• Title/Summary/Keyword: HEXA

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Polymerization and Optical Properties of Polymers with High Tensile Strength Added Isocyanate Group

  • Sung, A-Young;Ye, Ki-Hun
    • Journal of Integrative Natural Science
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    • v.6 no.1
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    • pp.1-7
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    • 2013
  • Polyurethane resin containing isocyanate is marked by excellent tensile and mechanical strengths and this test aims to gauge its applicability as a medical high polymer. Tris [2-(acryloyloxy)ethyl]isocyanurate and hexamethylenediisocyanate were added to a basic mixing ratio of HEMA (2-hydroxyethyl methacrylate), MMA (methyl methacrylate), NVP (n-vinyl-2-pyrrolidone) and crosslink agent, EGDMA (ethylene glycol dimethacrylate) with increasing proportions and copolymerized respectively. Also, the basic physical properties of the polymerized high polymers including refraction rate, tensile strength, light transmission and water content were measured to confirm that they are appropriate as hydrogelcontact lenses. After measuring the physical properties of high performance polymers produced by adding tris [2-(acryloyloxy) ethyl]isocyanurate, it was found that the average tensile strengths of sample TRIS1 to TRIS10 were between 0.285 and 0.612 kgf, while the average values of refractive index were ranged from 1.441 to 1.449 with water content from 30.00 to 37.35%.The measurement of physical properties of the copolymers generated by adding hexamethylenediisocyanate showed that the average tensile strength of sample HEXA1 to HEXA10 ranged from 0.267 to 1.742 kgf, the refractive index ranged from 1.443 to 1.475 and water contents were in the range of 21.22 to 35.58%. In all combinations the transmission rates satisfied the transmittance of general hydrogel contact lenses. From theresults, it is possible to conclude that the produced copolymers can be used as contact lens materials with excellent tensile strength.

Comparison of Dioxin Analytical Results Between SP-2331 and DB-5MS Capillary Columns in the HRGC/HRMS Analysis (HRGC/HRMS에 SP-2331 및 DB-5MS 컬럼 사용시 다이옥신 결과의 비교)

  • Hong, Jongki;Yang, Jeong-Soo;Shin, Jung-Hwa;Ahn, Yun-Gyong;Lee, Dai-Woon
    • Analytical Science and Technology
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    • v.17 no.2
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    • pp.184-191
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    • 2004
  • In this study, the separation of toxic dioxin 2,3,7,8-congeners by DB-5MS and SP-2331 GC columns which are widely used in HRGC/HRMS analysis was examined. Through the dioxin analysis of column performance check standard solution and fly ash sample, the isomer specific separation of 2,3,7,8-substituted dioxins from tetra to hexa-isomers on DB-5MS and SP-2331 columns were studied. The effect of I-TEQ value by these columns was also studied. The total concentrations of toxic dioxins for the column performance check standard solution were 508.4 ng/mL analyzed by DB-5MS and 515.8 ng/mL analyzed by SP-2331, respectively. The I-TEQ value obtained by both columns was shown to be almost equivalent for the column performance check standard solution and fly ash sample.

Accumulation Levels and Distribution Characteristics of Polychlorinated Biphenyls in Crucians and Leopard Frogs from the Nakdong River Basin (낙동강 유역에 서식하는 붕어와 황소개구리 체내의 Polychlorinated biphenyls의 축적도와 분포특성)

  • Moon, Ji Yong;Lee, Sung In;Song, Heeyoung;Lee, Kyoung Jin;Choi, Kyunghee;Jeong, Gi Ho
    • Analytical Science and Technology
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    • v.17 no.4
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    • pp.347-354
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    • 2004
  • We collected crucians (Carassius auratus) and leopard frogs(Rana pipiens) along the Nakdong River and the basin area at five locations from Koomi to Nakdong-estuary. The muscular tissue were separated and a GC-MSD system was used for quantification of PCBs. The 62 PCB congeners which represent total PCB levels were selected as analytes. We determined concentrations of PCBs and studied distribution characteristics by individual congeners and homologs. In the crucian, 24 congeners were detected and total PCB levels ranged from 0.74 to 5.41 ng/g wet weight. In the leopard frog, however, only 2 congeners were detected from Nakdong estuary only. The PCB level was 0.24 ng/g wet weight, around 22 times lower than the crucians. The PCB 153 showed the highest concentrations in the congeners and penta- and hexa-CBs showed the strong predominance which accounted for 78% of the total PCBs.

Development of the hot ring rolling processes for multilayered ring parts with a large outer diameter (외경이 큰 환형 부품의 다중형상 열간 링 롤링 공정의 개발)

  • Kim, Kyung-Ryool;Kim, Young-Suk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.2
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    • pp.952-962
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    • 2015
  • In this study, multilayered rings with a large outer diameter have been developed using a hot ring rolling process. The ring rolling process has been analyzed by rigid plastic finite element analyses (FEA) using the AFDEX2D and AFDEX3D/HEXA/RING simulators, where the finite element meshes received severe plastic deformation are remeshed into a fine mesh-size using a dual-mesh system. According to the simulated results, the design variables of the multilayered rings were determined and real tests were conducted to check the validity of the simulation results. By adopting the hot ring rolling process, the input weight of raw materials was reduced by 40% against the conventional hot forging process and that the recovery rate was increased by 24%. The measurement of the averaged roundness was satisfied within 0.5 mm for both the inner and outer diameters. Moreover, the hot ring rolling processes yielded 1.49 Cpk for the outer-diameter and 0.84 Cpk 0.84 for the inner-diameter.

Dynamic Modeling and Control Techniques for Multi-Rotor Flying Robots (멀티로터 무인비행로봇 동역학적 모델링 및 제어기법 연구)

  • Kim, Hyeon;Jeong, Heon Sul;Chong, Kil To;Lee, Deok Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.2
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    • pp.137-148
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    • 2014
  • A multi-rotor is an autonomous flying robot with multiple rotors. Depending on the number of the rotors, multi-rotors are categorized as tri-, quad-, hexa-, and octo-rotor. Given their rapid maneuverability and vertical take-off and landing capabilities, multi-rotors can be used in various applications such as surveillance and reconnaissance in hostile urban areas surrounded by high-rise buildings. In this paper, the unified dynamic model of each tri-, quad-, hexa-, and octo-rotor are presented. Then, based on derived mathematical equations, the operation and control techniques of each multi-rotor are derived and analyzed. For verifying and validating the proposed models, operation and control technique simulations are carried out.

Evaluation on the Usefulness of 6DoF Couch in V-MAT on Patients with Long length of Target (표적의 길이가 긴 환자의 용적회전변조 방사선치료 시 6DoF Couch의 유용성 평가)

  • Choi, Young Se;Park, Hyo Kuk;Kim, Se Young;Kim, Joo Ho;Lee, Sang Kyoo;Yoon, Jong Won;Cho, Jung Heui
    • The Journal of Korean Society for Radiation Therapy
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    • v.29 no.2
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    • pp.53-64
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    • 2017
  • Purpose: To evaluate the usefulness of the $HexaPOD^{TM}$ evo RT system(6DoF couch) and the tendency of dose difference according to size of rotational direction error for volumetric rotational modulated radiotherapy(V-MAT) in patients with long target lengths. Therefore, it is suggested to recommend the need for rotational error correction. Materials and Methods: Ten patients with Esophagus cancer or Breast cancer including SCL treated with HexaPOD 6DoF(Six-Degree of Freedom) couch were included in this study. 6DoF couch was used to measure the difference in dose according to the rotation error in the directions of Rx(pitch), Ry(roll), and Rz(yaw). Each rotation error was applied. Positioning variation on x, y and z axis was verified and random variations were made by 6DoF couch with positioning variation. Modified DQA is conducted and point dose and gamma value are analyzed and compared. In addition, after applying the rotation error every $1^{\circ}$ to treatment plans of each target with a diameter of 3 cm, 5, 10, 15, and 20 cm respectively, gamma passing rate is being monitored by its aspect of change according to types and sizes of the target length and rotation error. Results: Mean error of the point dose and Gamma passing rate when the position variation was applied were $2.50{\pm}1.11%$ and $84.1{\pm}7.39%$ in the Rx direction, $2.36{\pm}1.16%$, and $81.0{\pm}8.49%$ in the Ry, $2.35{\pm}1.10%$ and $84.4{\pm}6.99%$ in the Rz direction, respectively. As a result of analysis on gamma passing rate according to types and sizes of the target length and rotation error, the gamma passing rate tended to decrease with increasing rotation error in the Rx and Rz directions except Ry direction. In particular, the lowest gamma passing rate (74.2 %) was in the case of $2.5^{\circ}$ rotation error in Rz direction of the target of 10 cm. Conclusion: The correction of the rotational error is needed for volumetric modulated radiotherapy of the treatment area with a long target length, and the use of 6DoF couch will improve the reproducibility of the patient position and the quality of the treatment.

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Preparation and Characterization of Chemically Stable PVDF-HFP Asymmetric Microfiltration (MF) Membranes

  • Lee, Yeon-Ee;JeGal, Jong-Geon
    • Membrane Journal
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    • v.22 no.2
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    • pp.104-112
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    • 2012
  • Chemically stable Polyvinylidene fluoride-hexa-fluoropropane (PVDF-HFP) copolymer asymmetric membranes were prepared by the conventional phase inversion process, using Dimethyacetamide (DMAc) as a solvent and water as a non-solvent. To control the pore size and porosity of the PVDF-HFP membranes, tetra-ethoxysilane (TEOS) was used as a pore-forming agent. The prepared membranes were characterized, using several analytical methods such as Fourier Transform Infrared spectroscopy (FTIR), Thermo-gravimetric analyzer (TGA), Field Emission Scanning Electronic Microscopy (FESEM). TEOS turned out to increase porosity and make homogeneous pores on the membranes. Depending on the composition of the dope solutions, the pore size was ranged from 0.1 to 1.0 ${\mu}m$. The flux of the PVDF-HFP membranes prepared by using TEOS as a pore forming agent was increased substantially without much decrease in the rejection. When 15 wt% PVDF-HFP solution was blended with 13 wt% TEOS solution at composition ratio of 70/30 in wt%, the water flux at 2 bars was about 2 $m^3/m^2day$.

Structural and Magnetic Properties of Z-type Barium Ferrite (Z-type 바리움 페라이트의 구조 및 자기적 성질)

  • Nam, In Tak
    • Journal of Industrial Technology
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    • v.28 no.A
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    • pp.119-123
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    • 2008
  • Structural and magnetic properties of $CO_{1-x}Zn_xZ$ ($Ba_3Co_{1-x}Zn_xFe_{24}O_{41}$) hexa-ferrite are studied using XRD, VSM and SEM, respectively. Powder was prepared from co-precipitation and firstly heat treated at $1350^{\circ}C$ for 6 hours in $O_2$ atmosphere. Second heat treatment was performed at 900, 1000, $1100^{\circ}C$ for 6 hours in air, respectively. Saturation magnetization value of first heat treated powder is acceptable and coercivity is high for applying to device. These result may be originated from incomplete formation reaction from M and Y phases to Z phase. Second heat treatment leads to small value of coercivity.

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Characterization of the Dye-degrading Bacteria in Aquatic Habitat (담수계내 염료 분해 세균의 특성)

  • Kim, Do-Gyeom;Hong-Bum Cho;Ho-Yong Lee;Yong-Keel Choi
    • The Korean Journal of Ecology
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    • v.16 no.1
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    • pp.51-61
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    • 1993
  • Crystal violet, a typical triphenylmenthane dye (N, N, N', N', N", N"-hexa methylparaosaniline), extensively used in textile dye, industry and research, has been suggested to cause tumor growth in botton-feeding fishes. For the isolation of crystal violet degrading bacteria, wastewaters were sampled from plants' wastewater treatment facility, textile treatment facility, textile wastewater treatment plant and etc.. The most efficient strain in crystal violet degrading bacteria was identified as Klebsiella oxytoca. Added sole carbon source in PAS minimal media was 10mg/l crystal violet, which incubated at 30。C, the degrading efficiency was maximum 12.3%. When fructose, glucose, sucrose and yeast-extract were added 0.01% in PAS media respectively, the degrading efficiency were all 96% within 24 hours.

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Horizontal and vertical profiles of PCBs in sediments from southeastern coastal areas of Korea

  • Kim, Sang-Soo;Moon, Hyo-Bang;Lee, Pil-Yong;Choi, Hee-Gu
    • Journal of the korean society of oceanography
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    • v.36 no.4
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    • pp.93-100
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    • 2001
  • The concentrations of 20 congeners of PCBs were determined in surficial and dated sediments from Jinhae, Busan, Ulsan and Yeongil Bay of Korea to assess current distributions as well as historical trends. The concentration ranges of total CBs in sediments were nd-138.60 ng/g dry wt. The concentrations of total CBs were significantly different among bays in the southeastern coastal areas (Kruskal-Wallis Test, p=0.036), Showing the Order Of Busan>Ulsan>Yeongil>Jinhae Bay. Predominant PCB homologues were penta-, hexa- and hepta-CBs. The down-core distributions of PCBs showed that the highest concentrations occurred in the late 1960s, coinciding with the onset of industrialization of Korea. The compositions of PCB congeners in sediment among bays were uniform, suggesting that major sources were not changed over time.

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