• Computers and Concrete
• /
• v.26 no.2
• /
• pp.115-125
• /
• 2020

To reduce the damage of concrete in fire, a new type of lightweight cinder aggregate concrete was developed due to the excellent fire resistance of cinder. To further enhance its fire resistance, Polypropylene (PP) Fibers which can enhance the fire resistance of concrete were also used in this type of concrete. However, the bond behavior of this new type of concrete after fire exposure is still unknown. To investigate its bond behavior, 185 specimens were heated up to 22, 200, 400, 600 or 800℃ for 2 h duration respectively, which is followed by subsequent compressive and tensile tests at room temperature. The concrete-rebar bond strength of C30 PP fiber-reinforced cinder concrete was subsequently investigated through pull-out tests after fire exposure. The microstructures of the PP fiber-reinforced cinder concrete and the status of the PP fibre at different temperature were inspected using an advanced scanning electron microscopy, aiming to understand the mechanism of the bonding deterioration under high temperature. The effects of rebar diameter and bond length on the bond strength of PP fiber-reinforced cinder concrete were investigated based on the test results. The bond-slip relation of PP fiber-reinforced cinder concrete after exposure at different temperature was derived based on the test results.

• Restorative Dentistry and Endodontics
• /
• v.32 no.1
• /
• pp.9-18
• /
• 2007

The purposes of this study were to examine the variability of adhesive thickness on the different site of the cavity wall when used total-etch system without filler and simplified self-etch system with filler and to evaluate the relationship between variable adhesive thickness and microtensile bond strength to the cavity wall. A class I cavity in six human molars was prepared to expose all dentinal walls. Three teeth were bonded with a filled adhesive, $Clearfil^{TM}$ SE bond ana the other three teeth were bonded with unfilled adhesives, $Scotchbond^{TM}$ Multi Purpose. Morphology and thickness of adhesive layer were examined using fluorescence microscope. Bonding agent thickness was measured at three points along the axial cavity wall edge of cavity margin (rim). halfway down each cavity wall (h1f), internal angle of the cavity (ang). After reproducing the adhesive thickness at rim, h1f and ang, micro-tensile bond strength were evaluated. For both bonding agents, adhesive thickness of ang was significantly thicker than that of rim and h1f (P <0.05). As reproduced the adhesive thickness, microtensile bond strength was increased as adhesive thickness was increased in two bonding agents. Adhesive thickness of internal angle of the cavity was significantly thicker than that of the cavity margin and the halfway cavity wall for both bonding agents. Microtensile bond strength of the thick adhesive layer at the internal angle of the cavity was higher than that of the thin adhesive layer at 1,he cavity margin and the halfway cavity in the two bonding systems.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.04a
• /
• pp.1089-1092
• /
• 2008

The bond behavior between concrete and reinforcement is a important requirement for reinforced concrete constructions. For practical application, it is very important to study bond behavior of reinforcing bars in recycled fine aggregate concrete. Therefore, pull-out test in order to investigate the bond behavior between recycled fine aggregate concrete and deformed bars was performed. Recycled fine aggregate concrete replacement ratios (i.e., 0% and 100%) and positions of deformed bars (i.e., vertical and horizontal position) were considered as variables in this study. Test results were compared with the bond strength requirement recommended by CEB-FIP code. Based on the test results, It was found that the bond strength between the recycled fine aggregate concrete and deformed bars were influenced by both recycled fine aggregate concrete replacement ratios and positions of deformed bars. The reduction of bonded area at the soffit of horizontal reinforcement caused by concrete bleeding was observed in H type specimen. So, Only V type and HB specimen satisfied the bond strength requirement recommended by CEB-FIP code.

• Bulletin of the Korean Chemical Society
• /
• v.13 no.6
• /
• pp.627-631
• /
• 1992

The dihydrido iridium(Ⅲ) complex [$Ir(PPh_3)_2H_2(ac)_2$]$BF_4$ (ac=acetone) reacts with 2-phenylpyridine and 7,8-benzoquinoline to yield the C-H activated complexes [$Ir(PPh_3)_2$H(ac)(L)]$BF_4$ (L= phenylpyridine; 7,8-benzoquioline). The dihydrido iridium(Ⅲ) complex [$Ir(PPh_3)_2H_2(ac)_2$]$BF_4$ also reacts with triaklysilane via an oxidative addition reaction to yield the trihydrido iridium complexes [$Ir(PPh_3)_2H_3SiR_3$]$BF_4$ (R =Et and Ph). The structual configuration was studied by conventional spectroscopy.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.12
• /
• pp.3641-3648
• /
• 2013

Energy transfer and bond dissociation of $C-H_{methyl}$ and $C-H_{ring}$ in excited toluene in the collision with $H_2$ and $D_2$ have been studied by use of classical trajectory procedures at 300 K. Energy lost by the vibrationally excited toluene to the ground-state $H_2/D_2$ is not large, but the amount increases with increasing vibrational excitation from 5000 and $40,000cm^{-1}$. The principal energy transfer pathway is vibration to translation (V-T) in both systems. The vibration to vibration (V-V) step is important in toluene + $D_2$, but plays a minor role in toluene + $H_2$. When the incident molecule is also vibrationally excited, toluene loses energy to $D_2$, whereas it gains energy from $H_2$ instead. The overall extent of energy loss is greater in toluene + $D_2$ than that in toluene + $H_2$. The different efficiency of the energy transfer pathways in two collisions is mainly due to the near-resonant condition between $D_2$ and C-H vibrations. Collision-induced dissociation of $C-H_{methyl}$ and $C-H_{ring}$ bonds occurs when highly excited toluene ($55,000-70,400cm^{-1}$) interacts with the ground-state $H_2/D_2$. Dissociation probabilities are low ($10^{-5}{\sim}10^{-2}$) but increase exponentially with rising vibrational excitation. Intramolecular energy flow between the excited C-H bonds occurring on a subpicosecond timescale is responsible for the bond dissociation.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.6
• /
• pp.1823-1824
• /
• 2012

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• v.y2005m4
• /
• pp.106-111
• /
• 2005

Failure mechanisms were investigated for the two layer thermal barrier coatings consisting of NiCrAlY bond coat and $ZrO_2-8wt.\% Y_{2}O_3$ ceramic coating during cyclic oxidation. $Al_{2}O_3$ developed at the ceramic coating/bond coat interface first, followed by the Cr/Ni rich oxides such as $NiCr_{2}O_4 and Ni(Al,Cr)_{2}O_4$ during cyclic oxidation It was observed that the spalling of ceramic coatings took place primarily within the NiCrAlY bond coat oxidation products or at the interface between the bond coat oxidation products and zirconia based ceramic coating or the bond coat. It was also observed that the fracture within these oxidation products occurred with the formation of $Ni(Cr,Al)_{2}O_4$ spinel or Cr/Ni rich oxides. It was therefore concluded that the formation of these oxides was a life-limiting event for the thermal barrier coatings.

• Structural Engineering and Mechanics
• /
• v.5 no.5
• /
• pp.663-677
• /
• 1997

Bond-slip behavior between reinforcement and concrete under push-pull cyclic loadings is numerically investigated based on a reinforcement model proposed in this paper. The equivalent reinforcing steel model considering the bond-slip effect without taking double nodes is derived through the equilibrium at each node of steel and the compatibility condition between steel and concrete. Besides a specific transformation algorithm is composed to transfer the forces and displacements from the nodes of the steel element to the nodes of the concrete element. This model first results in an effective use in the case of complex steel arrangements where the steel elements cross the sides of the concrete elements and second turns the impossibility into a possibility in consideration of the bond-slip effect in three dimensional finite element analysis. Finally, the correlation studies between numerical and experimental results under the continuously repeated large deformation stages demonstrate the validity of developed reinforcing steel model and adopted algorithms.

• The Korean Journal of Ceramics
• /
• v.4 no.4
• /
• pp.340-344
• /
• 1998

Failure mechanisms were investigated for the two layer thermal barrier coatings consisting of NiCrAlY bond coat and $ZrO_2$-8wt.% $Y_2O_3$ ceramic coating during cyclic oxidation. $Al_2O_3$ developed at the ceramic coating/bond coat interface first, followed by the Cr/Ni rich oxides such as $NiCr_2O_4$ and $Ni(Al, Cr)_2O_4$ during cyclic oxidation. It was observed that the spalling of ceramic coatings took place primarily within the NiCrAlY bond coat oxidation products or at the interface between the bond coat oxidation products and zirconia based ceramic coating or the bond coat. It was also observed that the fracture within these oxidation products occurred with the formation of $Ni(Cr, Al)_2O_4$ spinel or Cr/Ni rich oxides. It was therefore concluded that the formation of these oxides was a life-limiting event for the thermal barrier coatings.

• Journal of the Korean Chemical Society
• /
• v.46 no.3
• /
• pp.179-186
• /
• 2002

A molecular orbital analysis based on the extended Huckel calculations has been carried out to study the OH bond activation of water on the $TiO_2$(110) surface. $H_2O$ binds with its axis perpendicular to the surfac on top of the five-coordinate $Ti^{4+}$ atom via its $3a_1$ orbital. In this bonding situation, the two-coordinated bridging $O^{2-}$ atom ($O_b$, basic site) on $TiO_2$(110) is too distant from an H atom of water to form hydrogen-bondig interactions with water that facilitate O-H bond cleavage. It has been elucidated that the O-H bond is appreciably weakened when the water molecule is tilted to give a hydrogen bond with the $O_b$ atom. This mechanism includes mutual transfer of electron density from the $3a_1$ orbital of the water molecule to the $Ti^{4+} 3d_{z2}$ orbital and from the $O_b$ P orbitals to the $2b_1$ of the adsorbed water molecule This should result in lengthening of the O-H bond in the surface complex and the subsequent dissociation into the fragments OH and H.