• Title/Summary/Keyword: HCHO (Formaldehyde)

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The Evaluation of Air Quality in Educational Child Care Centers (영유아 교육시설에서의 실내공기질 평가)

  • Lim, Ji-Hye;Pang, Seung-Ki;Shon, Jang-Yeul
    • The Journal of Sustainable Design and Educational Environment Research
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    • v.9 no.1
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    • pp.1-10
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    • 2010
  • It is indispensable for child care centers to investigate and manage indoor air quality (IAQ) because they perform education and day care for children who usually have weak immunity. Nevertheless, there is insufficient research being done, given its importance. This study aims to investigate indoor pollutants' concentration and to seek the causes in order to improve the air quality conditions. Also it aims to secure data which can be used for further researches. Measurements were performed for air temperature, relative humidity, carbon dioxide, carbon monoxide, fine particle mass, formaldehyde and volatile organic compounds. Temperature, humidity, CO and CO2 were measured 30times(1min/time) and PM10 was measured 10times (3min/time). Formaldehyde and volatile organic compounds were measured and analyzed based on The Indoor Air Quality Official Test Method. The results show that the temperatures were within the comfort zone in over half of the centers. CO2 was found to be the main pollutants as its concentration exceeded the IAQ standard. The concentrations of TVOC and PM10 exceeded the standard, by 32% and 24% respectively, whereas those of HCHO and CO were under the standard. HCHO and CO concentrations were under the guideline. 24% of child care centers for education were found to exceed the standard in 2 or more of the pollutants. 82% of were found to exceed the standard by 1 or more. Therefor it is requested for IAQ to manage and improve in child care center for education.

Determination of Rhodium by Inverted Catalytic Hydrogen peak as Analytical peak (뒤집힌 촉매수소 전류 봉우리를 이용한 로듐의 정량)

  • Kwon, Young-Soon;Lim, Kyong-Hee
    • Analytical Science and Technology
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    • v.16 no.4
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    • pp.269-276
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    • 2003
  • A new type of stripping voltammetry, inverted catalytic stripping voltammetry $IC_tSV$, is introduced. The rhodium-formaldehyde complex in hydrochloric acid gives an inverted catalytic hydrogen peak (reduction current peak during positive-going scan). The characteristics of the inverted peak were studied. By using the peak as analytical peak the detection limit of $1.2{\times}10^{-10}M$ Rh (50s preconcentration) can be reached at the optimal conditions: 0.015% (W/V) HCHO-0.42 M HCl; accumulation potential, -1.1 V; scan rate, 100 mV/s.

Encapsulation of Semiconductor Gas Sensors with Gas Barrier Films for USN Application

  • Lee, Hyung-Kun;Yang, Woo Seok;Choi, Nak-Jin;Moon, Seung Eon
    • ETRI Journal
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    • v.34 no.5
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    • pp.713-718
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    • 2012
  • Sensor nodes in ubiquitous sensor networks require autonomous replacement of deteriorated gas sensors with reserved sensors, which has led us to develop an encapsulation technique to avoid poisoning the reserved sensors and an autonomous activation technique to replace a deteriorated sensor with a reserved sensor. Encapsulations of $In_2O_3$ nanoparticles with poly(ethylene-co-vinyl alcohol) (EVOH) or polyvinylidene difluoride (PVDF) as gas barrier layers are reported. The EVOH or PVDF films are used for an encapsulation of $In_2O_3$ as a sensing material and are effective in blocking $In_2O_3$ from contacting formaldehyde (HCHO) gas. The activation process of $In_2O_3$ by removing the EVOH through heating is effective. However, the thermal decomposition of the PVDF affects the property of the $In_2O_3$ in terms of the gas reactivity. The response of the sensor to HCHO gas after removing the EVOH is 26%, which is not significantly different with the response of 28% in a reference sample that was not treated at all. We believe that the selection of gas barrier materials for the encapsulation and activation of $In_2O_3$ should be considered because of the ill effect the byproduct of thermal decomposition has on the sensing materials and other thermal properties of the barrier materials.

Comparative Efficiency Evaluation of Air Cleaners for Improving Indoor Air Quality (실내용 공기청정기 유형별 실내환경개선 성능에 대한 비교평가)

  • Na, Kyung-Ho;Son, Jin-Seok;Sung, Kijune;Jang, Young-Kee
    • Journal of Environmental Impact Assessment
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    • v.14 no.3
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    • pp.109-115
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    • 2005
  • This study was conducted to evaluate the efficiency of indoor air cleaners and to inform how to select them correctly to the users. The efficiencies of removing suspended bacteria per hour were $64.3{\pm}13.1%$ for filter, wet, and complex type, respectively, which showed the complex type was the most efficient. The removal efficiencies of formaldehyde (HCHO) after two hours operation of air cleaners showed 88.3% and 81.1% for filter and wet type, respectively. The efficiency of complex type, with removal rate of 55.5~58.4%, was decreased after 30 minutes operation. Therefore, it is recommended to perform over 60 minutes when doing air cleaner certification test for HCHO removal efficiency. Generally, air cleaners having low wind volume showed higher efficiency. All tested air cleaners had no potential for removing of volatile organic compounds (VOCs), which is toxic substances, and it is desirable to develop a device which can control these substances. The results also confirmed that there was no ozone production from all tested air cleaners. And it is recommended to ventilate for 20 minutes every four hours to maintain 50% ventilation status.

A Study on the Dehydrogenation of Methanol by Alkali-doped Silica-alumina Catalyst (알칼리 금속이 첨가된 silica-alumina 촉매에 의한 메탄올의 탈수소반응의 연구)

  • Kwak, Jong Woon;Park, Jin-Nam;Lee, Ho-In
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.698-706
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    • 1996
  • Dehydrogenation of methanol to produce formaldehyde was carried out over various silica-alumina catalysts doped with alkali metals in a continuous flow system. The reaction was rather dependent on Lewis acid than Br${\ddot{o}}$nsted acid suggesting that dehydrogenation of methanol was an electronic reaction. The Br${\ddot{o}}$nsted acid sites on silica-alumina were neutralized by doping with alkali metals, and the neutralization effect of Br${\ddot{o}}$nsted acid was dependent on the electron-donating capacity of the dopant metals. Activation energy for dehydrogenation of methanol decreased when Br${\ddot{o}}$nsted acid was neutralized by doping with K.

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Sensing Characterization of Metal Oxide Semiconductor-Based Sensor Arrays for Gas Mixtures in Air

  • Jung-Sik Kim
    • Korean Journal of Materials Research
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    • v.33 no.5
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    • pp.195-204
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    • 2023
  • Micro-electronic gas sensor devices were developed for the detection of carbon monoxide (CO), nitrogen oxides (NOx), ammonia (NH3), and formaldehyde (HCHO), as well as binary mixed-gas systems. Four gas sensing materials for different target gases, Pd-SnO2 for CO, In2O3 for NOx, Ru-WO3 for NH3, and SnO2-ZnO for HCHO, were synthesized using a sol-gel method, and sensor devices were then fabricated using a micro sensor platform. The gas sensing behavior and sensor response to the gas mixture were examined for six mixed gas systems using the experimental data in MEMS gas sensor arrays in sole gases and their mixtures. The gas sensing behavior with the mixed gas system suggests that specific adsorption and selective activation of the adsorption sites might occur in gas mixtures, and allow selectivity for the adsorption of a particular gas. The careful pattern recognition of sensing data obtained by the sensor array made it possible to distinguish a gas species from a gas mixture and to measure its concentration.

Identification of Gas Mixture with the MEMS Sensor Arrays by a Pattern Recognition

  • Bum-Joon Kim;Jung-Sik Kim
    • Korean Journal of Materials Research
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    • v.34 no.5
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    • pp.235-241
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    • 2024
  • Gas identification techniques using pattern recognition methods were developed from four micro-electronic gas sensors for noxious gas mixture analysis. The target gases for the air quality monitoring inside vehicles were two exhaust gases, carbon monoxide (CO) and nitrogen oxides (NOx), and two odor gases, ammonia (NH3) and formaldehyde (HCHO). Four MEMS gas sensors with sensing materials of Pd-SnO2 for CO, In2O3 for NOX, Ru-WO3 for NH3, and hybridized SnO2-ZnO material for HCHO were fabricated. In six binary mixed gas systems with oxidizing and reducing gases, the gas sensing behaviors and the sensor responses of these methods were examined for the discrimination of gas species. The gas sensitivity data was extracted and their patterns were determined using principal component analysis (PCA) techniques. The PCA plot results showed good separation among the mixed gas systems, suggesting that the gas mixture tests for noxious gases and their mixtures could be well classified and discriminated changes.

Characteristics of VOCs and Formaldehyde Emitted from Floorings (바닥재로부터 방출되는 휘발성유기화합물과 폼알데하이드 특성)

  • Park, Hyun-Ju;Jang, Seong-Ki;Seo, Soo-Yun;Lim, Jun-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.1
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    • pp.38-45
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    • 2009
  • Since the seventies and the oil crisis, energy-saving measures have led to a reduction in the ventilation of room. The use of synthetic materials which emit various chemical substances had led to an increase in the concentration of indoor pollutants. "Sick building syndrome (SBS)" and "Sick house syndrome (SHS)" are worldwide problems. Also, the number of complaints about indoor air pollution caused by VOCs (Volatile organic compound) and HCHO (Formaldehyde) has increased. It is important that evaluating and understanding emission of indoor air pollutant from building materials. The object of this study was to evaluate emission test method for flooring such as wood based flooring, carpet tile, rubber tile, PVC sheet and tile, and to determine emission of TVOC and form-aldehyde. The quantity of TVOC and carbonyl compounds emission were sampled and measured by Tenax TA and gas chromatography/mass spectrometry (GC/MSD), 2,4-DNPH cartrige with ozone scrubber and high performance liquid from flooring. The TVOC concentration emitted from carpet tile was ($7.419\;mg/m^2 h$) the highest among 5 groups of test materials. In wood based flooring and PVC tile, the emitted concentration of toluene was high. And the dodecane emission was highest in carpet. The concentration of TVOC decreased by an increase in emission test period. After 7 days, the concentration of TVOC from floorings were about 50% below of the concentration at the first day. TVOC emission from wood based flooring, carpet tile, rubber tile, PVC sheet and tile were decreased in 28 days and remained steady after about 15 days. The concentration of formaldehyde emission from floorings showed extremely low.

Scavenging Effect of Injurious VOC from Flooring using Green Tea Leaves Powder (녹차잎분말을 이용한 마루판의 유해 TVOC 제거효과)

  • Kang, Seog Goo;Lee, Hwa Hyoung
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.6
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    • pp.49-58
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    • 2008
  • This research was carried out to use green tea leaves powder for scavenging effects of volatile organic compounds on the UV varnishes and adhesives of fancy cherry veneer overlaid on the PF resin bonded Meranti plywood. The results are as follows: 1) Green tea leaves contained 9.85% of polyphenol compounds. 2) FT-IR results showed green tea leaves had effects to react with benzaldehyde and ethyl hexyl alcohol to form a chemical bond. 3) 2.5% of green tea leaves powder content was proper for scavenging effect on the UV varnishes and adhesives of fancy veneer overlaid on the PF resin bonded plywood 4) 20 liters small chamber test indicated excellent emission speed results such as $0.089mg/m^2hr$ of TVOC and $0.001mg/m^2hr$ of HCHO (on 7th day), as compared with standard (less than $0.1mg/m^2hr$ of TVOC and $0.015mg/m^2hr$ of HCHO emission are the excellent grade).

Convergence Evaluation of Indoor Air Measurement in Medical Institution (의료기관 실내공기 측정의 융합적 평가)

  • Lee, Yu-Hee;Choi, Yu-Jin;Choi, Jung-OK
    • Journal of the Korea Convergence Society
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    • v.8 no.1
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    • pp.71-76
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    • 2017
  • The purpose of this study was to investigate the indoor air quality of medical institutions and to present the detailed management plan by analyzing the actual situation of management and analyzing the difference according to the place in a convergent. ($PM_{10}$), carbon dioxide ($CO_2$), formaldehyde (HCHO), total aerobic bacteria (TAB) and carbon monoxide (CO) were investigated in 153 hospitals in Busan. As a result, The overall output average did not exceed the maintenance criteria, but the maximum values for each item were 91% for $PM_{10}$, 97% for $CO_2$, 96% for HCHO, and 99% for bioaesol. And It is confirmed that this is very close to the standard. In addition, the results of each place showed different values according to each feature, but there was no significant difference in the results of five measurements. In conclusion, Indoor air in medical institution considering the characteristics should be performed systematic and detailed management of ventilation facilities and energy problems.