• Title/Summary/Keyword: Hazardous

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Removal of haloacetonitrile by adsorption on thiol-functionalized mesoporous composites based on natural rubber and hexagonal mesoporous silica

  • Krueyai, Yaowalak;Punyapalakul, Patiparn;Wongrueng, Aunnop
    • Environmental Engineering Research
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    • v.20 no.4
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    • pp.342-346
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    • 2015
  • Haloacetonitriles (HANs) are nitrogenous disinfection by-products (DBPs) that have been reported to have a higher toxicity than the other groups of DBPs. The adsorption process is mostly used to remove HANs in aqueous solutions. Functionalized composite materials tend to be effective adsorbents due to their hydrophobicity and specific adsorptive mechanism. In this study, the removal of dichloroacetonitrile (DCAN) from tap water by adsorption on thiol-functionalized mesoporous composites made from natural rubber (NR) and hexagonal mesoporous silica (HMS-SH) was investigated. Fourier-transform infrared spectroscopy (FTIR) results revealed that the thiol group of NR/HMS was covered with NR molecules. X-ray diffraction (XRD) analysis indicated an expansion of the hexagonal unit cell. Adsorption kinetic and isotherm models were used to determine the adsorption mechanisms and the experiments revealed that NR/HMS-SH had a higher DCAN adsorption capacity than powered activated carbon (PAC). NR/HMS-SH adsorption reached equilibrium after 12 hours and its adsorption kinetics fit well with a pseudo-second-order model. A linear model was found to fit well with the DCAN adsorption isotherm at a low concentration level.

Application of Drones for the Analysis of Hazard Areas in Mountainous Disaster (산지재해 발생 위험지역 분석을 위한 드론의 적용)

  • Lee, Jeong Hoon;Jun, Kye Won;Jun, Byong Hee
    • Journal of the Korean Society of Safety
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    • v.33 no.3
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    • pp.65-70
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    • 2018
  • Terrain data for disaster analysis in hazardous or disaster areas is not only important but also needs to be built quickly. In particular, the introduction of drones is in the early stages of research using drones in a variety of fields such as shooting, analyzing and managing hazardous areas. It is expected that drone will be faster, safer and more effective than existing data collection method in case of small scale disaster hazard area and disaster area where equipment or manpower input is difficult. Therefore, in this study, drone shooting was performed for hazardous areas in mountainous roads located in Samcheok city, Gangwon province, and ground reference points were measured by RTK-GPS. The measured data were converted into DSM (Digital Surface Model) data by coordinate correction using Pix4D postprocessing program and then applied to the analysis of the hazard area of mountainous area. As a result, it was shown that it is effective to identify the risk by using the basic terrain data obtained from the drones.

Home Environmental Hazards of Falling Accident in the Elderly (노인가정의 낙상사고 위험 환경요인)

  • Park, Young-Hae;Moon, Jung-Soon
    • Korean Journal of Health Education and Promotion
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    • v.22 no.4
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    • pp.203-213
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    • 2005
  • Purpose: To assess the environmental hazards of falling accident in the homes of the elderly. Method: 222 homes of the elderly were assessed by the home environmental Checklist from May to July in 2003. Results: The mean score of home environmental hazards for fall were 13.19 with the highest score being 49, ranging from 4 to 24. The bathroom was the most hazardous place in the home, porch came next bedroom, kitchen, living room and stair followed them. The floor surface such as finishes and non-skid mats was the most hazardous interior factor in the home, using bathroom came next furniture and illumination followed them. The floor surface such as finishes and non-skid mats in the bathroom, kitchen, living room and porch, illumination of bedroom and stair were the most prevalent hazards in the home of interior. Of the 49 potential hazards, bathroom grab bar was the most prevalent one with 89.9%, and non-skid rugs in the porch, bathroom and kitchen, safety of dinner table, the threshold and furniture of porch, and illumination of bedroom were prevalent more than half of the home under assessing. Men, living in the separate house or villa with stairs were in more hazardous environments. Conclusion: To reduce the potential hazards of fall accident in the home, improving hazards relating to floor surface such as slip resistance surface and mats is important specially those of the separate house or villa with stairs.

A Developmental Study on Preventing Occupational Disease Programme in Small- Medium Sized Industries (보건관리대행사업장 직업병예방관리 사업 프로그램 개발에 관한 연구)

  • Lee Myung-Sook
    • Journal of Korean Public Health Nursing
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    • v.9 no.2
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    • pp.104-114
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    • 1995
  • This study was designed to develop preventing occupational disease programme in small-medium scale industries. The intervention was done in 354 enterprises from July to December in 1993 by health personnels in mobile occupational health centers. The summarized results of the above achievements were as follows. 1. Total number of enterprises were 354. Among them $66.9\%$ was under 100 workers, $26.6\%$ was u!1der 200 workers, and $6.5\%$ was belong to over 200 workers. The majority manufactures were non-metallic mineral product industries $(11.3\)$ fabricated metal product industries $(11.0\%)$. and textile industries $(10.7\%)$. 2. In 1993, for 350 enterprises were carried out evaluation of workplace environment. A total of $76.3\%$ industries were found to improper showing higher level of hazardous agent than the TLV. Noise and dust are the typical agent of which levels in workplace were high in most of industries. 3. A total 60 cases $(0.8\%)$ of occupational diseases were detected through physical check-up from 7,394 industrial workers in 1993. Detection rate by hazardous agent was highest among workers in relation to dust, and secondly highest to noise. 4. Through the systematic approach by hazardous agent was increased to the monitoring of work condition and follow up care of occupational disease. In future, there should be development in the scaled check list of preventing occupational disease management.

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Use of hazardous event frequency to evaluate safety integrity level of subsea blowout preventer

  • Chung, Soyeon;Kim, Sunghee;Yang, Youngsoon
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.8 no.3
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    • pp.262-276
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    • 2016
  • Generally, the Safety Integrity Level (SIL) of a subsea Blowout Preventer (BOP) is evaluated by determining the Probability of Failure on Demand (PFD), a low demand mode evaluation indicator. However, some SIL results are above the PFD's effective area despite the subsea BOP's demand rate being within the PFD's effective range. Determining a Hazardous Event Frequency (HEF) that can cover all demand rates could be useful when establishing the effective BOP SIL. This study focused on subsea BOP functions that follow guideline 070 of the Norwegian Oil and Gas. Events that control subsea well kicks are defined. The HEF of each BOP function is analyzed and compared with the PFD by investigating the frequency for each event and the demand rate for the components. In addition, risk control options related to PFD and HEF improvements are compared, and the effectiveness of HEF as a SIL verification for subsea BOP is assessed.

Discussions on the Disaster Management for NaTech based on the Foreign Case Studies (국외 NaTech 사례연구를 통한 재난관리 방안 고찰)

  • Yoo, Byungtae;Baek, Jong-bae;Ko, Jae-wook
    • Journal of the Korean Society of Safety
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    • v.31 no.1
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    • pp.111-117
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    • 2016
  • Natural disasters can cause major accidents in chemical facilities where they can lead to the release of hazardous materials which in turn can result in fires, explosions or toxic dispersion. Technological disasters triggered by natural disasters are referred to as NaTech(Natural Disaster Triggered Technological Disaster). These trends increase the probability of catastrophic future disasters and the potential for mass human exposure to hazardous materials released during disasters. In the present study, we proposed some methods for effective disaster management by conducting case study of major NaTech. First, establishing information sharing system of chemical accident for stakeholders and improving disaster manuals and standards of central and local government and co-operation support system. Second, activating information service of emergency planning and community right to know. Third, improving the integrated chemical accident database including NaTech accidents.

A Study of Emergency Response for the Leakage Accident of Hazardous and Noxious Substances in a Port (항만에서의 위험·유해물질(HNS) 누출사고 대응에 관한 연구)

  • Woo, Young Jin;Lee, Chang Jun
    • Journal of the Korean Society of Safety
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    • v.31 no.6
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    • pp.32-38
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    • 2016
  • In general, lots of containers including various dangerous materials are transported to the port located in big cities such as Busan where massive residents live. Thus, it's really important how to make the emergency response for the leak accidents of dangerous materials and evaluate the direct or indirect damages to adjacent areas. In this study, in order to make reasonable emergency plans, CA (Consequence Analysis) is employed after selecting a key hazardous and noxious material, hydrogen fluroide. This material accounts for the third largest portion of cargo volume among all dangerous materials and can cause a huge damage in case of leakages. As a case study, Busan North port is selected as a test port since the portion of dangerous materials is higher than that of other ports in Busan. It is assumed that 1 ton of hydrogen fluoride is spilled at Busan North port. CA is performed to assess the impact of this accident. Throughout CA, the ERPG-2 range of a leak accident can be evaluated and this result can be used for decision making tools for mitigating the impact of a leak accident. To mitigate the damage of this accident, suitable a protective equipment and resident evacuation procedures should be prepared. Finally, this study can provide a systematic approach to make the emergency plan for reducing economical and personal losses.

Determination of PCDD/Fs in Disposable Diaper for Infant (유아용 일회용 기저귀의 다이옥신 분석)

  • Shin Jeoung Hwa;Ahn Yun Gyong;Seo Jung Ju
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.6
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    • pp.814-824
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    • 2005
  • This study analyzed and standardized the harmful substances of organic compounds(dioxins) in disposable diapers for infant's clothing. Commercial samples obtained from Korea, Japan, America and German were determined by HRGC/HRMS. Experimental Methods were consisted of comparision of extracting solvent, analysis of PCDD/Fs, and analysis of PCDD/Fs of extraction in disposable diaper. The results were as follows. No high TEQ values in TCDD(1), PCDD(0.5) and HxCDD(0.1) were found for commercial disposable diapers from country Korea, Japan, U.S.A and German. In extraction for 6hrs experiments, HpCDD and OCDD were detected in disposable diapers of U1, U2 and G2, respectively. In extraction fur 24hrs experiments, HpCDD, OCDD and OCDF were detected in disposable diapers of J3, U1, U2 and U3. So we need to set standards of measurement for harmful materials contained in textile goods. This will make a safe and comfortable clothing environment for all users, regardless of age.

Human Health Risk based Priority Ranking for Hazardous Air Pollutants (대기중 유해 화학 물질의 인체 위해도 우선순위 선정 연구)

  • Park Hoa-sung;Kim Ye-shin;Lee Dong-soo;Shin Dong-chun
    • Environmental Analysis Health and Toxicology
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    • v.19 no.1
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    • pp.81-91
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    • 2004
  • Although it is suggested that risk -based management plan is needed to manage air pollution effectively, we have no resources enough to evaluate all aspects of substances and set priorities. So we need to develop a logical and easy risk-based priority setting method. However, it if impossible that only one generic system that is consistent with all the use is developed. In this study, we proposed a human health risk based priority-setting method for hazardous air pollutants, and ranked priorities for this method. First of all, after investigating previous chemical ranking and scoring systems, we chose appropriate indicators and logics to goal of this study and made a chemical priority ranking method using these. As results, final scores in priority ranking method were derived for 25 substances, and ethylene oxide, acrylonitrile and vinyl chloride were included in high ranks. In addition, same substances were highly ranked when using default values like when using no default, but the scores of hydrofluoric acid and ryan and compounds were sensitive to default values. This study could be important that priorities were set including toxicity type and quality and local inherent exposure conditions and we can set area-specific management guidelines and survey plans as a screening tool.

A Study on the Control Performance for Hazardous Gases by Surface Discharge induced Plasma Chemical Process (연면방전의 플라즈마 화학처리에 의한 유해가스제어 성능에 관한 연구)

  • 이주상;김신도;김광영;김종호
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.2
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    • pp.185-190
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    • 1995
  • Recently, because of the worse of the air pollution, the excessive airtught of building and the inferiority of air conditioning system, the development of high efficiency air purification technology was enlarged to the environmental improvement of an indoor or a harmful working condition. The air purification technology has used chemical filters or charcoal filters or charcoal to remove hazardouse gaseous pollutants (SO$_{x}$, NO$_{x}$, NH$_{3}$, etc.) by air pollutant control technology, but they have many problems of high pressure loss, short life, wide space possession, and treatment of secondary wastes. For these reason, the object of reasearch shall be hazardous gaseous pollutants removal by the surface discharge induced plasma chemical process that is A.C. discharge of multistreams applied A.C. voltage and frequency between plane induced eletrode and line discharge eletrode of tungsten, platinum or titanium with a high purified alumina sheet having a film-like plane. As a result, the control performance for hazardous gaseous pollutants showed very high efficiency in the normal temperature and pressure. Also, after comtact oxidation decomposition of harmful gaseous pollutants, the remainded ozone concentration was found much lower than that of ACGIH or air pollution criteria in Korea.rea.

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