• Title/Summary/Keyword: HOST

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Vibrational Relaxation and Fragmentation in Icosahedral (Ar2+)Ar12 Clusters

  • Ree, Jongbaik;Kim, Yoo Hang;Shin, Hyung Kyu
    • Bulletin of the Korean Chemical Society
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    • 제35권9호
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    • pp.2774-2780
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    • 2014
  • A dynamics study of relaxation and fragmentation of icosahedral argon cluster with a vibrationally excited $Ar_2^+$ (${\nu}$) is presented. Local translation is shown to be responsible for inducing energy flow from the embedded ion to host atoms and fragmentation of the cluster consisting of various low frequency modes. The total potential energy of $(Ar_2^+)Ar_{12}$ is formulated using a building-up procedure of host-guest and host-host interactions. The time dependence of ion-to-host energy transfer is found to be tri-exponential, with the short-time process of ~100 ps contributing most to the overall relaxation process. Relaxation timescales are weakly dependent on both temperature (50-300 K) and initial vibrational excitation (${\nu}$ = 1-4). Nearly 27% of host atoms in the cluster with $Ar_2^+$ (${\nu}$ = 1) fragment immediately after energy flow, the extent increasing to ~43% for ${\nu}$ = 4. The distribution of fragmentation products of $(Ar_2^+)Ar_{12}{\rightarrow}(Ar_2^+)Ar_n+(12-n)Ar$ are peaked around $(Ar_2^+)Ar_8$. The distribution of dissociation times reveals fragmentation from one hemisphere dominates that from the other. This effect is attributed to the initial fragmentation causing a sequential perturbation of adjacent atoms on the same icosahedral five-atom layer.

새로운 Spiro[fluorene-benzofluore]계 청색 호스트 물질의 유기전계발광 특성 (Electroluminescence Properties of New Spiro(fluorene-benzofluore)-Type Blue Host Materials)

  • 전영민;이현석;이칠원;김준우;장지근;공명선
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 춘계학술대회 및 기술 세미나 논문집 디스플레이 광소자
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    • pp.29-30
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    • 2008
  • New spiro-type host materials, 5'-phenylnaphthyl-spiro[fluorene-7,9'-benzofluorene](BH-lPN) and 5',6-bis(phenylnaphthyl)-spiro[fluorene-7,9'-benzofluorene](BH-6PN) were designed and successfully prepared by the Suzki reaction. The EL characteristics of BH-1PN as blue host material doped with blue dopant materials, BD-1 were evaluated and compared with the existing host MADN:dopant BD-1 system. The structure of the device is ITO/DNTPD/NPB/Host:5% dopant/Alq3/Al-LiF. The device obtained from BH-lPN doped with BD-1 showed a good color purity and efficiency, on the other hand luminance and current-density characteristics are worse than that of MADN doped with BD-1.

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Verification of aecial host ranges of four Gymnosporangium species based on artificial inoculation.

  • Yun, Hye-Young;Lee, Seung-Kyu;Lee, Kyung-Joon
    • 한국식물병리학회:학술대회논문집
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    • 한국식물병리학회 2003년도 정기총회 및 추계학술발표회
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    • pp.134.1-134
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    • 2003
  • Aecial host ranges of four Gymnosporangium species causing cedar-apple rust diseases, G. asiaticum, G. cornutum, 5. japonicum and G. yamadae, were investigated through artificial inoculation. Thirteen species of nine genera among Rosaceous plants, which have been reported as social hosts in Korea, were inoculated with fresh teliospores spores in early days of May of 2000 and of 2001, respectively. In the results, we re-confirmed that there was highly specific relationship between the rust species and aecial hosts and report new aecial hosts of four Gymnosporangium species. Teliospores of G. cornutum collected from Juniperus rigida successively produced spermogonia and aecia only on Sorbus alntifolia, the first report on host alteration of G. cornutum in Korea. Positive responses by teliospores of G. japonicum from J. chinenis of Suwon and from J. chinenis var. horizontalis of Jeju island were obtained only on P. villosa. Crataegus pinnatifida was confirmed as a new aecial host of G. viatium. Until this time, G. ymadae was believed to have Malus as the aecial host. However, teliospores of G. yamadae collected from J. chinensis var. kaizuka successively formed spermogonia and aecia on the leaves of Chaenomeles lagenaria, C. sinensis, Pyrus pyrtifolia var, culta, P. ussuriensis, Malus pumila and M. sileboldii. The date for maturation of spermogonia and aecia, and symptom development varied according to the rust fungi and aecial host plants, respectively.

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UV-VIS Spectrophotometer를 이용한 ORMOSIL의 투광특성 (A Study on the Charateristics of ORMOSIL as a Dye Host by Measurement of UV/VIS Spectrophotometer)

  • 김구대;이동아;강현규;문지웅
    • 분석과학
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    • 제7권1호
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    • pp.17-23
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    • 1994
  • 졸-겔법에 의해 dye host로 사용될 수 있는 무기/유기 복합체(ORMOSIL)를 제조하였으며, 이 복합체가 dye host로 적합한 조건을 갖췄음을 UV/VIS Spectrophotometer를 이용하여 90% 정도의 투광성을 얻음으로써 알 수 있었다. 이 투광성은 졸-겔 공정 중 촉매로 쓰이는 염산의 양이 적고 묵힘시간이 짧을수록 커짐을 알 수 있었다. 또한 이렇게 제조된 Host에 Rhodamine 6G Perchlorate를 도핑하여 유기염료의 형광 및 투광성을 측정한 결과 겔화온도가 증가될수록 형광 강도가 증가하며 투광성은 감소하는 것을 관찰할 수 있었다.

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유비쿼터스 지능형 공간에서의 로봇 에이전트 설계 및 응용 (Robotic Agent Design and Application in the Ubiquitous Intelligent Space)

  • 윤한얼;황세희;김대욱;이동훈;심귀보
    • 제어로봇시스템학회논문지
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    • 제11권12호
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    • pp.1039-1044
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    • 2005
  • This paper presents a robotic agent design and application in the ubiquitous intelligent space. We set up an experimental environment with Bluetooth host, Bluetooth client, furniture and home appliance, and robotic agents. First, the agents basically performed patrol guard to detect unexpected penetration, and to keep home safely from gas-leakage, electric leakage, and so on. They were out to patrol fur a robbery while navigating in a living room and a private room. In this task, we used an area-based action making and a hexagon-based Q-learning to control the agents. Second, the agents communicate with Bluetooth host device to access and control a home appliance. The Bluetooth host offers a manual control to person by inquiring a client robot when one would like to check some place especially. In this exercise, we organize asynchronous connection less (ACL) between the host and the client robots and control the robot maneuver by Bluetooth host controller interface (HCI).

Host Cell Nuclear Localization of Shigella flexneri Effector OspF Is Facilitated by SUMOylation

  • Jo, Kyungmin;Kim, Eun Jin;Yu, Hyun Jin;Yun, Cheol-Heui;Kim, Dong Wook
    • Journal of Microbiology and Biotechnology
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    • 제27권3호
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    • pp.610-615
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    • 2017
  • When Shigella infect host cells, various effecter molecules are delivered into the cytoplasm of the host cell through the type III secretion system (TTSS) to facilitate their invasion process and control the host immune responses. Among these effectors, the S. flexneri effector OspF dephosphorylates mitogen-activated protein kinases and translocates itself to the nucleus, thus preventing histone H3 modification to regulate expression of proinflammatory cytokines. Despite the critical role of OspF, the mechanism by which it localizes in the nucleus has remained to be elucidated. In the present study, we identified a potential small ubiquitin-related modifier (SUMO) modification site within OspF and we demonstrated that Shigella TTSS effector OspF is conjugated with SUMO in the host cell and this modification mediates the nuclear translocation of OspF. Our results show a bacterial virulence factor can exploit host post-translational machinery to execute its intracellular trafficking.

Study of Specific Oligosaccharide Structures Related with Swine Flu (H1N1) and Avian Flu, and Tamiflu as Their Remedy

  • Yoo, Eun-Sun
    • Journal of Microbiology and Biotechnology
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    • 제21권5호
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    • pp.449-454
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    • 2011
  • The infection of pandemic influenza viruses such as swine flu (H1N1) and avian flu viruses to the host cells is related to the following two factors: First, the surface protein such as HA (hemagglutinin) and NA (neuraminidase) of the influenza virus. Second, the specific structure of the oligosaccharide [sialic acid(${\alpha}2$-6) galactose(${\beta}1$-4)glucose or sialic acid(${\alpha}2$-3)galactose(${\beta}1$-4)glucose] on the host cell. After recognizing the specific structure of the oligosaccharide on the surface of host cells by the surface protein of the influenza virus, the influenza virus can secrete sialidase and cleave the sialic acid attached on the final position of the specific structure of the oligosaccharide on the surface of host cells. Tamiflu (oseltamivir), known as a remedy of swine flu, has a saccharide analog structure, especially the sialic acid analog. Tamiflu can inhibit the invasion of influenza viruses (swine flu and avian flu viruses) into the host cells by competition with sialic acid on the terminal position of the specific oligosaccharide on the surface of the host cell. Because of the emergence of Tamiflu resistance, the development of new potent anti-influenza inhibitors is needed. The inhibitors with positive-charge groups have potential as antiviral therapeutics, and the strain specificity must also be resolved.

High-z Universe probed via Lensing by QSOs (HULQ): Expected Number of QSOs acting as Gravitational Lenses

  • Taak, Yoon Chan;Im, Myungshin
    • 천문학회보
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    • 제43권1호
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    • pp.37.4-38
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    • 2018
  • The HULQ project proposes to use gravitational lensing to determine the masses of QSO host galaxies, an otherwise difficult goal. If these host galaxy masses, along with their SMBH masses from single-epoch measurements, are estimated for a substantial number of QSOs at various redshifts, the co-evolution of SMBHs and their host galaxies can be studied for a large portion of the history of the universe. To determine the feasibility of this study, we present how to estimate the number of sources lensed by QSO hosts, i.e. the number of lensing QSO host galaxies (hereafter QSO lenses). SMBH masses in the literature are transformed into the velocity dispersions of their host galaxies using the M_BH -sigma relation, and in turn the Einstein radii for each QSO -source redshift combination is calculated, assuming singular isothermal spherical mass distributions. Using QSOs and galaxies as potential sources, the probability of a QSO host galaxy being a QSO lens is calculated, as a function of limiting magnitude. The expected numbers of QSO lenses are estimated for ongoing and future wide-imaging surveys, and the Hyper Suprime-Cam Wide survey is illustrated as an example.

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Phytophthora capsici 균주와 토마토의 친화적, 불친화적 상호작용에 대한 광학 및 전자현미경적 연구 (A Light and Electron Microscopical Study of Compatible and Incompatible Interactions between Phytophthora capsici and Tomato (Lycopersicon esculentum))

  • 황재순;황병국;김우갑
    • 한국식물병리학회지
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    • 제10권2호
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    • pp.83-91
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    • 1994
  • Stem tissues of tomato plants (cv. Kwanyang) inoculated with Phytophthora capsici were examined by light and electron microscopy to compare early cytological differences between comaptible and incompatible interactions of tomatoes with the fungus. Twenty four hours after inoculation, the compatible isolate S 197 colonized severely the epidermis, cortex, and xylem vessels of stem tissue, whereas only few fungal cells colonized the stem tissues inoculated with the incompatible isolate CBS 178.26. Fragmented plasma membrane, distorted chloroplast, degraded cell wall, remnants of host cytoplasm were early ultrastructural features of the damaged host cell observed both in the compatible and incompatible interaction, a number of vesicles were distributed in the space between fungal cell walls and plasma membrane. The degradation of host cell walls by P. capsici was more pronounced in the compatible than the incompatible interactions. The incompatible interactions of tomato cells with P. capsici were characterized by formation of host cell wall apposition in the cortical parenchyma cells, indicating that the apposition of electron-dense material from the host cell walls may function as a plant defense reaction to the fungus. The fungal cells encased by wall appositions had abnormal cytoplasm and separated plasma membranes. The haustorium which formed from the fungal hyphae did not further penetrate through the host wall apposition and cytoplasmic aggregation, especially in the incompatible reactions. In contrast, the haustorium of the compatible isolate S 197 was not encased by wall appositions.

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Effect of Host Materials on Eelectrophosphorescence Properties of PtOEP-doped Organic Light-emitting Diodes

  • Kang, Gi-Wook;Lee, Chang-Hee
    • Journal of Information Display
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    • 제8권2호
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    • pp.15-19
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    • 2007
  • We have studied the effect of host materials on the electrophosphorescence properties by comparing three different host materials such as tris(8-hydroxyquinoline)-aluminum (III) $(Alq_3)$, bis(8-hydroxyquinoline)-zinc (II) $(Znq_2)$, and 4,4'-N,N' dicarbazole-biphenyl (CBP) doped with a red-emissive phosphorescent dye, 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphyrin platinum (II) (PtOEP). The EL spectra show a strong red emission (peak at 650 nm) from the triplet excited state of PtOEP and a very weak emission from an electron transport layer of $Alq_3$ and a hole transport layer of N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1-biphenyl-4,4'-diamine (TPD). We find that the triplet exciton lifetime and the quantum efficiency decrease in the order of CBP, $Alq_3$, and $Znq_2$ host materials. The results are interpreted as a poor exciton confinement in $Alq_3$, and $Znq_2$ host compared with in CBP. Therefore, it is very important for the triplet-exciton confinement in the emissive layer for obtaining a high efficiency.