• Journal of the Korean Applied Science and Technology
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• v.31 no.2
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• pp.231-237
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• 2014

The supercritical fluids (SCFs) have been widely used for material synthesis and processing due to their remarkable properties including low viscosity, high diffusivity and low surface tension. Carbon dioxide is one of the suitable solvents in SCFs processes in terms of its advantages such as easy processibility (with low critical temperature and pressure), inexpensive, nonflammable, nontoxic, and readily available. However, it has generally low solubility for high molecular weight polymers with the exception of fluoropolymers and siloxane polymers. Therefore, hydrocarbon solvents and hydrochlorofluorocarbons have been used for various SCFs process by its high solubility for high molecular weight polymers. In this report, a PMMA/clay nanocomposites were fabricated by using supercritical fluid process. The $Na^+$-MMT(montmorillonites)was modified by a fluorinated surfactant which is able to enhance compatibility with the chlorodifluoromethane(HCFC-22) and thus, improve dispersability of the clay in the polymer matrix. The PMMA/fluorinated surfactant modified clay nanocomposite shows enhanced mechanical and thermal properties which characterized by X-raydiffraction(XRD), Thermo gravimetric analysis(TGA), Dynamic mechanical analysis (DMA) and Transmission electron microscopy (TEM).

• Journal of Advanced Marine Engineering and Technology
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• v.41 no.3
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• pp.191-196
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• 2017

Owing to the harmful environmental effects of HCFC and CFC refrigerants discovered in the late 20th century, the need for environmentally friendly refrigerants such as $CO_2$ in cooling systems has increased. Air-source $CO_2$ heat pumps that utilize ambient heat in cold winter are less efficient because of a higher evaporation temperature, and it is difficult to manufacture the components of the heat pump owing to a super critical pressure of over 130 bar. This research aims to overcome these disadvantages and improve energy efficiency by introducing a new lower-pressure $CO_2$ auto-cascade heat pump system. $CO_2$-R32 zeotropic refrigerants were considered for two-stage expansion and effective cooling heat exchanging system configurations of the new auto-cascade heat pump. The results indicated that the efficiency of the two-stage expansion system was higher than that of the original one-stage expansion system. Furthermore, the two-stage expansion system showed significant performance improvements when the two-stage expansion stage from highest pressure of 70bar, intermediate expansion pressure of 25bar, and final low pressure of 10bar is applied. The COP of the new two-stage auto-cascade system (2.332) was 43.15% higher than that of the present simple auto-cascade system (1.629). Refrigerants having an evaporation temperature of $-10^{\circ}C$ or lower can be obtained that can be easily evaporated in an evaporator even at a low temperature.

• Clean Technology
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• v.14 no.1
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• pp.53-60
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• 2008

The condensation heat transfer coefficients and pressure drops of hydrocarbon refrigerants (R-290 and R-600a) and hydrochlorofluorocarbon (HCFC) refrigerants were measured in the two horizontal double pipe heat exchangers with inner diameters of 10.07 mm and 5.80 mm at a mass flux of $35.5{\sim}210.4\;kg/m^2s$ and the condensation temperature of $40^{\circ}C$. The average condensation heat transfer coefficients of hydrocarbon refrigerants were higher than that of HCFC refrigerant(R-22). The pressure drop had a magnitude in the order of R-600a > R-290 > R-22. The pressure drops in the tubes with inner diameter of 10.07 mm were approximately $6{\sim}15%$, $9.8{\sim}12.5%$ and $2.1{\sim}4.6%$ higher for R-600a, R-290 and R-22, respectively, than those with inner diameter of 5.80 mm. The condensation heat transfer coefficients were compared with the published experimental data, and showed the best agreement with Haraguchi et al.'s correlation.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1996.11a
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• pp.57-61
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• 1996

Our goal was to make a cost-effective automatic fire extinguishing system for the engine compartment use of automobiles. We designed this system for the engine compartment. This system consists of 1)foam extinguisher, 2)four nozzles, 3)a pipe arrangement, and 4)an extinguishing device which is equipped with a glass bulb as detector. First and foremost, the extinguishing device was carefully designed to keep the system cost to a minimum. Second, a AFFF foam extinguisher was used because no other fire-fighting agents proved effective against fire in the engine compartment. The AFFF(Aqueous Film Forming Foam) agent which was used in the extinguisher is the 3M company's Light Water. We sought, however, to make other foams by using Halon 1301 and Halon alternatives such as HCFC Blend A, HFC-227ea. We selected these alternatives instead of air in order to raise the expansion ratio of the AFFF agent. By these means we discovered that it is possible to increase the expansion ration of the AFFF agent up to 44:1. We then demonstrated that our automatic fire extinguishing system is the most effective and lowest cost-system yet devised for passenger cars.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.9
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• pp.2358-2372
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• 1993

In this study, the computer modeling for prediction of the performance of fin-tube heat exchanger using alternative refrigerant, HFC-134a was developed and the computer program for calculating the various properties of HFC-134a and the existing refrigerant CFC-12 and HCFC-22 was made. The heat exchanger modeling is based on a tube-by-tube approach, which is capable of analysis for the complex coil array. Performance of each tube is analyzed separately by considering the cross-flow heat transfer with external airstream and the appropriate heat and mass transfer relationships. A performance comparison according to the different refrigerants is provided using this developed model. As the result of this study, total heat transfer rate of evaporator and condenser using HFC-134a were found higher than that of using CFC-12 for the same operating conditions. When the mass flow rate of HFC-134a was less than CFC-12 about 18. 16%, the cooling capacities of evaporator were found to be the same.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.7
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• pp.681-687
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• 2005

Experimental results for heat transfer characteristic and pressure gradients of HCs refrigerants R-290, R-600a, R-1270 and HCFC refrigerant R-22 during evaporating inside horizontal double pipe heat exchangers are presented. The test sections which has one tube diameter of 12.70 m with 0.86 mm wall thickness, another tube diameter of 9.52 mm with 0.76 mm wall thickness are used for this investigation. The local evaporating heat transfer coefficients of hydrocarbon refrigerants were higher than that of R-22. The average evaporating heat transfer coefficient increased with the increase of the mass flux. It showed the higher values in hydrocarbon refrigerants than R-22. Hydrocarbon refrigerants have higher pressure drop than R-22 in 12.7 mm and 9.52 mm. This results form the investigation can be used in the design of heat transfer exchangers using hydrocarbons as the refrigerant for the air- conditioning systems.

• Journal of Power System Engineering
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• v.12 no.3
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• pp.19-25
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• 2008

This paper deals with the heat transfer and pressure drop characteristics of R-290 (Propane), R-600a (Iso-butane) and R-1270 (Propylene) as an environment friendly refrigerant and R-22 as a HCFC's refrigerant for condensing. The test section is a horizontal double pipe heat exchanger. Condensing heat transfer and pressure drop measurements were Peformed for 12.70 mm micro-fin tube and compared with the results in smooth tube. The local condensing heat transfer coefficients of hydrocarbon refrigerants were superior to those of R-22 and the maximum increasing rate of heat transfer coefficient was found in R-600a. The average condensing heat transfer coefficients in hydrocarbon refrigerants showed 20 to 28% higher values than those of R-22. Hydrocarbon refrigerants have a higher pressure drop than that of R-22 with respect to refrigerant qualify and mass flux. Also, the condensing heat transfer coefficient and pressure drop of working fluids in smooth and micro-fin tube were compared. The heat transfer enhancement factor (EF) between smooth and micro-fin tube varied from 2.2 to 2.6 in all experimental conditions.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.3
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• pp.381-388
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• 2003

An experimental study was carried out to measure the heat transfer coefficient in flow boiling to mixtures of HFC-l34a and HCFC-123 in a uniformly heated horizontal tube. Tests were run at a pressure of 0.6 MPa and in the ranges of heat flux 1-50 kw/$m^2$, vapor quality 0-100 % and mass velocity 150-600 kg/$m^2$s. Heat transfer coefficients of mixture were less than the interpolated values between pure fluids both in the low quality region where the nucleate boiling is dominant and in the high quality region where the convective evaporation is dominant. Measured data of heat transfer are compared to a few available correlations proposed for mixtures. The correlation of Jung et. al. satisfactorily predicted the present data, but the data in lower quality was overpredicted and underpredicted the high quality data. The correlation of Kandlikar considerably underpredicted most of the data. and showed the mean deviation of 35.1%.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.5
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• pp.728-734
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• 2004

Environmentally friendly refrigerants with zero ozone layer depletion potential are required to be used in refrigerators and air conditioners due to the difficulties related to ozone layer depletion and global warming. A rigorous study for the system performance with new refrigerants having zero ozone layer depletion potential is inevitable before adopting that as a new fluid. The HFC(Hydrofluorocarbon) potential has been recommended as alternatives. In this paper. system performance in the heat pump facilities were studied using R-290, R-600a. R-1270 as an environment friendly refrigerant. R-22 as a HCFC's refrigerant. The experimental apparatus has been set-up as a conventional vapor compression type heat Pump system. The test section is a horizontal double pipe heat exchanger. A tube diameter of 12.70mm with 1.315mm wall thickness is used for this investigation. The test results showed that the COP of hydrocarbon refrigerants were superior to that of R-22 and the maximum increasing rate of COP was found in R-1270. The refrigeration capacity of hydrocarbon refrigerants were higher than that of R-22. The compressor work was obtained with the maximum value in R-1270 and the minimum one in R-22.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.5
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• pp.754-761
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• 2004

In this paper, evaporating heat transfer characteristics in the refrigeration and air-conditioning facilities were studied using the environmentally friendly refrigerants R-1270 (Propylene). R-290 (Propane). R-600a (Iso-butane) and HCFC refrigerant R-22 The test tube was surrounded by an annulus with water flowing counter to the refrigerant. The tube is copper. with an outside diameter of 12.7mm and the wall thickness of 1.315mm. The test results showed that the local evaporating heat transfer coefficients of hydrocarbon refrigerants were superior to that of R-22 and the maximum increasing rate of heat transfer coefficient was found in R-1270. The average evaporating heat transfer coefficient increased with the increase of the mass velocity and it showed the higher values in hydrocarbon refrigerants than R-22 Comparing the heat transfer coefficient of experimental results with that of other correlations. the presented results had agood agreement with the Kandlikar's correlation. This results form the investigation can be used in the design of heat transfer exchangers using hydrocarbons as the refrigerant for the air-conditioning systems.