• Title/Summary/Keyword: HFP

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Synthesis and Characteristics of Partially Fluorinated Poly(vinylidene fluroide)(PVDF) Cation Exchange Membrane via Direct Sulfonation (직접술폰화반응에 의한 부분불소화 Poly(vinylidene fluroide)(PVDF) 양이온교환막의 합성 및 특성)

  • Kang, Ki Won;Hwang, Taek Sung
    • Membrane Journal
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    • v.25 no.5
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    • pp.406-414
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    • 2015
  • In this study, partially fluorinated cation exchange membranes were prepared by direct sulfonation of Poly(VDF-co-hexafluoropropylene) copolymers (PVDF-co-HFP) followed by a casting method for application in the Membrane capacitive deionization (MCDI). The structure of sulfonated PVDF-co-HFP (SPVDF) was confirmed by Fourier-transform infrared (FT-IR) and $^1H$ Nuclear magnetic resonance ($^1H$ NMR) analysis. For quantitative analysis of the chemical composition, the X-ray Photoelectron Spectroscopy (XPS) was used. The membrane properties such as water uptake, ion exchange capacity and electrical resistance were measured. It was suggested that the optimum direct sulfonation condition of PVDF-co-HFP ion exchange membranes was $60^{\circ}C$ and 7 hours for temperature and duration of sulfonation, respectively. The water uptake of the SPVDF ion exchange membrane was 21.5%. The ion exchange capacity and electrical resistance were 0.89 meq/g and $3.70{\Omega}{\cdot}cm^2$, respectively. It was investigated that if it is feasible to apply these membranes in MCDI at various cell potentials (0.9~1.5 V) and initial flow rates (10~40 mL/min). In the MCDI process, the maximum salt removal rate was 62.5% in repeated absorption-desorption cycles.

A Case of Pleural Effusion in a Patient with Heart Failure with Preserved Ejection Fraction Improved by A Combined Korean-Western Medicine Approach (좌심실 수축 기능 보전 심부전증으로 인한 흉수에 대한 한양방 복합치료 치험 1례)

  • Ha, Won Jung;Seo, Yuna;Lee, Young seon;Cho, Ki-Ho;Mun, Sang-Kwan;Jung, Woo-Sang;Kwon, Seungwon
    • The Journal of the Society of Stroke on Korean Medicine
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    • v.22 no.1
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    • pp.45-56
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    • 2021
  • ■ Background Heart Failure with Preserved Ejection Fraction(HFpEF) is a heart failure that appears to have normal contraction function. In the case of HFpEF, no pharmacological therapy has been found to improve clinical prognosis, so it should be approached as an symptomatic treatment, therefore alternatives are needed due to concerns over adverse effects such as electrolyte imbalance caused by medication. ■ Case report A 81 year old female patient with Heart Failure with Preserved Ejection Fraction(HFpEF) patient complained dyspnea. Herbal prescription Mokbanggi-tang and Oryeongsan was administered on 6th day and 8th day respectively since the symptoms started. The NYHA Classification and Chest X-ray had been evaluated during the treatment period. Until the 7th day, the patient was classified as Class II, and when discharged from the hospital on the 28th day, it gradually improved and was classified as Class II. Chest X-Ray took on 2nd day showed pleural effusion and it was aggravated until 13th day. Follow up Chest X-Ray showed improving state of pleural effusion from 20th day and gradually got better. Mokbanggi-tang treatment continued for 52 days and stopped on 58th day. After Mokbanggi-tang treatment ended, only Oryeongsan treatment was maintained. ■ Conclusion The present case report suggests that Korean-Western medicine approach with Mokbangki-tang and Oryeongsan might be effective to pleural effusion and heart failure symptoms such as poor physical activity shown in a NYHA Classification. This shows that Mokbanggi-tang and Oryeongsan can be a therapeutic option as a treatment for patient with Heart Failure with Preserved Ejection Fraction(HFpEF).

Some Studies on Physics Parameters of Wolsung Unit No. 1

  • Kim, Seoung-Yun;Kim, Bong-Ghi;Kim, Dong-Hoon
    • Nuclear Engineering and Technology
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    • v.12 no.2
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    • pp.111-120
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    • 1980
  • Nuclear physics parameters of the Wolsung CANDU-PHW reactor are computed by use of the PHWCELL computer code that is an improved version of LATREP. The PHWCELL code mainly computes cell parameters of heavy water moderated reactors, and modeling scheme of heavy water reactor cell calculations has been developed with the PHWCELL computer code. The reactor operating conditions considered in the study are cold zero power (CZP) and hot full power (HFP) with equilibrium poison. The cell parameters are also computed as a function of fuel burnup and the numerical results are compared with the results in PSR of the Wolsung unit and in the previous study.

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A Study on Hierarchical Fuzzy Process using Fuzzy Relation Equation (퍼지관계방정식을 이용한 계층퍼지분석법에 관한 연구)

  • 류형근;이철영
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2000.11a
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    • pp.25.2-31
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    • 2000
  • Recently, Fuzzy theory has been applied in evaluation problem. Fuzzy evaluation based on Fuzzy theory can accommodate fuzziness of judgement with people through introducing Fuzzy measure. Representative Fuzzy evaluation is Fuzzy Integral using Fuzzy measure. Definite methodology using Fuzzy Integral HFI(Hierarchical Fuzzy Integrals), HFEA(Hierarchical Fuzzy Evaluation Algorithm), HFP(Hierarchical Fuzzy Process), etc. In this paper, we deal with problem identifying evaluation value using Fuzzy Relation Equation at these Fuzzy evaluation. We verify relation between Input data and Output data through @-operation and apply this to HFP. And that we verify evaluation value which objects of evaluation are able to possess.

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A Study on the Selection of the Administration System for Busan New Port using the Hierarchical Fuzzy Process (계층퍼지분석법을 이용한 부산신항만의 항만관리 방안에 관한 연구)

  • Kim, Sung-Kuk
    • Journal of Navigation and Port Research
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    • v.27 no.5
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    • pp.547-555
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    • 2003
  • A Port Authority system has been regarded as one of the efficient ways of port management. The Korean government is thus now planning to set up such a system into the Busan Port. Busan New Port is located in Kadok Island but divided Busan and Kyongnam administrative district, so complicated in the appropriate selection to Busan New Port Administration. The research method which was used in this study accounted for overlapping between attributes, and introduced the HFP( Hierarchical Fuzzy Process) method that can perform an operation.

The rheological properties of poly(vinylidene fluoride-co-hexafluoropropylene) solutions in dimethyl acetamide

  • Lee, Ki-Hyun;Song, In-Kyu;Kim, Byoung-Chul
    • Korea-Australia Rheology Journal
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    • v.20 no.4
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    • pp.213-220
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    • 2008
  • The effects of temperature on the rheological properties of the solutions of poly(vinylidene fluoride-co-hexafluopropylene) (PVDF-HFP) in dimethyl acetamide (DMAc) were investigated in terms of frequency and concentration. The effects of temperature on the intrinsic viscosity of the solutions were discussed. In dynamic rheological measurement, the concentrated solutions showed a little unexpected rheological response; as temperature was increased dynamic viscosity was increased and the solutions exhibited more noticeable Bingham body character over the temperature range, 30 to $70^{\circ}C$. In addition, the solution gave longer relaxation time, lower value of loss tangent and higher value of yield stress at higher temperature and at higher concentration. On the other hand, the dilute solutions revealed that intrinsic viscosity was decreased and its Huggins constant was increased with increasing temperature. These physical parameters suggested that the increase of viscosity with increasing temperature resulted from the localized gelation of PVDF-HFP due to reduced solubility to the solvent.

Development of Competitive Port Model Using the Hybrid Mechanism of System Dynamic Method and Hierarchical Fuzzy Process Method (SD법과 HFP법의 융합을 이용한 항만경쟁모델의 개발)

  • 여기태;이철영
    • Korean System Dynamics Review
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    • v.1 no.1
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    • pp.103-131
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    • 2000
  • If a system such as a port has a large boundary and complexity, and the system's substance is considered as a black box, forecast accuracy will be very low. Futhermore various components in a port exert significant influence on each other. To copy with these problem the form of structure models were introduced by using SD method. The Competitive Ports Model had several sub-systems consisting of each Unit Port models, and each Unit Port model was made by quantitative, qualitative factors and their feedback loops. The fact that all components of one port have influence on the components of the other ports should be taken into account to construct Competitive Port Models. However, with the current approach that is impossible, and in this paper therefore, models were simplified by HFP adapted to integrate level variables of unit port models. Although many studies on modelling of port competitive situation have been conducted, both theoretical frame and methodology are still very weak. In this study, a new algorithm called ESD(Extensional System Dynamics) for the evaluation of port competition was presented, and applied to simulate port systems in northeast asia.

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Rational Design of Extractive Distillation Toward Enhanced Separation of HFPO from HFP/HFPO Mixture

  • Lee, Yongtaek
    • Clean Technology
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    • v.24 no.1
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    • pp.15-20
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    • 2018
  • Hexafluoropropyleneoxide ($C_3F_6O$, HFPO) is highly expensive and it may be used as a raw material for the synthesis of various fluorine based compounds. Currently, extractive distillation method has gained considerable attention to collect the HFPO from a mixture of HFPO / hexafluoropropylene ($C_3F_6$, HFP). Optimized operating conditions are studied using a theoretical method for the extraction process. Among available solvents for the purification process, the use of 1,1-dichloro-1-fluoroethane exhibits a high purity of HFPO as a top product and minimize the required heat duty. Since the boiling point of the solvent increases as the pressure in the column increases, the enhanced extractive capability of the solvent led to the high purity of HFPO at the high pressure.