• Title/Summary/Keyword: HAS-2

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Enhanced photocatalytic oxidation of humic acids using Fe3+-Zn2+ co-doped TiO2: The effects of ions in aqueous solutions

  • Yuan, Rongfang;Liu, Dan;Wang, Shaona;Zhou, Beihai;Ma, Fangshu
    • Environmental Engineering Research
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    • v.23 no.2
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    • pp.181-188
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    • 2018
  • Photocatalytic oxidation in the presence of Fe-doped, Zn-doped or Fe-Zn co-doped $TiO_2$ was used to effectively decompose humic acids (HAs) in water. The highest HAs removal efficiency (65.7%) was achieved in the presence of $500^{\circ}C$ calcined 0.0010% Fe-Zn co-doped $TiO_2$ with the Fe:Zn ratio of 3:2. The initial solution pH value, inorganic cations and anions also affected the catalyst photocatalytic ability. The HAs removal for the initial pH of 2 was the highest, and for the pH of 6 was the lowest. The photocatalytic oxidation of HAs was enhanced with the increase of the $Ca^{2+}$ or $Mg^{2+}$ concentration, and reduced when concentrations of some anions increased. The inhibition order of the anions on $TiO_2$ photocatalytic activities was $CO{_3}^{2-}$ > $HCO_3{^-}$ > $Cl^-$, but a slightly promotion was achieved when $SO{_4}^{2-}$ was added. Total organic carbon (TOC) removal was used to evaluate the actual HAs mineralization degree caused by the $500^{\circ}C$ calcined 0.0010% Fe-Zn (3:2) co-doped $TiO_2$. For tap water added with HAs, the $UV_{254}$ and TOC removal rates were 57.2% and 49.9%, respectively. The $UV_{254}$ removal efficiency was higher than that of TOC because of the generation of intermediates that could significantly reduce the $UV_{254}$, but not the TOC.

Structure of sensilla on the Antenna and Mouthparts of the Oriental Tobacco Budworm(Heliothis assulta Guenee) Larvae (담배나방의 유충의 촉각 및 구기 감각기의 구조)

  • 박순식;부경생
    • Korean journal of applied entomology
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    • v.27 no.2
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    • pp.94-102
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    • 1988
  • Studies were carried out to describe the structure and distribution of various sensilla on the antenna and mouthparts of the Oriental tobacco bud worm (H. assulta) larvae by light and scanning electron microscopy. The larval antenna has 3 segments. The second segment has 2 hairs and 3 pegs, while the third segment shows 3 regular pegs and a segmented peg (styloconicum type). Each mandible bears 2 aporous hairs on the lateral surface. The labrum bears 12 aporous hairs on its external surface. and 6 aporous hairs, 4 coeloconica-like sensilla and 2 campaniformia-like sensilla on its epipharynx. The stipes has 3 hairs, and the galea has 3 pegs. 2 papillae and 2 domes. The maxillary palpus has only a digitiform sensillum on its 1st segment but 11 sensilla of 4 different types on its 2nd segment. Maxillary sensilla represent almost 70% of total number of larval sensilla on the mouthparts. Labial pal pus has a single segment bearing a large segmented uniporous peg and a small peg. Finally their possible fun¬ctions were suggested.

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Aminolysis of 2,4-Dinitrophenyl 2-Furoate and 2-Thiophenecarboxylate: Effect of Modification of Nonleaving Group from Furoyl to Thiophenecarbonyl on Reactivity and Mechanism

  • Um, Ik-Hwan;Min, Se-Won;Chuna, Sun-Mee
    • Bulletin of the Korean Chemical Society
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    • v.29 no.7
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    • pp.1359-1363
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    • 2008
  • Second-order rate constants have been determined spectrophotometrically for reactions of 2,4-dinitrophenyl 2- thiophenecarboxylate (2) with a series of alicyclic secondary amines in 80 mol % $H_2O$/20 mol % DMSO at 25.0 ${\pm}$ 0.1 ${^{\circ}C}$. The Brønsted-type plot exhibits a downward curvature, i.e., the slope decreases from 0.74 to 0.34 as the amine basicity increases. The $pK_a$ at the center of the Brønsted curvature, defined as $pK_a^o$, has been determined to be 9.1. Comparison of the Brønsted-type plot for the reactions of 2 with that for the corresponding reactions of 2,4-dinitrophenyl 2-furoate (1) suggests that reactions of 1 and 2 proceed through a common mechanism, although 2 is less reactive than 1. The curved Brønsted-type plot has been interpreted as a change in RDS of a stepwise mechanism. The replacement of the O atom in the furoyl ring by an S atom (1 $\rightarrow$ 2) does not alter the reaction mechanism but causes a decrease in reactivity. Dissection of the apparent second-order rate constants into the microscopic rate constants has revealed that the $k_2/k_{-1}$ ratio is not influenced upon changing the nonleaving group from furoyl to thiophenecarbonyl. However, $k_1$ has been calculated to be smaller for the reactions of 2 than for the corresponding reactions of 1, indicating that the C=O bond in the thiophenecarboxylate 2 is less electrophilic than that in the furoate 1. The smaller k1 for the reactions of 2 is fully responsible for the fact that 2 is less reactive than 1.

Effect of $ M_2O_3$ on the Sinterbility and Electrical Conductivity of $ZrO_2(Y_2O_3)$ System(II) : Ceramics of the $ZrO_2(Y_2O_3)$-$Sb_2O_3)$ System ($ZrO_2(Y_2O_3)$계 세라믹스의 소결성과 전기전도도에 대한 $ M_2O_3$의 영향 (II): $ZrO_2-Y_2O_3-Sb_2O_3$계 세라믹스)

  • 오영재;정형진;이희수
    • Journal of the Korean Ceramic Society
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    • v.23 no.6
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    • pp.37-44
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    • 1986
  • Yttria-antimonia-stabilized zirconia was investigated with respect to the amount of $Sb_2O_3$ addition in the range of 0.5~5mole% to the base composition of $(ZrO)_{0.92}(Y_2O_3)_{0.08}$ The sinterbility modulus of rupture Vickers hardness evaporation of components phase form-tion and mcicrostructure were evaluated with antimonia content. Also two probe A. C conductivity measurement was subjected to all specimens and the best results are achieved with 1mol% $Sb_2O_3$ as a sinter agent and relative density of~98% obtained at 140$0^{\circ}C$ and this composition has a maximum electrical conductivity due to the possible substition of $Sb^{3+}$ for $Zr^{4+}$ site. The effect of $Sb_2O_3$ on the electrical conductivity of th bulk and the grain boundaries has on investigated using frequency dispersion analysis (5~106 Hz) Antimonia addition has a negative in-fluence on both the bulk and the grain boundary conductivity except for a 1 mon% addition. The additive antimonia has improve a modulus of rupture to 60~MPa due to metastable-tetragonal phase apparence and decrease the hardness with increasing the $Sb_2O_3$ content.

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Sintering and Machanical Properties of Y2O3 Added Al2O3-TiC Composite (Y2O3가 첨가된 Al2O3-TiC복합 소결체의 치밀화와 기계적 성질)

  • 최종선;박상엽;김득중;강석중
    • Journal of the Korean Ceramic Society
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    • v.26 no.3
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    • pp.438-444
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    • 1989
  • The role of TiC and the effect of Y2O3 addition on the densification, microstructure and mechanical properties of Al2O3-TiC composite have been studied. The amount of Y2O3 has been varied from 0 to 2 wt.% while keeping the TiC content at 10, 20 or 30 wt.%. The powder compacts have been sintered at 1,75$0^{\circ}C$ for various times in 1 atm Ar atmosphere and hot isostatically pressed (HIPed) at 1,$600^{\circ}C$ for 0.5h under 1,500atm Ar. Considerable increase in sintered density(over 95%) has been achieved by adding 0.5 wt.% Y2O3 in specimens containing high TiC volume. More addition of Y2O3 does not affect the densification. With increasing the sintering time from 0.5 to 4h, slight increase in density results. The growth of Al2O3 grain has been enhanced by Y2O3 addition ; this tendency is reduced with increasing TiC content because of grain boundary dragging effect of TiC particles. The hardness of specimens increases considerably by an addition of 0.5wt.% Y2O3 owing to the density increase. Further addition of Y2O3 has no effect on hardness. Fracture toughness augments with TiC content by crack deflection around the particles. By adding 0.5wt.% Y2O3, all the specimens can be densified to isolated pore stage and thus can be HIPed to full densification and better mechanical property. In particular, the fracture toughness of Al2O3-30 TiC specimen increases about 50% by HIPing. Fully dense Al2O3-30 TiC with good mechanical properties can be prepared by normal Sintering/HIPing process.

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Shopping Orientation Impacting Reuse Intention of O2O Services: Focusing on the Moderation of Impulse Buying Tendency (쇼핑성향이 패션 O2O 서비스 재이용 의도에 미치는 영향: 충동구매성향 조절효과를 중심으로)

  • Hahn, Jungwon;Lee, Eun-Jung
    • Fashion & Textile Research Journal
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    • v.20 no.6
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    • pp.645-655
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    • 2018
  • Online to Offline(O2O), a new model of e-commerce, has been gradually recognized and accepted by consumers. Electronic commerce has become diversified and O2O marketing is the new trend of e-commerce. The rapid popularization of mobile Internet and online shopping makes O2O service gets more attention. Although recently O2O service and O2O marketing get much attention, there is no much preceding research about the antecedents of mobile shopping of O2O market. The purpose of the study is to examine the effect of shopping orientation on intention to reuse O2O services and the moderating effect of impulse buying tendency. A total of 209 surveys were collected online in total for the data of the study. The key findings of this study are as follows: First, convenience seeking shopping orientation has a positive effect on the intention to reuse O2O service and brand seeking shopping orientation has, too. Second, impulse buying tendency positively moderated the relationship between hedonic seeking shopping orientation and intention to reuse O2O service, and negatively moderated sales seeking shopping orientation and intention to reuse O2O service. The results of this study presented some implications for operators at O2O service area. Research findings and study limitations are discussed.

Simulations of Capacitively Coupled Plasmas Between Unequal-sized Powered and Grounded Electrodes Using One- and Two-dimensional Fluid Models

  • So, Soon-Youl
    • KIEE International Transactions on Electrophysics and Applications
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    • v.4C no.5
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    • pp.220-229
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    • 2004
  • We have examined a technique of one-dimensional (1D) fluid modeling for radio-frequency Ar capacitively coupled plasmas (CCP) between unequal-sized powered and grounded electrodes. In order to simulate a practical CCP reactor configuration with a grounded side wall by the 1D model, it has been assumed that the discharge space has a conic frustum shape; the grounded electrode is larger than the powered one and the discharge space expands with the distance from the powered electrode. In this paper, we focus on how much a 1D model can approximate a 2D model and evaluate their comparisons. The plasma density calculated by the 1D model has been compared with that by a two-dimensional (2D) fluid model, and a qualitative agreement between them has been obtained. In addition, 1D and 2D calculation results for another reactor configuration with equal-sized electrodes have also been presented together for comparison. In the discussion, four CCP models, which are 1D and 2D models with symmetric and asymmetric geometries, are compared with each other and the DC self-bias voltage has been focused on as a characteristic property that reflects the unequal electrode surface areas. Reactor configuration and experimental parameters, which the self-bias depends on, have been investigated to develop the ID modeling for reactor geometry with unequal-sized electrodes.

The Green Growth Policy of the Lee Myung-bak Government: Policy Integration Perspectives for System Transition

  • Seong, Jieun
    • STI Policy Review
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    • v.2 no.2
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    • pp.11-24
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    • 2011
  • S&T policy has been traditionally regarded as a sector policy; however, it is now evolving into an infrastructure innovation policy that forms the foundation of diverse types of policies. Simultaneously, environmental and energy policies formerly considered as sector policies are now being expanded and integrated into a higher level policy for sustainable development. With these changes underway, the importance of policy integration has increased. Efforts are being made to minimize contradictions between environmental, social, and innovation policies that emphasize proactive linkage among policies or place the highest priority on environmental policy following the theory of Environmental Policy Integration (EPI). Confronted with these policy changes, the Lee Myung-bak government announced "Low-Carbon Green Growth" in 2008 as national agenda for development that focus attention on environmental and energy issues. Economic policy and environmental policy have been traditionally seen in a conflicting relationship with different paths of policy development. However, the administration of President Lee is now emphasizing the synergy effects between the environment and economic growth with the concept of green growth. The green growth policy of the Korean government has great significance as it has built a momentum for incorporating social goals such as environmental values or sustainable development into economic growth-oriented policies; however, there remain many challenges due to the legacy of the development period that has dominated Korean society. The Korean government says it reflects "EPI" or "environmentalism" in policy goals; however, in reality it prioritizes development over the environment.

Isolated Digit Recognition Combined with Recurrent Neural Prediction Models and Chaotic Neural Networks (회귀예측 신경모델과 카오스 신경회로망을 결합한 고립 숫자음 인식)

  • Kim, Seok-Hyun;Ryeo, Ji-Hwan
    • Journal of the Korean Institute of Intelligent Systems
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    • v.8 no.6
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    • pp.129-135
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    • 1998
  • In this paper, the recognition rate of isolated digits has been improved using the multiple neural networks combined with chaotic recurrent neural networks and MLP. Generally, the recognition rate has been increased from 1.2% to 2.5%. The experiments tell that the recognition rate is increased because MLP and CRNN(chaotic recurrent neural network) compensate for each other. Besides this, the chaotic dynamic properties have helped more in speech recognition. The best recognition rate is when the algorithm combined with MLP and chaotic multiple recurrent neural network has been used. However, in the respect of simple algorithm and reliability, the multiple neural networks combined with MLP and chaotic single recurrent neural networks have better properties. Largely, MLP has very good recognition rate in korean digits "il", "oh", while the chaotic recurrent neural network has best recognition in "young", "sam", "chil".

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Floodwave Modeling in Inundated Area Resulting from Levee-Break (제내지에서의 범람홍수파 해석을 위한 수치모형의 개발)

  • 이종태;한건연
    • Water for future
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    • v.28 no.5
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    • pp.163-174
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    • 1995
  • A diffusion hydrodynamic model named "DFLOW-2" for the floodwave analysis from levee-break in protected lowland has been developed. The model has been applied to Ilsan levee-break, which occurred on September 12-13, 1990 in the downstream of the Han River. An unsteady flow analysis has been made in the reach from Indokyo to Junryu. Overflow through broken levee has been treated as internal boundary condition in the channel. A post-processor has been also developed to demonstrate the simulation results. The velocity distributions and inundated depths have been presented. The computed results have good agreements with observed data in terms of inundation depth, flood arrival time and flooded areas.ded areas.

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