• Title/Summary/Keyword: Hazardous heavy metal

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The Effect of Productivity on Regional Harzardous Environment in Large National Industrial Complex (대형 국가산업단지의 생산성이 지역 유해 환경 변화에 미치는 영향)

  • Jun, Yun Sang;Han, Kyoung Hoon;Chun, Yu Jin;Jo, Seoweon;Kim, Jin Ho
    • Clean Technology
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    • v.24 no.3
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    • pp.255-266
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    • 2018
  • In this paper, the effects of large national industrial complexes on the generation of local hazardous substances were analyzed based on their size, industrial characteristics. In Seoul, the proportion of hazardous substances, which adversely affect the atmosphere of the entire city, was much less than that of other regional industrial complexes, centered on knowledge-based industries. On the other hand, other national industrial complexes based on manufacturing industries, such as machinery, metal, electricity, and electronics, were found to have a combination of industry characteristics and logistics and regional characteristics. Overall, it was found that the increase in productivity in large national industrial complexes was not proportional to the increase in hazardous substances throughout the region. In addition, it was also found that in North Gyeongsang Province, which is based on the heavy chemical industry, the percentage of hazardous substances is different from other regions due to the characteristics of the industry.

Assessment for Exposure Levels of Hazardous Substances in Kids Cafes within Some Metropolitan Area (일부 수도권지역에서의 키즈카페 내 유해물질 노출수준 평가)

  • Kim, Ho-Hyun;An, Sun-Min;Lee, Jae-Young;Choi, In-Seak;Lee, Jeong-Hun;Nam, Yi-Hyun;Yoo, Si-Eun;Jung, Da-Young;Lee, Chul-Woo;Park, Choong-Hee
    • Journal of Environmental Health Sciences
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    • v.45 no.1
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    • pp.54-61
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    • 2019
  • Objectives: In this study, we investigated an assessment for exposure levels of hazardous substances to kids cafes that unregulated by law. Methods: Heavy metals, volatile organic compounds, formaldehyde, pesticides and phthalate were measured at 20 kids cafes in Gyeonggi-do and Incheon. Samplings were conducted from April to July in 2018. Results: Heavy metals were detected over the standard mainly around the floor and walls in the 19 kids cafes. Pesticides were detected in 7 locations with chlorpyrifos, diazinon and cypermethrin, and showed the highest detection level of chlorpyrifos. The concentrations of DEHP in all kids cafes were exceeded with standard. The risk assessment results showed that HCHO as carcinogen had a safety level and DEHP as non-carcinogens had a safety level as assessed to be under than 0.1. Conclusions: Considering the exposure investigation results and the importance of child health protection, kids cafe should be included in the legal management list of children's activities zones.

Study on Transfer Rate of Hazardous Materials in Herbal Medicine Prescriptions (한방처방 전탕 단계별 위해물질의 이행률에 대한 연구)

  • Seo, Chang-Seob;Kim, Jung-Hoon;Ha, Hye-Kyung;Lee, Mee-Young;Lee, Jun-Kyoung;Lee, Nam-Hun;Lee, Ho-Young;Lee, Jin-Ah;Lee, Sul-Lim;Shin, Hyeun-Kyoo
    • The Journal of Korean Medicine
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    • v.31 no.4
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    • pp.9-19
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    • 2010
  • Objective: To compare the contents and transfer rate of hazardous substances in crude, washing solution, crude after washing, decoction and remnant after boiling. Methods: The heavy metal contents of each step were measured by inductively coupled plasma mass spectrometer (ICP-MS) and mercury analyzer (SP-3DS). In order to analyze pesticides in each sample we used simultaneous multi-residue analysis of pesticides by GC/ECD, which was followed by GC/MSD analysis to confirm the identity of the detected pesticide in each sample. In addition, the contents of sulfur dioxide ($SO_2$) were performed by Monier-Williams distillation method. Results: 1. Contents (mg/kg) of heavy metals were not detected in decoctions of any tested herbal medicine prescriptions. 2. Transfer rates (%) of heavy metals from crude to remnant were as follows: Yijin-tang (As: 46.9, Cd: 50.0 and Pb: 100.0), Oryung-san (As: 80.0, Cd: 100.0 and Pb: 73.8), Hwangryunhaedok-tang (As: 88.9, Cd: 71.4 and Pb: 92.7), Bangpungtongseong-san (As: 100.0, Cd: 17.3 and Pb: 56.1), Oyaksungi-san (As: 47.4, Cd: 175.0 and Pb: 142.4). 3. Contents (mg/kg) of residual pesticides were not detected in any samples. 4. Transfer rate (%) of sulfur dioxide ($SO_2$) from crude to remnant in all samples were as follows: Yijin-tang (25.0), Oryung-san (166.7), Hwangryunhaedok-tang (50.0), Bangpungtongseong-san (181.8), Oyaksungi-san (50.0). Conclusion: Our results showed that the boiled herbal medicine prescriptions which we take are safe from the hazardous substances.

A Study on the Toys Assessment of Harmful Substances and Control (완구제품에 함유된 유해물질 및 관리방안에 대한 연구)

  • Kim, Seung-Don;Son, Ki-Sang
    • Journal of the Korean Society of Safety
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    • v.25 no.5
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    • pp.27-32
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    • 2010
  • This study is to investigate and compare domestic hazardous toys with harmful substances with foreign toys so that we can find out management criteria for in cognitive infants. Actually, commercially used toys have been collected and tested to find out more effective management standard. it is tried to produce evaluation criteria of environmentally harmful substance but variety of product is needed for overcoming actual barrier due to lot of difficulty huge cost, time, objectiveness. Therefore, This study does not cover all the above. Establishment of evaluation criteria for product harmfulness made by Government or Local government should be continued to improve. Foreign reference material for toy product in Europe, USA, Japan have been investigated and domestic product have been collected and tested for containing heavy metals, formaldehyde, phthalate in the study. All the test have been made in accordance with KSM ISO 2124 to measure heavy metal transfer into body. Toy product used for the study have been purchased in the real market and some of them contains harmful elements with over standard. Post management system such as RAPEX to control periodically should be established for plastic toy with low quality product.

Evaluation on Probability and Intensity of Hazards Exposure by Construction Occupations (건설업 직종별 노출 가능 유해인자 및 노출강도에 관한 평가)

  • Hyunhee Park;Sedong Kim
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.33 no.3
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    • pp.317-331
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    • 2023
  • Objectives: Construction workers are exposed to various hazardous substances simultaneously. However, little is known about the exposure hazards in construction industry. This study was aimed at identifying the risk of exposure hazards among construction workers. Methods: The expert survey (n=29) was conducted, including construction industry health managers (n=11) and work environment monitoring experts (n=18), on exposure probability, intensity and risk of hazardous substances by construction occupations Results: The exposure hazards of 30 construction occupations were identified and summarized through a literature review and expert survey. The most prevalent hazards were in order of noise, awkward posture, heat/cold, crystalline silica, cement/concrete dust, metal fumes, and volatile organic compounds. The hazards with highest risk score(over seven points) at construction occupations were noise(formwork carpenter, concrete finisher, rebar worker, demolition worker, driller/rock blaster), hazardous rays(welder), heat/cold (earthworks, formwork carpenter, rebar worker, concrete placer, scaffolder), awkward posture(bricklayer, caulker/tile setter, rebar worker) and heavy lifting(bricklayer, rebar worker). Among construction workers, the job types with the highest risk of exposure to carcinogens, and in which occupational cancer has been reported, were in order of stonemason, concrete finisher, rock blaster, welder, insulation installer, painter, scaffolder, plant worker and earthworks in order Conclusions: Systematic research and discussion on occupational disease among construction workers and its various hazardous factors are needed to establish job exposure matrix for facilitating standard for promptly processing the workers' compensation.

Organobentonite as a dual sorbent for Chlombenzene and Lead (클로로벤젠과 납의 동시 제거를 위한 흡착제로서의 유기 벤토나이트에 관한 연구)

  • 이정주;박재우;김일규
    • Journal of Soil and Groundwater Environment
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    • v.6 no.4
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    • pp.41-50
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    • 2001
  • The use of clay has been the favored method of reducing or eliminating hazardous contaminants in the leachate from landfills. But, neither natural clays nor organoclays modified with surfactants are able to effectively sorb both heavy metals and organic contaminants. Therefore, the objective of this study is to determine the optimal amount of surfactant added on the clay mineral to effectively remove both of them. For this purpose, Na-Bentonite as the natural clay, and hexadecyltrimethylammonium (HDTMA) as the cationic surfactant were used, Chlorobenzene and lead ($Pb^{2-}$) were selected as representative contaminants. Experimental result showed that chlorobenzene sorption increased with increasing HDTMA to bentonite, ratios. On the contrary, the removal rate of lead decreased as the amount of HDTMA increased. The removal of chlorobenzene was influenced by the amount of HDTMA added to the bentonites rather than initial concentration of chlorobenzene, but the removal of lead was much more influenced by the initial concentration of lead. The adsorption of lead was not affected by chlorobenzene, and vice versa. The competitive sorption between the heavy metal and the organic contaminant was not present.

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On the Generation and Processing of the Sludge Containing Heavy Metals in Korea (우리나라 重金屬 함유 汚泥의 發生과 處理)

  • On, Jae-Hyun;Kim, Mi-Sung;Shin, Hee-Duck
    • Resources Recycling
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    • v.13 no.5
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    • pp.3-16
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    • 2004
  • There are over 190,000 tons per year of the sludge containing heavy metals (SHM) generated from industries in Korea. The SHM is so hazardous waste, it needs proper intermediate treatment before final disposal. At present, the common intermediate treatment and final disposal technologies of SHM are solidification and landfill. However, the future treatment and disposal technologies of SHM will be carry out to fulfill in both the environmental aspect and resource recycling. Thus, how to reduce the generation of SHM and recycle the valuable metal from SHM become the major subjects in the global world. In this article, in order to prospect the effective processing of SHM, the generation and processing of the sludge from plating wastewater, the research and development of valuable metal recycling technology and problems were summarized.

Pollution Characteristics of Hazardous Elements for Roadside Dust in Gwangju City, Korea (광주광역시 도로변 분진에 대한 유해원소의 오염특성)

  • Lee, Jang-Jon;Park, Young-Seog;Kim, Jong-Kyun;Han, Min-Su
    • Economic and Environmental Geology
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    • v.40 no.3 s.184
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    • pp.263-275
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    • 2007
  • The purpose of this study was to show the pollution characteristics of hazardous elements from roadside dust in the Gwangju city. We collected 47 samples from November to December in 2004 and separated four groups such as residential area, industrialized area, downtown area and heavy traffic area fer characteristics comparison on hazardous elements. Roadside dust mostly consisted of quartz, albite, microcline, muscovite in XRD analysis. Content of hazardous elements varied: As $3.4{\sim}11.9 ppm$, Cd $0.2{\sim}28.2 ppm$, Co $32{\sim}526 ppm$, Cr $25{\sim}526 ppm$, Cu $11{\sim}375 ppm$, Ni $14{\sim}247 ppm$, Pb $13{\sim}413 ppm$ and Zn $101{\sim}972 ppm$. Average contents of hazardous elements of Zn>Cu>Pb>Cr>Co>Ni>Cd. Content of hazardous elements was low in residential area, whereas that of heavy metal was much the same in both in heavy traffic area. Content of hazardous elements such as Cd, Co, Cr, Cu, Ni, Pb, Zn was found to be particularly high in industrialized area. According to these results it was possible to presume that industrialized area was affected by industry activity such as machinery, petrochemical, automobile and electronics industry. The SEM analysis, detected Pb, Cr, Ni, and Fe particles in samples of industrialized area contaminated by industry activity. The correlation coefficient table resulted from the samples of roadside dust showed that there was same direction increase of content between elements. In other words, when the content of Cd increase, Cr and Ni increase, as Cr increase, Cu and Ni increase, as Cu increase Ni increase and Pb increase Zn increase. Based on these results it was possible to predict and interpret similar contamination patterns in this study.

Characteristics of Hazardous Air Pollutant Emissions from Waste Incinerators (폐기물소각시설의 유해대기오염물질 배출특성 연구)

  • Park, J.M.;Lee, S.B.;Kang, J.G.;Kim, J.P.;Choi, E.S.;Hwang, W.G.;Kwon, O.S.
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.2
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    • pp.183-190
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    • 2007
  • In this study, we have investigated waste incinerators which are one of the major HAPs emission sources. In order to obtain more reliable HAPs emission data from waste incinerators, direct sampling for the possible pollutants from the stack was carried out and the analysis was performed. The purpose of study was to understand the emission status from waste incinerators and recognize the problems and finally to set up a strategy to reduce the HAPs emissions from waste incinerators. The emission concentrations of 8 species of heavy metals and 16 species of PAHs have been analyzed for the first time in Korea. Not only the emission characteristics of HAPs from waste incinerators were identified, but also the analysis of reduction efficiencies for control devices such as BF and wet scrubbing systems was carried out.

Exposure Assessment of Hazardous Substances in Small Academy of Children's Activity Zones (어린이 주요활동공간 중 소규모학원 내 유해물질 노출 평가)

  • Kim, Ho-Hyun;Lee, Jeong-Hun;An, Sun-Min;Lee, Jae-Young;Choi, In-Seak;Yoo, Si-Eun;Jung, Da-Young;Lee, Chul-Woo;Park, Choong-Hee
    • Journal of Environmental Health Sciences
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    • v.44 no.3
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    • pp.283-292
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    • 2018
  • Objectives: This study was conducted to identify hazardous factors that reflect the characteristics of the academy and to provide basic data of environmental safety standard. Methods: Heavy metals, volatile organic compounds, formaldehyde, pesticides and phthalates were measured in 20 academies, which were supplementary, music, art and physical education institutes. Results: In case of heavy metals, the 12 locations were detected for lead (Pb) over the standard value, and 15 locations were exceeded for the total heavy metal. In six locations, the concentrations of volatile organic compounds were exceeded the standard value of $400{\mu}g/m^3$, and two locations for formaldehyde were exceeded the standard value of $100{\mu}g/m^3$. The most commonly detected agents in the air dust were chlorpyrifos and diazinon. The concentrations of DEHP, DINP, and DBP were detected and exceeded in several academies, The risk assessment results showed that HCHO as carcinogen had a safety level of 10-7 to 10-6, and DEHP and DINP as non-carcinogens had a safety level as assessed to be under than 0.1. Conclusions: Through the investigation of long-term environmental and health effects related laws on academies, indoor air quality management might be needed because there were cases of exceeding standard.