• Title/Summary/Keyword: HFP

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Charge-Discharge Characteristics of Lithium Metal Polymer Battery Adopting PVdF-HFP/(SiO2, TiO2) Polymer Electrolytes Prepared by Phase Inversion Technique (상반전 기법으로 제조한 PVdF-HFP/(SiO2, TiO2) 고분자 전해질을 채용한 리튬금속 고분자 2차전지의 충방전 특성)

  • Kim, Jin-Chul;Kim, Kwang-Man
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.131-136
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    • 2008
  • Silica- or titania-filled poly (vinylidene fluoride-co-hexafluoropropylene)-based polymer electrolytes were prepared by phase inversion technique using N-methyl-2-pyrrolidone and dimethyl acetamide as solvent and water as non-solvent. The polymer electrolytes were adopted to the lithium metal polymer battery using high-capacity cathode $Li[Ni_{0.15}Co_{0.10}Li_{0.20}Mn_{0.55}]O_2$ and lithium metal anode. After the repeated charge-discharge test for the cell, it was proved that the cell adopting the polymer electrolyte based on the phase-inversion membrane containing 40~50 wt% silica showed the highest discharge capacity (180 mAh/g) until 80th cycle and then abrupt capacity fade was just followed. The capacity fade might be due to the deposition of lithium dendrite on the polymer electrolyte, in which the capacity retention was no longer sustainable.

On the Evaluation of Physical Distribution Service in Ports (항만물류서비스의 평가에 관하여)

    • Journal of Korean Port Research
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    • v.10 no.2
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    • pp.17-29
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    • 1996
  • It is required to consider pricing and non-pricing factors and external economy in order to achieve the objects of physical distribution system in a port. Recently, among the three factors, much attention has been paid to non-pricing factor in the system. Although physical distribution service in a port(PDSP)has been frequently mentioned in documents and literature related to port and shipping studies, few study on it has not been systematically and scientifically made due to the following problems; $\circ$ there are not proper criteria to evaluate level and quality of PDSP and as a result it is difficult to set up a unified standard for doing so. $\circ$ algorithms to evaluate problems with complex and ambiguous attributes and multiple levels in PDSP are not available. This thesis aims to establish a paradigm to evaluate PDSP and to abvance existing decision making methods to deal with complex and ambiguous problems in PDSP. To tackle the first purpose, extensive and thorough literature survey was carried out on general physical distribution service, which is a corner stone to handle PDSp. In addition, through interviews and questionnaire to the expert, it have extracted 82 factors of physical distribution service in a port. They have been classified into 6 groups by KJ method and each group defined by the expert's advice as follows; a. Potentiality b. Exactness c. safety d. Speediness e. Convenience f. Linkage Prior to the service evaluation, many kinds of its attributes must be identified on the basis of rational decision owing to complexity and ambiguity inherent in PDSP. An analytical hierarchy process (AHP) is a method to evaluate them but it is not applicable to PDSP that have property of non-additivity and overlapped attributes. Therefore, probablility measure can not be used to evaluate PDSP but fuzzy measure is required. Hierarchical fuzzy integral method, which is merged AHP with fuzzy measure, is also not effective method to evaluate attributes because it has vary complicated way to calculate fuzzy measure identification coefficient of attributes. A new evaluation algorithm has been introduced to solve problems with multi-attribute and multi-level hierarchy, which is called hierarchy fuzzy process(HFP).Analysis on ambiguous aspects of PDSP under study which is not easy to be defined is prerequisite to evaluate it. HFP is different from algorithm existed in that it clarified the relationship between fuzzy measure and probability measure adopted in AHP and that it directly calculates the family of fuzzy measure from overlapping coefficient and probability measure to treat and evaluate ambiguous and complex aspects of PDSP. A new evaluation algorithm HFP was applied to evaluate level of physical distribution service in the biggest twenty container port in the world. The ranks of the ports are as follows; 1. Rotterdam Port, 2. Hamburg Port, 3. Singapore Port, 4. Seattle Port, 5. Yokohama Port, 6. Long beach Port, 7. Oakland Port, 8. Tokyo Port, 9. Hongkong Port, 10. Kobe Port, 11. Los Angeles Port, 12. New york Port, 13. Antwerp Port, 14. Felixstowe Port, 15. Bremerhaven Port, 16. Le'Havre Port, 17. Kaoshung Port, 18. Killung Port, 19. Bangkok Port, 20. Pusan Port

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MMA/fluoroalkyl methacrylate copolymers as cladding materials for polymer optical fibers (고분자광섬유 클래드용 MMA/fluoroalkyl methacrylate 공중합체)

  • 이무성;김영필;정민진;김진봉
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.327-328
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    • 2003
  • 최근, 가정 안까지 고속광통신망이 구축되면서 폴리머광섬유 (polymer optical fiber, POF)에 대한 관심이 매우 증가하고 있다[l,2] POF는 빛을 전송하는 코어층과 내부전반사를 유도하면서 코어를 보호하는 클래드 층으로 구성되어 있다. 빛을 직접 전송하지 않으나 POF가 최적의 성능을 보이기 위해서는 적절한 클래드 선택이 중요하다. 그러나 PVDF/PMMA 블렌드, fluoroacrylate, VDF-HFP 공중합체 등이 클래드용 재료로 사용되고 있다는 사실만이 알려져 있을 뿐 보다 자세한 정보는 보고된 바 없다. (중략)

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Preparation of Affinity Membrane by Electrospinning Method (전기방사법에 의한 친화막 제조)

  • Byun, Hong-Sik;Hong, Byung-Pyo
    • Membrane Journal
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    • v.17 no.1
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    • pp.23-30
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    • 2007
  • Protein affinity membranes based on polyethersulfone (PES) and bovine serum albumin (BSA) were prepared by using an electrospinning method. The changes in the size of nanofiber according to the various conditions of electrospinning (concentration of spinning solution, voltage, flow rate, tip to collector distance) were investigated, and the preparation conditions of the affinity membrane were optimized. XPS and FT-IR results showed the firm incorporation of BSA with PES. It was found PES-BSA nanofibers could be prepared at the temp. of $20{\sim}22^{\circ}C$ and humidity of $45{\sim}55%$. The size of nanofibers increased with increase of the content of PES in the spinning solution while BSA did not affect much to the size of nanofiber. It was also revealed that the narrow size distribution of nanofiber could be obtained with PES 7 wt%, BSA 0.7 wt%, HFP 92.3 wt% at the electrospinning conditions of 1 mL/hr, 10 cm TCD, and 10 kV.

A Study on the Analysis of the Level of ITs Performance in Major Container Terminals (주요 컨테이너 터미널의 정보화 수준 분석에 관한 연구)

  • Ryu, Hyung-Geun;Lee, Hong-Girl;Lee, Cheol-Yeong
    • Journal of Navigation and Port Research
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    • v.32 no.3
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    • pp.199-205
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    • 2008
  • Currently, ITs(Information Technologies} performances have been recognized as an essential tool for terminal operations. However, there have been little research that analyze level of ITs performance on port operation. Thus, the aim of this research is to analyze current level of ITs performance of major container terminals in Busan and Gwangyang. To achieve this objective, we developed HFP-based index that improve pervious indicator for evaluation of ITs performance. And then, level of ITs performance of four major container terminals were measured by the collected data through face to face interviews. Finally, through this analysis, some findings including weaknesses of ITs performance and implications were discussed.

Enhancement in the Amine Resistance of Membranes for Membrane Contactors by Plasma Treatment (플라즈마를 이용한 막접촉기용 막의 아민 용액에 대한 저항성 향상)

  • Choi, Seung-Hak;Oh, Sae-Joong;Cho, Nam-Joon;Koo, Ja-Kyung
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.719-724
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    • 2002
  • Celgard and Durapore membranes were plasma-treated to enhance the hydrophobicity and durability to amine solution. The plasma gases or vapors used were $CF_4$, Hexafluorobenzene(HFP), Pentafluoropyridine(PFP) and Hexamethyldisiloxane(HMDS). The surface structure of plasma treated membranes was analyzed by FT-IR spectra. The contact angles of plasma treated Celgard and Durapore were dependent of the plasma gases used. $CF_4$ and HMDS plasma increased the contact angles of Celgard and Durapore, while HFB and PFP plasma decreased the contact angles. Durability to monoethanolamine(MEA) solution was enhanced for $CF_4$ plasma-treated Durapore, while the durability was not good for plasma-treated Celgard.

Development of Polyvinyl Alcohol (PVA) Non-woven Separator Coated with ZrO2 Ceramic Nanoparticles for Improving Electrochemical Performance and Thermal Property of Lithium Ion Batteries (열 특성 및 전기화학 특성이 향상된 리튬이차전지용 ZrO2 코팅 PVA (Polyvinyl Alcohol) 복합 부직포 분리막 개발)

  • Kim, Ki Jae
    • Journal of the Korean Electrochemical Society
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    • v.20 no.3
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    • pp.49-54
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    • 2017
  • We develop a ceramic composite separator prepared by coating $ZrO_2$ nanoparticles with a poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) copolymer on a polyvinyl alcohol (PVA) mechanical support prepared by electrospinning technique to improve thermal properties. The gurley number of the ceramic composite separator shows much lower value than that of a PE separator even though it possesses the polymeric coating layer with ceramic nanoparticles. In addition, the proposed sample shows higher electrolyte uptake than PE separator, leading to enhancing the ionic conductivity of the proposed sample and, by extension, the rate discharge properties of lithium ion batteries. Thermal stability of the ceramic composite separator is dramatically improved without any degradation in electrochemical performance compared to the performance of conventional PE separators.

Effects of Thermal Processing Combined with High Pressure on the Characteristics of Cooked Pork (초고압 열처리가 가열 돈육의 품질특성에 미치는 효과)

  • Hong, Geun-Pyo;Shim, Kook-Bo;Choi, Mi-Jung;Min, Sang-Gi
    • Food Science of Animal Resources
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    • v.28 no.4
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    • pp.415-421
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    • 2008
  • This study evaluated the effects of thermal processing combined with high pressure on the properties of cooked pork. Pressurization followed by heating (PFH), heating followed by pressurization (HFP) and heating under pressurization (HUP) treatments were compared to a heated only control. Cooked meat without simultaneous pressurization showed little or no decrease in water binding properties relative to the control, regardless of the sequence of pressurization and heating. However, HUP treated pork had significantly higher water binding properties than the control (p<0.05). The pH values of all treatments were not significantly different with the exception of HUP at 300 MPa. The HUP treated pork showed the best tenderizing effects among all the treatments tested and the effect was more significant at increased pressure levels (p<0.05). In addition, increasing pressure levels significantly increased the L-values of pork (p<0.05). PFH and HFP treated pork had significantly lower a-values (p<0.05), while no significant differences were observed in HUP. HUP treated pork had the lowest b-values at 100 MPa. however, the differences were not significant at increasing pressure levels. These results indicate that heating under pressure is the best cooking condition for improving the quality characteristics of pork without adversely affecting its appearance.