microbial reduction. After the 2nd washing step followed by ozone treatment, there was no difference in microbial number. The number of colifroms in the materials of fresh vegetable juice were $8.0{\times}10^3{\sim}3.5{\times}10^3\;CFU/g$ initially but showed $1.5{\times}10^2{\sim}3.0{\times}10^2\;CFU/g$ after the ozone treatment (1 log reduction). On the other hand, there was no changes in the contents of ascorbic acid, flavonoids, polyphenols, minerals (cadmium and lead) during all processes. In addition, no color changes were observed during washing process. Therefore, ozone treatment in the materials of fresh vegetable juice decreased the microbial numbers. Also, chemical characteristics of ozone treated sample were not different when compared with control.

Study of Benefit Characteristics for Low Impact Development (LID) Facilities demonstrated in Seoul Metropolitan (서울시 저영향개발(LID) 시범 시설에 대한 편익 특성 연구)

  • Lee, Seung Won;Kim, Reeho
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.6
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    • pp.299-308
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    • 2016
  • Seoul metropolitan has established a vision as 'Healthy water-cycle city' to resolve urban water-environmental deterioration. And it established administrative structure to expand Low Impact Development (LID) facilities to recover aggravated water-cycle and water-environment. Therefore, various LID facilities are constructed and operated, however, benefit analytic plans for systematic valuation are insufficient. In this study, to analyze economic, environmental and social benefits of LID facilities, contents for benefit analysis were selected and categorized as water, energy, air quality and climate changes. As a result of quantification and valuation to the beneficial effects, LID facilities showed the total benefit as 1,191~3,292 won/yr. Characteristics of benefit distribution by analysis contents were various reflecting functional characteristics of each LID facility (Water: 30~90%, Energy: 4~44%, Air quality: <1~2%, Climate change: 5~22%). As a result of Triple Bottom Line analysis, economic benefit showed the greatest portion as 75~90%. As further studies, suggested benefit assessment plans for each LID facility should be applied to inter-connected LID systems on complex-scaled area, and synergy effects by various LID systems would be evaluated such as prevention of heat island and flood disasters.

Study of the Recycling Policy to Make Efficient Resource-recycling Society (효율적(效率的)인 자원순환사회 형성을 위한 자원재활용(資源再活用) 정책 고찰(考察))

  • Ryu, Su-Ho
    • Resources Recycling
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    • v.18 no.2
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    • pp.3-15
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    • 2009
  • To accomplish the greenhouse gas reduction which is over core unit project of the "Green growth" policy and "Resource circulation society", it is important to maintain proper balance and complement between energy recovery from waste and material recycling. This research(study) examined the related policies on the past of korea and foreign country, and also "The 4th resource recycling master plan" and "Energy recovery from waste plan" to provide advisable direction for resource recycling policy. The results of the research(study) showed that there were no significant difference between korea and developed foreign countries waste management policies. But in German policy, energy recovery from waste and pre-treatment are importantly considered and highly required for permission. Under current circumstance in korea, recycling will be more difficult than in the past. According to "The 4th resource recycling master plan", film type of synthetic resin was not sustainable recycled material in substance."Energy recovery from waste plan", proved that the energy recovery from RDF/RPF have lower efficiency than regular incineration generation and substance recycling. To solve these problems, the energy and remainder heat recovery must be generalized to "Energy recovery" concept and institutional improvement such as LCA(Life Cycle Assessment) system are need to support it. And also technology development to extract synthetic polymer by dissolved film type of synthetic resin must be provided.

Eco-Industrial Park (EIP) Development and Key Technologies for Clean Production (청정 생산을 위한 생태산업단지 구축과 주요기술)

  • Yoo, ChangKyoo;Heo, Soon-Ki;Yoo, Dong Joon;Lee, SeungJun;Shin, Ji Na;Park, Yong Joon;Yoon, Hack Mo;Chun, Hee Dong;Moon, Jeong Ki;Lee, In-Beum
    • Korean Chemical Engineering Research
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    • v.43 no.5
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    • pp.549-559
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    • 2005
  • Sustainable industrial development which can minimize an ecological effect by the mankind exertion is recently interested due to an environmental contamination and a resource exhaustion problem. An eco-industrial park (EIP) is a community of manufacturing and service businesses seeking enhanced environmental and economic performance through collaboration in managing environmental and resource issues, including energy, water, and materials. EIP developments which improve a production plant within an eco-friendly greenfield and design a new industrial ecosystem are accomplished recently, which can efficiently re-use the waste and resources from each company within EIP. In this review, the outside and domestic case studies of EIP and cornerstone technologies to develop the EIP, such as energy integration, waste reuse, mass flow analysis, water pinch, and life cycle assessment, are summarized.

On the Diurnal Variation of Cloudiness over the Weatern Pacific by Using GMS-IR Data (GMS-IR 자료를 이용한 서태평양에서의 운량 일변동에 관한 연구)

  • 김영섭;한경수
    • Korean Journal of Remote Sensing
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    • v.13 no.1
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    • pp.1-12
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    • 1997
  • The western equatorial Pacific Ocean, where sea surface temperature is the warmest on the globe, is characterized by numerous convective systems and large annual precipitation. In this region, the cloudiness data with tops higher than 8km level obtained from the GMS-IR data are used to investigate the diurnal variation of cloudiness. The amplitude and phase of diurnal and semi-diurnal cycles are mainly investigated to examine details on the temporal and spatial structure of clouds. Cloudiness variation has typical cycles and each cycle is associated with the air-sea interactive phenomena. Spectral analysis on the cloudiness time series data indicates that 30-60 day, 17-20day, 7-8 day, diurnal and semi diurnal cycle are peaked. During Northern Winter and Southern Summer, the large cloudiness exsists over New Guinea, the adjacent seas of North Australia, and the open oceanic regions east of $160^{\circ}$E. Cloudiness diurnal variability over the lands and their adjacent seas is about 2.0 times larger than that over the open sea regions. That may be due to the difference of specific heat between the land and sea. The maximum and minimum cloudiness appeared at 18:00 and 09:00 hours over the land, and at noon and 21:00 hours over the sea, respectively. The amplitude of diurnal component over the land is 4,7 times larger than that of semi-diurnal component, and 1.5 times over the sea.

A Case Study on Economic Analysis of a Solar Water Heating System and a Ground Source Heat Pump System Applied to a Military Building (군 복지시설의 지열시스템과 태양열시스템 경제성 평가 사례 연구)

  • Lee, Jong-Chan;Park, Young-Ho;Lee, Ghang;Lee, Sang-Ho
    • Korean Journal of Construction Engineering and Management
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    • v.10 no.4
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    • pp.111-118
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    • 2009
  • This study is to analyze the performance of SWH(Solar Water Heating) and GSHP(Ground Source Heat Pump) systems by evaluating their energy efficiency and LCC(Life Cycle Cost) as being applied to the OO hall as a selected building in the Army. The OO hall, used as bathrooms, dining rooms, accommodations and offices, has reinforced concrete structure system with three floors above the ground and one underground, and its total floor area is approximately 2,917$m^2$. Two energy simulations are conducted to predict the yearly cooling and heating energy of the selected building: One is for analysis of an air-conditioning energy consumption using the e-Quest program, and another is for two new-renewable energy facilities as a water heating source using the RETScreen. The installed capacity of two new-renewable energy facilities is determined according to the 5% level of total standard construction cost. As a briefly result, SWH system is more energy-effective than GSHP system. Considering the break-even point, it is expected that SWH can take only 3 years 11 months to pay for itself in savings while the investment of GSHP can be recovered in more than 16 years 6 months.

Parametric Study for the Optimal Integration Design between the Gas Turbine Compressor and the Air Separation Unit of IGCC Power Plant (석탄가스화 복합발전플랜트 가스터빈 압축기와 공기분리장치 간의 최적 연계설계를 위한 매개변수연구)

  • Lee, Chan;Kim, Hyung-Taek
    • Journal of Energy Engineering
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    • v.5 no.2
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    • pp.160-169
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    • 1996
  • Parametric studies are conducted for optimizing the integration design between gas turbine compressor and air separation unit (ASU) of integrated gasification combined cycle power plant. The present study adopts the ASU of double-distillation column process, from which integration conditions with compressor such as the heat exchanger condition between air and nitrogen, the amount and the pressure of extracted air are defined and mathematically formulated. The performance variations of the compressor integrated with ASU are analyzed by combining streamline curvature method and pressure loss models, and the predicted results are compared with the performance test results of actual compressors to verify the prediction accuracy. Using the present performance prediction method, the effects of pinch-point temperature difference (PTD) in the heat exchanger, the amount and the pressure of extracted air on compressor performances are quantitatively examined. As the extraction air amount or the PTD is increased, the pressure ratio and the power consumption of compressor are increased. The compressor efficiency deteriorates as the increase of the flow rate of air extracted at higher pressure level while improving at lower pressure air extraction. Furthermore, through the characteristic curve between generalized inlet condition and efficiency of compressor, optimal integration condition is presented to maximize the compressor efficiency.

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Effects of Construction and Operation of Nuclear Power Plants on Benthic Marine Algae (원자력발전소의 건설과 가동이 저서 해조류에 미치는 영향)

  • 김영환
    • Korean Journal of Environmental Biology
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    • v.17 no.4
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    • pp.379-387
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    • 1999
  • During the past several decades, electricity generating plant increased with remarkable rapidity in Korea. Recently the increase has been much more rapid as the rate of industrialization has accelerated. Construction of nuclear power plants in coastal areas inevitably caused the perturbation of critical coastal habitats and thus influenced marine algal species composition. Particularly, an increase in the building of nuclear power plants led the amounts of heat discharged to increase exponentially. As far as the effects of cooling water and thermal discharges are concerned, benthic marine algae are likely to be vulnerable to a discharge. Heated effluents from nuclear power plants, with the temperature rises of 7~12$^{\circ}C$ under normal operating and design conditions, are discharged through the discharge canal and into natural water bodies. It is clear that the characteristic marine algal community is developed in the area affected by the thermal discharges; i.e. low species richness and low species diversity. Nevertheless, it is worthwhile to note that elevated temperatures exert differential effects depending on the algal populations. Benthic marine algae grown at the discharge canal can be regarded as warm tolerant species. 35 species (4 blue-green, 9 green, 8 brown and 14 red algae) of marine algae occurred more than 20eye frequency at discharge canal of three nuclear power plants in the east coast during 1992 ~ 1998 and thus can be categorized as warm tolerant species in Korea. To minimize the ecological impacts of waste heat on benthic marine algae, it is recommended that, in the future, nuclear power plants will have to employ some form of closed-cycle cooling for the condensers.

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Combustion Performance Test of Syngas Gas in a Model Gas Turbine Combustor - Part 2 : NOx/CO emission Characteristics, Temperature Characteristics and Flame Structures (모델 가스터빈 연소기에서 합성가스 연소성능시험 - Part 2 : NOx/CO 배출특성, 온도특성, 화염구조)

  • Lee, Min Chul;Yoon, Jisu;Joo, Seong Pil;Yoon, Youngbin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.8
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    • pp.639-648
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    • 2013
  • This paper describes on the NOx/CO emission characteristics, temperature characteristics and flame structures when firing coal derived synthetic gas especially for gases of Buggenum and Taean IGCC. These combustion characteristics were observed by conducting ambient-pressure elevated-temperature combustion tests in GE7EA model combustor when varying heat input and nitrogen dilution ratio. Nitrogen addition caused decrement in adiabatic flame temperature, thus resulting in the NOx reduction. At low heat input condition, nitrogen dilution raised the CO emission dramatically due to incomplete combustion. These NOx reduction and CO arising phenomena were observed at certain flame temperature of $1500^{\circ}C$ and $1250^{\circ}C$, respectively. As increasing nitrogen dilution, adiabatic flame temperature and combustor liner temperature were decreased and singular points were detected due to change in flame structure such as flame lifting. From the results, the effect of nitrogen dilution on the NOx/CO and flame structure was examined, and the test data will be utilized as a reference to achieve optimal operating condition of the Taean IGCC demonstration plant.