• Title/Summary/Keyword: H-bonding

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The effects of consolidation time on the strength and failure behavior of freshwater ice rubble

  • Shayanfar, Hamid;Bailey, Eleanor;Pritchett, Robert;Taylor, Rocky
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.10 no.3
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    • pp.403-412
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    • 2018
  • Medium-scale tests were conducted to measure and observe the strength and failure behavior of freshwater ice rubble. A custom box measuring $3.05m{\times}0.94m{\times}0.94m$, with Plexiglas walls was built so that failure mechanisms could be observed. Ice rubble beams of nominal thickness 50 cm were produced by placing randomly sized ice pieces into the box filled with water at its freezing temperature. After the specified consolidation time, ranging between 0.2 and 70.5 h, the ice rubble beam was deformed by pushing a platen vertically downwards though the center of the beam until failure. For consolidation times less than 4 h, the ice beam failed progressively and tended to fail by shearing on macroscopic scale. At times greater than 4 h the beam failed by bending. The change in failure behaviour has been attributed to the degree of bonding between ice blocks.

The Study and characteristics of integrated CMOS sensor's packaging (집적화된 CMOS 센서의 팩키징 연구 및 특성 평가)

  • Roh, Ji-Hyoung;Kwon, Hyeok-Bin;Shin, Kyu-Sik;Cho, Nam-Kyu;Moon, Byung-Moo;Lee, Dae-Sung
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1551_1552
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    • 2009
  • In this paper, we presented the packaging technologies of CMOS ISFET(Ion Sensitive Field Effect Transistor) pH sensor using post-CMOS process and MCP(Multi Chip Packaging). We have proposed and developed two types of packaging technology. one is one chip, which sensing layer is deposited on the gate metal of standard CMOS ISFET, the other is two chip type, which sensing layer is separated from CMOS ISFET and connected by bonding wire. These proposed packaging technologies would make it easy to fabricate CMOS ISFET pH sensor and to make variety types of pH sensor.

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Structural and Molar Mass Characterization of Commercial Aliphatic Hyperbranched Polyesters

  • Zager, Ema;Huskic, Miroslav;Zigon, Majda
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.114-115
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    • 2006
  • We investigated the effects of annealing on the rearrangement of H-bonding structure and its influence on the thermal and rheological properties of $2^{nd}\;and\;4^{th}$ pseudo-generation aliphatic hyperbranched (HB) polyesters based on 2,2-bis(methylol)propionic acid. During annealing of amorphous HB polyesters, the structure becomes more ordered as a consequence of multiple H-bonds formation between linear sequences. Structure ordering is more pronounced for the lower pseudo-generation HB polyester with low molar mass, low degree of branching and incompletely reacted core hydroxyl groups which greatly increases the possibility for multiple H-bond interactions.

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Dihydrogen Phosphate Selective Anion Receptor Based on Acylhydrazone

  • Pandian, T. Senthil;Kang, Jongmin
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.2025-2028
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    • 2014
  • Anion receptor 1 based on acylhydrazone has been designed and synthesized. UV-vis and $^1H$ NMR titration showed that receptor 1 is selective receptor for dihydrogen phosphate ($H_2PO_4{^-}$). Dihydrogen phosphate was complexed by the receptor 1 via at least 4 hydrogen bonding interactions, contributing from two amide N-Hs and two imine C-Hs. In addition, nitrogen in the aromatic ring could make 2 additional hydrogen bondings with OH groups in the dihydrogen phosphate. However, the receptor 1 could make only 4 hydrogen bonds with halides. Therefore, receptor 1 could bind anions through hydrogen bonds with a selectivity in the order of $H_2PO_4{^-}$ > $Br^-$ > $Cl^-$ in highly polar solvent such as DMSO.

A Study of Azo-Hydrazone Tautomerism in 3-Phenyl-4-arylazo-5-isozaolones by $^H-NMR$ spectra of $^{15}N-labeled$ Compounds and HMO Method

  • Shawali, Ahmad S.;Salkaabi, harifia S.;Abdallah, Magda A.
    • Archives of Pharmacal Research
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    • v.14 no.3
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    • pp.237-241
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    • 1991
  • The tautomerism in 3-phenyl-4-arylazo-5-isoxazolones 1 was examined by $^1H-NMR$ spectra of $^15N-labeled$ compound and by HMO method. Both spectra data $(^1H-NMR\;and\;IR)$ and bonding energies are in support of the assignment of the hydrazone structure to such compounds. It is further shown that intermolecular and intramolecular hydrogen bondings favor the hydrazone tautomer.

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Ab initio and Vibrational Predissociation Studies on Methylammonium-(Water)4 Complex: Evidence for Multiple Cyclic and Non-cyclic Hydrogen-bonded Structures

  • Kim, Kwang-Yon;Han, Woon-Hui;Cho, Ung-In;Lee, Yuan T.;Boo, Doo-Wan
    • Bulletin of the Korean Chemical Society
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    • v.27 no.12
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    • pp.2028-2036
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    • 2006
  • The combined ab initio and vibrational predissociation (VP) spectroscopic studies on methylammonium-$(water)_4$ complex aimed at understanding the hydration behavior of an amphiphilic ion core are described. The ab initio calculations predicted eleven low-energy isomers forming cyclic, tripod, chain, and caged structures, and their relative stabilities, total hydration energies and thermodynamic functions at 298 K and 150 K. The excellent correlation between the observed VP spectra and ab initio spectra for bonded N-H, bonded O-H and free O-H stretches suggested co-existence of five cyclic isomers and two non-cyclic isomers in ion beam at 150 K, consistent with the trends of calculated Gibbs free energies.

Packaging Technology for Driving 400DPI LED Array (400DPI LED array 구동을 위한 패키지 기술)

  • Choi, S.H.;Moon, H.C.;Park, K.B.;Kim, I.H.
    • Proceedings of the KIEE Conference
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    • 2000.07d
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    • pp.3075-3077
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    • 2000
  • 이동통신단말기 등의 표시소자로 사용되는 LCD(Liquid Crystal Diode)나 LED(Light Emitting Diode)의 표현의 한계를 극복하고 보다 많은 정보를 표시할 수 있는 가상의 화면을 구성하기 위한 400dpi급 LED array 칩과 이를 구동하기 위한 driver 칩을 패키징하는 방법에 대하여 연구하였다. 연성 인쇄회로기판(flexible Printed Circuit) 기판 위에 칩을 실장하여 제품의 소형화와 경량화 그리고 전선을 대체하여 신뢰성을 높일 수 있도록 설계하였고 알루미늄 wire bonding법으로 각각의 칩을 연결하는데 있어 고려해야할 패키지의 조건에 대하여 연구하였다. 본 연구의 목적은 휴대용 이동통신단말기의 경박단 소화를 위한 패키징 기술을 확보하는데 있다.

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Preparation of $Al_2O_3$.$2SiO_2$ glass by the sol-gel process (졸-겔법에 의한 $Al_2O_3$.$2SiO_2$ 유리의 제조)

  • Rhee, Jhun;Chi, Ung-Up;Jo, Dong-Soo
    • Journal of the Korean Ceramic Society
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    • v.20 no.1
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    • pp.3-12
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    • 1983
  • In the present study an attempt was made to synthesize the $Al_2O_3$.$2SiO_2$ glass in which atomic ratio is Al:Si=1:1 by sol-gel process. And at such a low temperature as 55$0^{\circ}C$ clear amorphous gel derived glass with Si-O-Al bonding was obtained. $Si(OC_2H_5)_4$ and $Al(NO_3)_3$.$9H_2O$ were used as the precursor and among the mutual solvents only n-butanol gave good results for the synthesis of the gel derived glass. Partial hydrolysis of TEOS with one-fold mol of $H_2O$ prior to the reaction with aluminum nitrate gave the better results., Total oxide content to the total reactants by weight was affective to the results.

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Development of an Intelligent Supervisory Programmable Controller for Automatic Assembly Machine (자동 조립 장치를 위한 지능 관리 제어기 개발에 관한 연구)

  • Jeon, C.H.;Lee, T.H.;Suh, I.H.;Huh, K.M.;Bien, Z.
    • Proceedings of the KIEE Conference
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    • 1987.07a
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    • pp.279-283
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    • 1987
  • In this paper an intelligent supervisory programmable controller for automatic assembly machine is developed. This is achieved by adding sequence control hardware with input-interrupts to supervisory real time language and also by incorporating an automatic planning method which uses a predicate logic model and an action model. The designed intelligent supervisory programmable controller is applied to Die Bonding Machine and is to found to work well.

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Wear Characteristics of Coated $Si_3N_4$-TiC Ceramic Tool (Coated $Si_3N_4$-TiC Ceramic 공구의 마모 특성)

  • 김동원;권오관;이준근;천성순
    • Tribology and Lubricants
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    • v.4 no.2
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    • pp.44-51
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    • 1988
  • Titanium carbide(TiC), Titanium nitride(TiN), and Titanium carbonnitride(Ti(C,N)) films were deposited on $Si_3N_4$-TiC composite cutting tools by chemical vapor deposition(CVD) using $TiCl_4-CH_4-H_2$, $TiCl_4-N_2-H_2$, and $TiCl_4-CH_4-N_2-H_2$ gas mixtures, respectively. The experimental results indicate that TiC coatings compared with TiN coatings on $Si_3N_4$ -TiC ceramic have an improved microstructural property, good thermal shock resistance, and good interfacial bonding. However TiN coatings compared with TiC coatings have a low friction coefficient with steel and good chemical stability. It is found by cutting test that coated insert compared with $Si_3N_4$-TiC ceramic have a superior flank and crater wear resistance. And multilayer coating compared with monolayer coating shows a improved wear resistance.