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검색결과 113,047건 처리시간 0.095초

Effects of iron atom, substrate on two-dimensional C2N crystals

  • Noh, Min Jong;Kim, Yong Hoon
    • EDISON SW 활용 경진대회 논문집
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    • 제5회(2016년)
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    • pp.288-291
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    • 2016
  • Recently, there has been a lot of researches related to two-dimensional (2D) materials due to their new properties and applications emerging upon 2D confinement. A new type of graphene like two-dimensional layer material, nitrogenated holey two-dimensional structure C2N-h2D, that is possession of evenly distributed holes and nitrogen atoms with proper bandgap has been synthesized. Previous calculation studies already have shown that the variance of the orbital interaction, band structure of few-layer C2N-h2D suggests that interlayer coupling does play an important role in its electronic properties. In this point, using first-principles density functional theory calculation, we here explore the effect of porous embedded iron atom and iron substrate on encapsulated few layer C2N-h2D. We show the atomic structures and the corresponding electronic structures of Fe@C2N to elucidate the effect of iron. Finally, this study demonstrates that embedded iron C2N has AA-stacking as most favorable stacked structure in contrast to pure C2N. In addition, iron substrate modifies its encapsulated C2N from semi-metallic states to metallic state.

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Characteristics of HfO2-Al2O3 Gate insulator films for thin Film Transistors by Pulsed Laser Deposition

  • Hwang, Jae Won;Song, Sang Woo;Jo, Mansik;Han, Kwang-hee;Kim, Dong woo;Moon, Byung Moo
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.304.2-304.2
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    • 2016
  • Hafnium oxide-aluminum oxide (HfO2-Al2O3) dielectric films have been fabricated by Pulsed Laser Deposition (PLD), and their properties are studied in comparison with HfO2 films. As a gate dielectric of the TFT, in spite of its high dielectric constant, HfO2 has a small energy band gap and microcrystalline structure with rough surface characteristics. When fabricated by the device, it has the drawback of generating a high leakage current. In this study, the HfAlO films was obtained by Pulsed Laser Deposition with HfO2-Al2O3 target(chemical composition of (HfO2)86wt%(Al2O3)14wt%). The characteristics of the thin Film have been investigated by x-ray diffraction (XRD), atomic force microscopy (AFM) and spectroscopic ellipsometer (SE) analyses. The X-ray diffraction studies confirmed that the HfAlO has amorphous structure. The RMS value can be compared to the surface roughness via AFM analysis, it showed HfAlO thin Film has more lower properties than HfO2. The energy band gap (Eg) deduced by spectroscopic ellipsometer was increased. HfAlO films was expected to improved the interface quality between channel and gate insulator. Apply to an oxide thin Film Transistors, HfAlO may help improve the properties of device.

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Depurination of Nucleosides and Calf Thymus DNA Induced by 2-Bromopropane at the Physiological Condition

  • Sherchan, Jyoti;Choi, Ho-Young;Lee, Eung-Seok
    • Bulletin of the Korean Chemical Society
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    • 제30권10호
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    • pp.2309-2317
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    • 2009
  • Depurination, the release of purine bases from nucleic acids by hydrolysis of the N-glycosidic bond, gives rise to alterations of the cell genome. Though cells have evolved mechanisms to repair these lesions, unrepaired apurinic sites have been shown to have two biological consequences: lethality and base substitution errors. 2-Bromopropane (2-BP) is used as an intermediate in the synthesis of pharmaceuticals, dyes, and other organics. In addition, 2-BP has been used as a replacement for chloroflurocarbons and 1,1,1-trichloroethane as a cleaning solvent in electronics industry. However, 2-BP was found to cause reproductive and hematopoietic disorders in local workers exposed to it. Owing to the toxicity of 2-BP, there has been a tendency to use 1-BP as an alternative cleaning solvent to 2-BP. However, 1-BP has also been reported to be neurotoxic in rats. Though $N^7$-guanine adduct of 2-BP has been reported previously, massive depurination of the nucleosides and calf thymus DNA was observed in this study. We incubated the nucleosides (ddG, dG, guanosine, ddA, dA and adenosine) with excess amount 2-BP at the physiological condition (pH 7.4, $37\;{^{\circ}C}$), which were analyzed by HPLC and LC-MS/MS. In addition, the time and dose response relationship of depurination in nucleosides induced by 2-bromopropane at the physiological condition was investigated. Similarly, incubation of calf-thymus DNA with the excess amount 2-BP at the physiological condition was also performed. In addition, the time and dose response relationship of depurination in calf-thymus DNA induced by 2-BP at the physiological condition was investigated. Those results suggest that the toxic effect of 2-BP could be both from the depurination of nucleosides and DNA adduct formation.

Aluminium Distearate 첨가가 $UO_2$ 핵연료 제조에 미치는 영향 (Effect of the Addition of Aluminium Distearate on Manufacturing of $UO_2$ Nuclear Fuel)

  • 박지연;정충환;김영석
    • 한국세라믹학회지
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    • 제29권8호
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    • pp.609-616
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    • 1992
  • This study has been investigated on the milling of Aluminium Distearate (ADS) powder and characteristics of the ADS-doped UO2 pellets. As-received ADS powder of the agglomerated particles has not shown any milling effect because of heat generated during planetary milling. But the use of coolant to effectively remove heat generated during milling has been found an effective way in breaking up the agglomerates of ADS powder. The green density of the UO2 pellet decreases with the amount of ADS powder doped. Therefore, in order to get the sintered density of 95% pellet decreases with the amount of ADS powder doped. Therefore, in order to get the sintered density of 95% theoretical density, the 200 ppm ADS-doped UO2 pellet has to be pressed under higher compacting pressure of 3500~4000 kgf/$\textrm{cm}^2$ compared with the ADS-undoped UO2 pellet pressed under around 3000 kgf/$\textrm{cm}^2$. The ADS-dpoed UO2 pellet with even relatively low sintered density of 10.27 g/㎤ exhibits open porosity of 1% while open porosity of the ADS-undoped UO2 pellet is reduced to around 1% only after its sintered density increases to 10.43g/㎤. It is, therefore, concluded that doping of ADS powder significantly contributes to the decrease in open porosity of the UO2 pellet. The dilatometry of the ADS doped UO2 pellet shows the sintering rate curve with the bimodal mode, which could be attributed to a phase reaction between UO2 and ADS. The X-ray diffraction analysis indicates that there occurs not any new phase formed but the shift of the peaks. It would be expected that a phase reaction resulting in solid solution would happen in the temperature range of 130$0^{\circ}C$ to 150$0^{\circ}C$ between UO2 and ADS.

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서울지역 일 여자 상업고등학교의 성에 대한 지식 및 태도에 관한 연구 (A Study on the Knowledge and Attitude about Sex in One Commercial Girls' High school in Seoul)

  • 김은희
    • 한국학교보건학회지
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    • 제4권2호
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    • pp.100-118
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    • 1991
  • This study was conducted in order to grasp the condition of the student's knowledge and attitude about sex. And to offer the basic materials for sex education of school health service. The objects were comprised of 464 volunteered students who study in commercial girls' high school. The material of this study was the questionaire suited to the purposed of this research which has been made through studying references. All the questionaire written by students. The self reported questionaires were collected immediately without explanation on supervision of school nurse. The data was collected from 28th to 30th of June on 1990. Analysis of the data was done utilizing SPSS for percentage, mean, ANOVA and Pearson Correlation Coefficients. The Results are as follows; 1. General features of the objects of study School grade distribution was similar. Fathers of 41-50 years were the highest(58.3%), mothers of 41-50 years were the highest(64.3%), family of living together were the highest(87.5%), fathers of graduated high school were highest(60.7%), mothers of graduated middle school were the highest(43.0%) and neuclear families were highest(91.5%). 2. The Conditions of Knowledge about sex When 5 Point was given to "Well known" and 1 point was given to "Never known", the total average was 2.97, Especially the mean of Female physiology was shown 3.93, 73.4% of students have known. But the mean of male physiology was shown 2.23, 17.2% of students only. And Family planning item was 3.54, hymen item was 3.38, female genitalia item was 3.35, abortion item was 3.25, Intercourse and pregnancy item was 3.24, Ovulation item was 3.02, Contraception item was 2.97, Veneral disease and masturbation item was 2.82, maintenance of pregnancy item was 2.76, Anatomical differences between male and female item was 2.59, male genitalia item was 2.31, ejaculation item was 2.27. 3. The conditions of attitude about Sex When 5 point was given to "Very affirming" and 1 point was given to "Very deny" the total average was 3.20. Especially the mean of social intercourse between other sex was shown 3.92, 73.4% of students have affirmed. But the mean of psychic response on menstruation was shown 2.24, 8.8% of students only. And baby birth item was 3.72, the fact that I am a woman item was 3.53, marriage item was 3.49. Secondary body change item was 3.38, puberty item was 3.31, delivery and sexual intercourse item was 3.05, pregenancy item was 3.02, psychic condition on menarche item was 2.50. Also present counsellors about sex were teachers in charge (44.9%), friends(21.6%), mothers(20.6%), elder sisters (10.6%), mass-communications (1.5%), fathers (0.4%), school nurses and elder brother(0.2%). In addition to, future counsellors about sex were friends (37.7%), mothers(30.6%), elder sister (18.4%), school nurses (4.6%), mass communication (3.8%), teachers in charge (2.5%), elder brothers (1.4%) and fathers(1.0%). 4. Correlation between the general features and knowledge variables School grade and knowledge condition has relationship to female genitalia(P<0.05), female physiology (P<0.00), male physiology (P<0.05),ovulation (P<0.00), and femily planning (P<0.005). Fathers age and knowledge condition has relationship to male physiology(P<0.05), and abortion (P<0.05). Marrital status and knowledge condition has relationship to female physiology (P<0.01), masturbation (P<0.05). Fathers educational background and knowledge condition has relationship to masturbation (P<0.00). Mothers age and knowledge condition has relationship to family planning (P<0.05). 5. Correlation between the general futures and attituded variables Fathers age and attitude condition has relationship to psychic response on menstruation (P<0.05). Mothers age and attitude condition has relationship to fact that I am a woman (P<0.00). Mothers educational background and attitude condition has relationship to social intercourse between other sex (P<0.05). Type of family and attitude condition has relationship to puberty (P<0.01). 6. Correlation between knowledge condition and attitude condition Those who had more knowledge about sex have more affirmative response (P<0.001).

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전복 양식업의 경영비 분석과 정책 시사점 연구 (The Research on the Cost Analysis of the Abalone Aquacultural Management in Korea)

  • 옥영수
    • 수산경영론집
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    • 제46권2호
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    • pp.13-29
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    • 2015
  • The abalone aquaculture has been very rapidly developed in Korea. Annual production quantity was less 200 tons before 2000th, it have been increased to over 9,000 tons in 2014. Also Abalone export amounts have been over 20 million dollars. The reason of rapid growth of Abalone aquaculture in Korea is due to high level profit ratio. Then now many fishing officers and other aquaculture fishers want to participate with abalone aquaculture newly. However Recent Abalone aquaculture in Korea is faced some problems. Aspects of production environmental status of fishing grounds are more aggravate, and then abalone aquaculture is exposed to various disease, and death rate of young abalone is higher. And aspect of management, the aquaculture cost is more increase. The demand of abalone also is depressing recently, this cause to come down the production price. In this viewpoint, Management analysis of abalone aquaculture in Korea is helpful for decision making of general aquaculture fisher want to participate newly. The analysis is practiced two aspects. One is index analysis, and the other is Break-even-point(BEP) analysis. The result of index analysis, average net profit rate has shown 28.0%, however the Regional difference has excessive. That is, Wando(major) has shown 39.4%, and Haenam province has shown 14.2%. On the other hand, the more scale has shown higher profit rate by aquaculture scale. And the result of BEP analysis, average has shown 93 cage number per abalone aquaculture household, and Wando(major) has shown 56 cage number, Haenam province has shown 131 cage number. The lower production abalone price of recent means higher BEP level.

제주도 개발사업의 '선보전 후개발' 원칙 적용 사례분석 (A Case Study on the Application of 'Conservation First Development Later' Principle for the Development Projects in Jeju Area)

  • 조은일;허철구
    • 한국환경과학회지
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    • 제23권1호
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    • pp.113-128
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    • 2014
  • Jeju Special Self-Governing Province has the natural assets resulting in UNESCO World Biosphere Reserve, World Heritage Listed and World Geopark Certification, so the principle of 'Conservation First Development Later' has been set up for the vision of environmental policy to preserve these assets. This case study has been carried out to investigate the realization of the principle of 'Conservation First Development Later' for the development projects performed environmental impact assessment from 1994 to 2012 in Jeju Province, using geographic information systems(GIS). The Jeju Province has its own ordinance to consult and operate an environmental impact assessment(EIA) system. In particular, the conservation area, such as, Absolute/Relative Conservation Area and Underground Water, Ecosystem and View Conservation Zone, has been assigned and managed specially to conserve the natural environment. The 179 projects has been performed EIA for last 18 years in Jeju Province, and then the Absolute Conservation Area has been included in 22 projects and the Relative Conservation Area has been included in 34 projects. However, the 2 projects only have included the Absolute Conservation Area for 7 years after 2005. This result suggests that the application of the principle for the Absolute Conservation Area is strengthened gradually. On the other hand, the 17 projects and the 24 projects have included the Underground Water Conservation Zone assigned grade 1 and 2, respectively, and the number has been increasing after 2004. The results show that it needs to strengthen the application of the principle for this Zone. And the Ecosystem Conservation Zone assigned grade 1 and 2 have been included in 1 project and 9 projects, respectively. It is considered from this result that the principle is realized successfully for the Ecosystem Conservation Zone. In addition, it could be known that the principle is applied well for the View Conservation Zone, in this study.

Allergy성(性) 접촉피부염(接觸皮膚炎)이 유발된 백서(白鼠)의 손상피부(損傷皮膚)에 열다한소탕(熱多寒少湯) 전탕액(煎湯液)이 미치는 영향(影響) (Effects of Yuldahansotang on rat skin occured the Allergic Contact Dermatitis)

  • 박성식;김만식
    • 사상체질의학회지
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    • 제14권3호
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    • pp.97-113
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    • 2002
  • Objective To study the effectiveness of Yuldahansotang against Allergic Contact Dermatitis, the change of cutaneous shape, histochemistry, immunohistochemistry and distribution of apoptotic cells was researched. materials and methods 4-month-old rats were divided into three groups of 10. One is a contrastive group which has applied Acetone olive oil only. Another is ACD group which has intentionally activated Allergic Contact Dermatitis by DNCB. And the other is YST group which has given medication of Yangkyuksanhawtang extract. Each group of mice were observed after 24, 48 and 72 hours. results 1. With the result of Contact hypersensitivity assay, YST group shows appreciably less ear swelling than ACD group. 2. Comparing YST and ACD groups to each other regarding general change of skin, YST group shows less hyperplasia of epidermis, less migration of inflammatory cells and less damage of epidermis than ACD group. 3. Regarding the change of collagen fiber, ACD group has appeared to be low in number of collagen fiber while YST shows similarity with the contrastive group. 4. In dermis YST group has showed lower number of mastocyte than ACD group and is granulated type. 5. In dermis YST group has showed less MAC-1,IL-1, $IL-2R-{\alpha}$, ICAM-1 and VCAM-1 than ACD group. 6. The distribution of apoptotic cells has appeared littler in YST group than in ACD 7. Among signal molecule of apoptosis Bcl-2 has distributed more in YST group than ACD group and Bax and Fas has distributed less in YST group than ACD group.

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효율적인 P2P 시스템개발 사례 (Study on the Effective System for P2P)

  • 송은지
    • 디지털콘텐츠학회 논문지
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    • 제7권2호
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    • pp.89-94
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    • 2006
  • 전 세계적으로 큰 파장을 일으키고 있는 P2P 비즈니스는 인터넷의 급속한 보급과 더불어 고속 인터넷 접속 서비스가 확산되고, 고성능 PC 보급을 통한 사용자 환경이 강화되면서 가능하게 되었다. P2P란 서버와 클라이언트 개념에서 벗어나 개인 컴퓨터끼리 직접 연결하고 검색함으로써 모든 접속자가 공급자인 동시에 수요자가 되는 형태를 말한다. 최근 P2P는 개인간의 단순한 파일공유 서비스가 아닌 기업 간 전자거래에 응용하는 등 다양한 시스템이 개발되고 있다. 본 연구에서는 기존의 P2P의 기능을 보완한 보다 효율적인 시스템을 제안한다.

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$H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$를 이용한 2중 효용 흡수식 냉동기 특성해석 (Characteristic Analysis of Double Effect Absorption Refrigeration Machine using $H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$)

  • 문춘근
    • Journal of Advanced Marine Engineering and Technology
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    • 제22권6호
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    • pp.792-799
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    • 1998
  • Further improvement of existing $H_{2}O/LiBr$ absorption refrigeration machine is absolutely neces-sary to promote the utilization of gas-cooling system Among various methods to improve the per-formance of the absorption refrigeration machine this research has focused on the use of a new working fluid that has better properties than the existing $H_{2}O/LiBr$ working fluid. In the series of the research, $H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$ system was selected as the most promisable candidate. The absorption refrigeration machine is water-cooled double-effect, $H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$ sys-tem with series flow type. In this study we found out the characteristic of new working solution through the cycle simulation and compared the result with that of LiBr solution to evaluate. Theoptimum designs and operating conditions were determined based on the operating constraints and the coefficient of performance. Results demonstrate that new working fluid subsrantially increases COP by as much as 10% and has a wider working range with 8% higher crystallization limits compared to the conventional $H_{2}O/LiBr$.

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