• Title/Summary/Keyword: Hard mask

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Frequency effect of TEOS oxide layer in dual-frequency capacitively coupled CH2F2/C4F8/O2/Ar plasma

  • Lee, J.H.;Kwon, B.S.;Lee, N.E.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.284-284
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    • 2011
  • Recently, the increasing degree of device integration in the fabrication of Si semiconductor devices, etching processes of nano-scale materials and high aspect-ratio (HAR) structures become more important. Due to this reason, etch selectivity control during etching of HAR contact holes and trenches is very important. In this study, The etch selectivity and etch rate of TEOS oxide layer using ACL (amorphous carbon layer) mask are investigated various process parameters in CH2F2/C4F8/O2/Ar plasma during etching TEOS oxide layer using ArF/BARC/SiOx/ACL multilevel resist (MLR) structures. The deformation and etch characteristics of TEOS oxide layer using ACL hard mask was investigated in a dual-frequency superimposed capacitively coupled plasma (DFS-CCP) etcher by different fHF/ fLF combinations by varying the CH2F2/ C4F8 gas flow ratio plasmas. The etch characteristics were measured by on scanning electron microscopy (SEM) And X-ray photoelectron spectroscopy (XPS) analyses and Fourier transform infrared spectroscopy (FT-IR). A process window for very high selective etching of TEOS oxide using ACL mask could be determined by controlling the process parameters and in turn degree of polymerization. Mechanisms for high etch selectivity will discussed in detail.

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Residual Stress Analysis of Cold Rolled Sheet in Shadow Mask (Shadow Mask용 냉간 압연박판의 잔류응력 해석)

  • 정호승;조종래;문영훈;김교성
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2002.05a
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    • pp.195-198
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    • 2002
  • Residual stress of sheet occurs during cold rolling and it is hard to avoid and inevitable. The residual stress in the sheet cause etching curls when it suffers peroration process. The residual stress through the thickness direction in the sheet is a function of a friction coefficient, total reduction, mil size and initial sheet thickness. To estimate the residual stress and deformation due to etching curl, FEM analysis is performed. A numerical analysis is used a ANSYS 5.6 and an elastic-plastic constitutive equations. rho simulation results indicate a distribution of residual stress.

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사파이어 기판에 sub-micron급 패터닝을 위한 나노 임프린트 리소그래피 공정

  • Park, Hyeong-Won;Byeon, Gyeong-Jae;Hong, Eun-Ju;Lee, Heon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.50.2-50.2
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    • 2009
  • 사파이어는 질화물계 광전자소자 제작 시 박막 성장 기판으로 주로 사용되어 최근 그 중요성이 부각되고 있다. 특히 미세 패턴이 형성된 사파이어 기판을 이용하여 질화물계 발광다이오드 소자를 제작하면 빛의 난반사가 증가하여 광추출효율에 큰 개선이 나타난다. 또한 사파이어는 화학적 안정성이 뛰어나고, 높은 강도를 지녀 나노임프린트 등 여러 가지 패터닝 공정에서 패턴 형성 몰드로도 응용될 수 있다. 그러나 이와 같은 사파이어의 화학적 안정성으로 인하여 sub-micron 크기의 미세 패턴을 형성하기 힘들며, 현재 사파이어의 패턴은 micron 크기로 제한되어 사용되고 있다. 본 연구에서는 나노임프린트 리소그라피(NIL)를 사용하여 사파이어 웨이퍼의 c-plane위에 sub-micron 크기의 hole 패턴 및 pillar 패턴을 형성하였다. 우선 Hole 패턴을 형성하기 위해 사파이어 기판 위에 금속 hard mask 패턴을 UV 임프린트 공정과 etch 공정을 통해 형성하였다. 그리고 이 금속 패턴을 mask로 사파이어를 ICP 식각을 하여 hole 패턴을 형성하였다. 또한 Pillar 패턴을 형성하기 위해 lift-off 공정을 이용하여 금속 마스크 패턴을 형성하였고 이를 ICP 식각을 통해 사파이어 기판 위에 pillar 패턴을 형성하였다.

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Etch Characteristics of CO/NH3 Plasma Gas for Magnetic Random Access Memory in Pulsed-biased Inductively Coupled Plasmas

  • Yang, Gyeong-Chae;Jeon, Min-Hwan;Yeom, Geun-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.200-200
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    • 2013
  • 기존 메모리 반도체에 비교해 빠른 재생속도와 높은 집적도, 비휘발성 등의 특성을 가지는 MRAM (Magnetic Random Access Memory)은 DRAM, flash memory 등을 대체할 수 있는 차세대 기억 소자로서 CoFeB/MgO/CoFeB로 구성된 한 개의 MTJ (Magnetic Tunnel Junction)를 단위 메모리로 사용한다. 이 MTJ 물질들은 고밀도 플라즈마를 이용한 건식 식각공정시 Cl2, BCl3 등과 같은 chlorine 을 포함한 가스를 이용하여 왔으나 식각 후 sidewall에서 발생하는 부식과 식각 선택비 확보의 어려움 등으로 마스크 물질에 제약을 받고 소자 특성이 감소하게 되는 등의 문제가 있다. 따라서 이러한 식각 문제점을 해결하기 위한 대안으로 noncorrosive 가스인 CO/NH3, CH3OH, CH4 등을 이용한 MTJ 식각 연구가 진행되어 오고 있으며 이중 CO/NH3 혼합가스는 부식성이 없고 hard mask와의 높은 선택비를 가지는 기체로 CO gas에 NH3 gas를 첨가하게 되면 etch rate이 증가하는 특성을 보인다. 또한 rf pulse-biased power를 이용하여 이온의 입사를 시간에 따라 제어함으로써 pulse off time 때 etch gas와 MTJ 물질간의 chemical reaction을 향상시킬 수 있다. 따라서 본 연구에서는 CO/NH3 혼합가스를 이용하여 다양한 rf pulse-biased power 조건에서 MTJ 물질인 CoFeB, MgO와 hard mask 물질인 W을 식각 한 뒤 식각특성을 분석하였으며 MTJ surface의 chemical binding state, surface roughness 측정을 진행하였다. 식각 샘플의 측정은 Alpha step profiler, XPS (X-ray Photoelectron Spectroscopy), AFM (Atomic Force Microscopy)를 통해 진행되었다. Time-averaged pulse bias에서는 duty ratio가 감소할수록 etch rate의 큰 감소 없이 CoFeB/W, MgO/W 물질의 etch selectivity가 향상됨을 확인할 수 있었으며 pulse off time 구간에서의 chemical reaction 향상으로 인해 식각부산물의 재증착이 감소하고 CoFeB의 surface roughness가 감소하는 것을 확인하였다.

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A Study on the Etcting Technology for Metal Interconnection on Low-k Polyimide (Low-k Polyimide상의 금속배선 형성을 위한 식각 기술 연구)

  • Mun, Ho-Seong;Kim, Sang-Hun;An, Jin-Ho
    • Korean Journal of Materials Research
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    • v.10 no.6
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    • pp.450-455
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    • 2000
  • For further scaling down of the silicon devices, the application of low dielectric constant materials instead of silicon oxide has been considered to reduce power consumption, crosstalk, and interconnection delay. In this paper, the effect of $O_2/SF_6$ plasma chemistry on the etching characteristics of polyimide-one of the promising low-k interlayer dielectrics-has been studied. The etch rate of polyimide decreases with the addition of $SF_6$ gas due to formation of nonvolatile fluorine compounds inhibiting reaction between oxygen and hydrocarbon polymer, while applying substrate bias enhances etching process through physical attack. However, addition of small amount of $SF_6$ is desirable for etching topography. $SiO_2$ hard mask for polyimide etching is effective under $O_2$plasma etching(selectivity~30), while $O_2/SF_6$ chemistry degrades etching selectivity down to 4. Based on the above results, $1-2\mu\textrm{m}$ L&S PI2610 patterns were successfully etched.

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Effects of $CH_{2}F_{2}$ and $H_2$ flow rates on process window for infinite etch selectivity of silicon nitride to PVD a-C in dual-frequency capacitively coupled plasmas

  • Kim, Jin-Seong;Gwon, Bong-Su;Park, Yeong-Rok;An, Jeong-Ho;Mun, Hak-Gi;Jeong, Chang-Ryong;Heo, Uk;Park, Ji-Su;Lee, Nae-Eung
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.250-251
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    • 2009
  • For the fabrication of a multilevel resist (MLR) based on a very thin amorphous carbon (a-C) layer an $Si_{3}N_{4}$ hard-mask layer, the selective etching of the $Si_{3}N_{4}$ layer using physical-vapor-deposited (PVD) a-C mask was investigated in a dual-frequency superimposed capacitively coupled plasma etcher by varying the following process parameters in $CH_{2}F_{2}/H_{2}/Ar$ plasmas : HF/LF powr ratio ($P_{HF}/P_{LF}$), and $CH_{2}F_{2}$ and $H_2$ flow rates. It was found that infinitely high etch selectivities of the $Si_{3}N_{4}$ layers to the PVD a-C on both the blanket and patterned wafers could be obtained for certain gas flow conditions. The $H_2$ and $CH_{2}F_{2}$ flow ratio was found to play a critical role in determining the process window for infinite $Si_{3}N_{4}$/PVDa-C etch selectivity, due to the change in the degree of polymerization. Etching of ArF PR/BARC/$SiO_x$/PVDa-C/$Si_{3}N_{4}$ MLR structure supported the possibility of using a very thin PVD a-C layer as an etch-mask layer for the $Si_{3}N_{4}$ layer.

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Crack Inspection and Mapping of Concrete Bridges using Integrated Image Processing Techniques (통합 이미지 처리 기술을 이용한 콘크리트 교량 균열 탐지 및 매핑)

  • Kim, Byunghyun;Cho, Soojin
    • Journal of the Korean Society of Safety
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    • v.36 no.1
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    • pp.18-25
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    • 2021
  • In many developed countries, such as South Korea, efficiently maintaining the aging infrastructures is an important issue. Currently, inspectors visually inspect the infrastructure for maintenance needs, but this method is inefficient due to its high costs, long logistic times, and hazards to the inspectors. Thus, in this paper, a novel crack inspection approach for concrete bridges is proposed using integrated image processing techniques. The proposed approach consists of four steps: (1) training a deep learning model to automatically detect cracks on concrete bridges, (2) acquiring in-situ images using a drone, (3) generating orthomosaic images based on 3D modeling, and (4) detecting cracks on the orthmosaic image using the trained deep learning model. Cascade Mask R-CNN, a state-of-the-art instance segmentation deep learning model, was trained with 3235 crack images that included 2415 hard negative images. We selected the Tancheon overpass, located in Seoul, South Korea, as a testbed for the proposed approach, and we captured images of pier 34-37 and slab 34-36 using a commercial drone. Agisoft Metashape was utilized as a 3D model generation program to generate an orthomosaic of the captured images. We applied the proposed approach to four orthomosaic images that displayed the front, back, left, and right sides of pier 37. Using pixel-level precision referencing visual inspection of the captured images, we evaluated the trained Cascade Mask R-CNN's crack detection performance. At the coping of the front side of pier 37, the model obtained its best precision: 94.34%. It achieved an average precision of 72.93% for the orthomosaics of the four sides of the pier. The test results show that this proposed approach for crack detection can be a suitable alternative to the conventional visual inspection method.

UV nanoimprint lithography using a multi-dispensing method (다중 디스펜싱 방법에 의한 UV-나노임프린트 리소그래피)

  • 심영석;손현기;신영재;이응숙;정준호
    • Journal of Institute of Control, Robotics and Systems
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    • v.10 no.7
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    • pp.604-610
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    • 2004
  • Ultraviolet-nanoimprint lithography (UV-NIL) is a promising method for cost-effectively defining nanoscale structures at room temperature and low pressure. Since the resolution of transferred nanostructures depends strongly upon that of nanostamps, the nanostamp fabrication technology is a key technology to UV-NIL. In this paper, a $5\times5\times0.09$ in. quartz stamp whose critical dimension is 377 nm was fabricated using the etching process in which a Cr film was employed as a hard mask for transferring nanostructures onto the quartz plate. To effectively apply the fabricated 5-in. stamp to UV-NIL on a 4-in. Si wafer, we have proposed a new UV-NIL process using a multi-dispensing method as a way to supply resist on a wafer. Experiments have shown that the multi-dispensing method can enable UV-NIL using a large-area stamp.

Use of Midazolam Intranasal Spray for Dental Treatment of Autism Patients (자폐증 환자의 행동조절을 위한 Midazolam Intranasal Spray 사용사례)

  • Song, Young-Gyun;Lee, Suk Young;Kim, Seung-Oh
    • Journal of The Korean Dental Society of Anesthesiology
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    • v.12 no.4
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    • pp.223-227
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    • 2012
  • Autism patients in general have bad oral hygiene. It is hard for autism patients to get dental treatment as poor communication. Therefore, they may have to be treated by deep sedation or general anesthesia in numerous cases. However, this process requires induction with mask, so it is not easy to do for disobliging autism patient. Midazolam is a water-soluble benzodiazepine, has been used in pediatric dentistry or dentistry for the handicapped because of rapid onset. Midazolam can be administered through oral, rectal, intramuscular,intravenous, and intranasal (IN) routes. IN route of midazolam may be considered as effective way to allay for uncooperative autism patients before general anesthesia. In this case report, two autism patients required dental treatment. Intranasal spray of midazolam before general anesthesia was safe and effective procedure of behavioral management.