• Title/Summary/Keyword: H17/28

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Synthesis and X-Ray Structure of 25-Acetoxy-26,27,28-trimethoxycalix[4]arene

  • Park, Yeong Ja;No Kwanghyun;Song Boo-Hee;Rhim Soo Kyung
    • Bulletin of the Korean Chemical Society
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    • v.15 no.12
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    • pp.1108-1112
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    • 1994
  • 25-Acetoxy-26,27,28-trimethoxycalix[4]arene was synthesized by the treatment of calix[4]arene trimethyl ether with acetyl chloride in the presence of NaH. The solution conformation was inferred as a partial cone conformation based on the $^1H$-and $^{13}C$ NMR spectra. The crystal structure has been determined by X-ray diffraction method. The crystals are monoclinic, space group $P2_1$/n, a=8.186 (1), b=17.137 (2), c=19.878 (3) ${\AA}$, ${\beta}$=95.67 (1)$^{\circ}$, Z=4, V=2774.90 ${\AA}^3$, $D_c$= 1.22 g $cm^{-3}$, $D_m$=1.23 g $cm^{-3}$. The intensity data were collected on an Enraf-Noninus CAD-4 Diffractometer with a graphite monochromated $Cu-K{\alpha}$ radiation. The structure was solved by direct method and refined by full-matrix least-squares methods to a final R value of 0.054 for 3675 observed reflections. The molecule possesses a partial cone conformation with one flattened phenyl unit, in which one anisol ring, distal to the ester ring, is inverted. The acetoxyphenyl ring is flattened.

Characterization of Shrinkage Reducing Type Cement Carbon Dioxide-reducible CSA Synthesis (이산화탄소 저감형 CSA합성을 통한 수축저감형 시멘트의 특성 평가)

  • Cho, Yong-Kwang;Nam, Seong-Young;Kim, Chun-Sik;Cho, Sung-Hyun;Lee, Hyoung-Woo;Ahn, Ji-Whan
    • Journal of Energy Engineering
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    • v.28 no.1
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    • pp.17-21
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    • 2019
  • Calcium sulfaluminate (CSA) was synthesized to improve the shrinkage of OPC. In this study, the setting time, the compressive strength and the length change ratio were confirmed by replacing the synthesized CSA with OPC by 10% and 13% by 16%. In the case of shrinkage-reducing type cement, formation of Ca-Al-$H_2$-based hydrate was activated. Therefore, the setting time was shortened. The compressive strength of the shrinkage - reducing type cement is comparable to that of OPC after 7 days' strength. However, shrinkage reducing type cement showed improved initial strength compared to OPC. The length change ratio was found to be improved by drying shrinkage from -0.075% to -0.047% on the 28th day.

Effect of Perforated PVC Underdrainage Pipe on Desalting of Plastic Film House Soils (시설재배지 유공관 암거배수에 의한 염류집적 경감효과)

  • Kim, Dae-Su;Yang, Jae E.;Ok, Yong-Sik;Yoo, Kyung-Yoal
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.2
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    • pp.65-72
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    • 2006
  • Objective of this research was to remove the accumulated salts in the plastic film house soils by installing the perforated PVC (${\phi}10cm$) underdrainage pipes at 50 cm depth of soils with cultivating vegetables. Efficiency of the underdrainage pipes was assessed based on the changes of soil chemical properties such as pH, EC, and cations, and growth and yield parameters of the vegetables between the two treatments; the control and the underdrainage pipe treatments. The EC of the underdrainage pipes installed soils after two growing seasons were in the ranges of $1.42-2.88dS\;m^{-1}$ but those of the control were in the ranges of $3.86-4.53dS\;m^{-1}$, indication the underdrainage pipes effectively removed the accumulated salts in soils. The pHs of the control soils and the underdrainage pipe installed soil were in the ranges of 7.2-7.5 and 6.9-7.3, respectively. There was a significant correlation between pH and cation exchange capacity (CEC) of the soils ($CEC=17.107{\times}pH-106.2$, $r^2=0.759$, P < 0.05). The ECs of the soils at different depths were compared between the two treatments after cultivating vegetables with lettuce-lettuce-garland chrysanthemum rotation systems. The ECs of the control soils at depths of 0-10, 10-20, 20-30, 30-40, and 40-50 cm were 3.45, 3.47, 3.03, 2.03, and $2.28dS\;m^{-1}$, respectively, with decreasing with soil depths. On the other hand, the respective ECs of the underdrainage pipes installed soils were 2.43, 2.52, 2.28, 4.00, and $4.23dS\;m^{-1}$ with increasing with soil depths. This might be derived from the salts moved downward with the draining water into the subsoil. The order of cations moved downward was Mg > Ca > K, based on the ratios of cations at specific depth over those at the surface soil. The survival rates of lettuce after 15 days of transplanting in the underdrainage pipe installed soils were 98.2% as compared to 86.6% of the control. The underdrainage pipe treatment also increased the diameter of the lettuce stalk from 12.9mm of the control to 13.7mm. Overall results demonstrated that the installment of the underdrainage pipes in the subsoils of the salt accumulated plastic film house soil effectively removed the salts by leaching downward,resulting in lowering soil EC and enhancing the growth and yield of vegetables.

Assessment of the Running Resistance of a High-speed Train Using a Coasting Test (타행 시험을 이용한 고속열차 주행저항 평가)

  • Kwon, Hyeok-Bin;Kim, Seogwon;Oh, Hyuck Keun
    • Journal of the Korean Society for Railway
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    • v.17 no.3
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    • pp.165-170
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    • 2014
  • The resistance to motion of the Korean next-generation high-speed train (HEUM-430X) was assessed on the basis of 12 coasting test runs at coasting speeds up to approximately 380km/h. Two different methods, a linear regression method and a time-integral method, were employed to calculate decelerations from the time-velocity data and the time-distance data, respectively, and an equation of resistance to motion was devised from the deceleration data calculated at each time section. The effect of an improvement of the aerodynamic shape on the resistance to motion was investigated, with the results showing that the running resistance was reduced by about 15% due to these improvements. An increase of approximately 28% of the running resistance was also noted when running in a tunnel relative to running through an open field.

Analysis of Dynamic Characteristics for Concept Design of Independent-Wheel Type Ultra-High-Speed Train (독립차륜형 초고속 열차 개념 설계안의 동특성 해석)

  • Lee, Jin-Hee;Kim, Nam-Po;Sim, Kyung-Seok;Park, Tae-Won
    • Journal of the Korean Society for Railway
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    • v.17 no.1
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    • pp.28-34
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    • 2014
  • In this paper, a concept design of a rail type ultra-high-speed train is proposed and its dynamic characteristics are analyzed. Instead of the existing solid axle, a new type bogie system and independently rotating wheels are applied in the proposed train. In order to analyze the dynamic characteristics, a multibody dynamic model of a vehicle is developed and the basic validity is verified by eigenvalue analysis. Also, it is shown that the critical speed is improved in comparison to that of existing high-speed train model HEMU-430X. Finally, through 7000R curved track driving analysis at a speed of 550 km/h, the lateral force of the wheels and the derailment quotient are estimated and the applicability of the new concept railway vehicle is confirmed.

Isolation and Linkage Mapping of Coding Sequences from Chicken Cosmids by Exon Trapping

  • Mannen, H.;Dote, Y.;Uratsuji, H.;Yoshizawa, K.;Okamoto, S.;Tsuji, S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.3
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    • pp.309-312
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    • 2004
  • We performed exon trapping in order to locate functional genes on chicken chromosomes (GGA) and to identify functional gene sequences from chicken cosmids. Sequence analysis of 100 clones revealed 17 putative exons, five of which were identified with known sequences in a gene database search: thymopoietin beta (TMPO), U5 snRNP-specific 40 kDa protein (HPRP8BP), dihydropyridine receptor alpha 1 subunit (CACNL1A3), cystein string protein (CPS) and C15orf4. We attempted to map the genes to chicken chromosomes by using FISH and linkage analysis. The chromosomal localizations were GGA1 (TMPO), GGA10 (C15orf4), GGA23 (HPRP8BP) and GGA28 (CPS) by FISH and linkage analysis, while that of CACNL1A3 was predicted to be on a microchromosome by FISH but not by linkage analysis. Comparative mapping analyses between chickens and humans for the genes revealed both known and new synteny. The syntenic conservation between GGA1 and human chromosome (HSA) 12q23 (TMPO) and between GGA10 and HSA15q25 (C15orf4), were consistent with a recent publication, while two new syntenies were observed between GGA28 and HSA20q13.3 in CPS and between GGA23 and HSA1p34-35 in HPRP8BP. The information of presently mapped genes can contribute as anchor markers based on functional genes and the construction of a comparative map.

Study on the Effects of Morphology, Preservation and Reproductive Cycle of In Vitro Developmental Rate of Cats Oocytes (난자의 형태와 난소의 보존 및 채취시기가 고양이 난자의 체외발생에 미치는 영향에 관한 연구)

  • 전연화;이명헌;김상근
    • Journal of Embryo Transfer
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    • v.18 no.2
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    • pp.109-113
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    • 2003
  • The study was carried out to investigate the effects of morphology, preservation and reproductive cycle of oocytes in vitro maturation of cats oocytes and development of IVM embryos. The results were summarized as follows : 1. Nuclear status of GV and MI of in vitro cultured(24 h) oocytes with and whithout cumulus cells were 74.3% and 25.7%, 28.6% and 11.4%, 77.1% and 5.7%, respectively, The rate of oocytes with cumulus cells was higher than that of denuded oocytes. 2. Nuclear status of GV and MI of in vitro cultured(24 h) oocytes recovered from ovaries collected at different stages of the reproductive cycle(inactive, follicular and luteal) were 88.6% and 6.5%, 60.0% and 11.4%, 77.1% and 5.7%, respectively. 3. Nuclear status of fresh and salts-stored oocytes with and whithout cumulus cells were 74.3%, 25.7% and 37.1%, 11.4% and 57.1%, 13.3%, 17.1%, 3.3%, respectively. The rate of oocytes with cumulus cells(13.3%∼74.3%) was higher than that of denuded oocytes(3.3%∼57.1%).

60 GHz Optical Carrier Generator using Quasi-Velocity-Matching Technique (Quasi-Velocity-Matching물 이용한 60 GHz 광캐리어 발생기)

  • Kim, W.K.;Yang, W.S.;Lee, H.M.;Lee, H.Y.;Jeong, W.J.;Kwon, S.W.
    • Korean Journal of Optics and Photonics
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    • v.17 no.2
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    • pp.181-185
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    • 2006
  • A novel 60GHz optical carrier generator with a polarization domain-inverted structure is suggested and is demonstrated. The two arms of the Mach-Zehnder optical waveguide are periodically poled for quasi-phase velocity matching between the optical wave at 1550nm and the RF wave at 30 GHz. The center frequency of band-pass modulation and the 3 dB bandwidth of the fabricated modulator were measured to be 30.3 GHz and 5.1 GHz, respectively. Sub-carriers with the frequency difference of 60GHz waeregenerated under appropriate DC biac voltage application while the carrier was suppressed to lead to the power ratio between the modulated sub-carrier and the suppressed fundamental carrier of 28 dB, which proves that double sideband- suppressed carrier(DSB-SC) operation can be realized by the suggested single device.

Carcass Traits and Their Relationships in Hanwoo(Korean Native) Steers (한우 거세우의 도체 형질간의 관계)

  • Baik, D.H.;Hoque, M.A.;Park, H.K.;Chung, Y.H.
    • Journal of Animal Science and Technology
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    • v.44 no.5
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    • pp.593-598
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    • 2002
  • This experiment was prosecuted to estimate the carcass traits and their relationships in Hanwoo steers. The mean carcass weight(CWT), back fat thickness (BFT), meat, bone, intra- muscular fat (IMF) and eye muscle area (EMA) of steers were 300.27 kg, 9.23 mm, 58.99%, 12.92%, 28.08% and 74.00 $cm^2$, respectively. The pHB(before aging), pHA(after aging), cook loss before aging($CL_B$) and cook loss after aging ($CL_A$) were 5.32, 5.60, 16.43% and 19.21%, respectively. It was also found that the MS and FC were 3.67 and 3.17, respectively. The EMA and quantity index (QIX) were positively correlated with CWT, meat% and bone% but negatively correlated with IMF%. The BFT was positively correlated with CWT and meat% but negatively correlated with bone% and IMF%. The pH (both before and after aging) was negatively correlated with CL (both before and after aging), water loss during freezing (WLF) and FC. The muscle score(MS) was negatively correlated with CL but positively correlated with WLF and FC. The ARM, HRD, CHW and CTM increased with the increasing of fat% and sharply decreased with the increasing of meat% in the carcass.

Physicochemical Properties of Functional Herb Mixtures (기능성 천연물 복합제의 이화학적 특성 확인)

  • Lee, Myung-Hee;Jo, Deok-Jo;Yoon, Sung-Ran;Lee, Gee-Dong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.36 no.12
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    • pp.1571-1577
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    • 2007
  • The herb mixtures that are known to lower blood pressure were selected through oriental medical books and prescriptions and the physicochemical properties of their water extracts were analyzed to examine the possibility as functional food materials. The total yield of 28 water extracts was in the range of $5.33{\sim}36.71%$. Total phenolics and flavonoid content were $204.89{\sim}2543.29mg%\;and\;59.79{\sim}1430.55mg%$, respectively, and especially No. 2, 5, 9, 17, 18, 20, 22, and 26 showed high rates of above 800 mg%. Electron donating ability (EDA) was $7.81{\sim}98.18%$, and the samples that showed high values in EDA were similar to the samples with high values in total phenolics and flavonoid content. Phenolics and flavonoid compounds of the herbs are considered to perform a major role in antioxidation. Nitrite scavenging ability reached the highest at pH 1.2 ($11.70{\sim}96.47%$) and the lowest at pH 6.0 (below 12.77%), which indicates that nitrite scavenging ability decreases when pH increases.