• 제목/요약/키워드: H-베타

검색결과 139건 처리시간 0.063초

NMR Spectroscopy and Mass Spectrometry of Benzyl Alcohol Galactoside synthesized using β-Galactosidase (베타-갈락토시데이즈를 이용하여 합성된 Benzyl Alcohol Galactoside의 NMR Spectroscopy 및 Mass spectrometry)

  • Lee, Hyang-Yeol;Jung, Kyung-Hwan
    • Journal of the Korean Applied Science and Technology
    • /
    • 제36권1호
    • /
    • pp.84-89
    • /
    • 2019
  • To characterize the molecular structure of BzO-gal synthesized using Escherichia coli ${\beta}$-gal, NMR ($^1H$- and $^{13}C$-) spectroscopy and mass spectrometry of BzO-gal were conducted. $^1H$ NMR spectrum of BzO-gal showed multiple peaks corresponding to the galactosyl group, which is an evidence of galactosylation on BzOH. Five proton peaks around the aromatic region at ${\delta}_H$ 7.43 ~ 7.24 ppm and 2 peaks from ${\delta}_H$ 4.93 and 4.67 ppm were evidence of the presence of the benzyl group. Seven proton peaks at ${\delta}_H$ 4.32 ~ 3.46 ppm showed the presence of a monosaccharide and were indicative of galactosylation on BzOH. $^{13}C$ NMR spectrum also revealed the presence of 11 carbons suggestive of BzO-gal. The mass value (sodium adduct ion of BzO-gal, m/z = 293.0994) from mass spectrometry analysis of BzO-gal, and $^1H$ and $^{13}C$ NMR spectral data were in good agreement with the expecting structure of BzO-gal. We are expecting that through future study it will eventually be able to develop a new additive of low cytotoxicity.

NUMERICAL ANALYSIS TO DESIGN HIGH TEMPERATURE HEAT EXCHANGER OF BETA TYPE STIRLING ENGINE IN 3-D COMBUSTION FIELD (3차원 연소장에서의 베타 형태의 스털링엔진 고온 열교환기 설계를 위한 수치해석 연구)

  • Kang, S.H.;Kim, H.J.;Chung, D.H.
    • Journal of computational fluids engineering
    • /
    • 제16권2호
    • /
    • pp.56-61
    • /
    • 2011
  • Numerical study is conducted to design the high temperature heat exchanger of Stirling engine by using the commercial CFD solver, FLUENT. The Fin-tube type of heat exchanger is designed as a reference model by considering the type of engine which is ${\beta}$-configuration. To find the optimal design of heat exchanger in heat transfer capacity numerical calculation is conducted by changing the shape, the number, and material of reference model in three-dimensional combustion field. Adjusted one-way constant velocity of working fluid that is helium is considered as the representative velocity of oscillating flow. The optimal design of heat exchanger considering the heat transfer capability is suggested by using the calculation results.

FPGA Design of Turbo Code based on MAP (MAP 기반 터보코드의 FPGA 설계)

  • Seo, Young-Ho
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • 제32권3C호
    • /
    • pp.306-313
    • /
    • 2007
  • In this paper, we efficiently implemented turbo code algorithm in FPGA H/W(hardware) resource. The used turbo code algorithm has the characteristics; the size of constraint is 3, encoder type is 1/3, the size of random interleaver is 2048. The proposed H/W consists of MAP block for calculating alpha and delta using delta value, storing buffer for each value, multiplier for calculating lamda, and lamda buffer. The proposed algorithm and H/W architecture was verified by C++ language and was designed by VHDL. Finally the designed H/W was programmed into FPGA and tested in wireless communication environment for field availability. The target FPGA of the implemented H/W is VERTEX4 XC4VFX12-12-SF363 and it is stably operated in 131.533MHz clock frequency (7.603ns).

Preparation of an Inorganic Scintillator Loaded Film for the Measurement of Surface Contamination and its Performance Test (표면오염 측정용 무기섬광 함침 필름의 제조 및 성능 평가)

  • 서범경;이근우;임난주;박진호;한명진
    • Journal of Energy Engineering
    • /
    • 제13권2호
    • /
    • pp.93-100
    • /
    • 2004
  • The smear media possible to sampling and radiation detection was prepared and evaluated for the surface contamination using indirect method. The films were made by impregnating Cerium Activated Yttrium Silicate (CAYS) in a polysulfone membrane. The membranes used solution as a dimethylformamide (DMF) and methylene chloride (MC), polysulfone as a polymer matrix and CAYS as a inorganic scintillator. The proximity membranes were prepared with single- and double-layered structure. The solidified methods were immersion to the nonsolvent bath such at water and ethanol and solvent evaporation. The measurement of the photon produced by interaction with radiation and inorganic scintillator used a photomultiflier tube (PMT), amplifier, and counter. In the comparison with the low background alpha/beta counter, the counter rate using inorganic scintillator proximity membrane for the $\^$14/C surface contamination was about 50%. Also. the $^3$H counting results revealed that the prepared membranes were efficient to monitor the surface contaminated with the low energy be-ray emitter nuclides.

Is the technology in renewable energy converging among countries? : Using the patent data of OECD (재생에너지 분야 국가 간 기술 확산 및 수렴 : OECD 특허 데이터를 이용한 분석)

  • Oh, Keunyeob;Yoo, Jinman
    • Environmental and Resource Economics Review
    • /
    • 제23권1호
    • /
    • pp.67-89
    • /
    • 2014
  • This paper uses patent data of OECD countries in order to investigate if there is converging tendency in renewable energy area. We used the concepts of sigma convergence and beta convergence to measure the convergence. GINI coefficient, HH index are also borrowed from other area of economics. The results show that technology level does not seem to have been converging in this area. Even though the number of patent in relatively less advanced countries has been increased a lot, we could find no evidence that there is the tendency that the gap among the countries have been narrowed. This is quite different from the results of IT industry or other industry since we could find the converging tendency in the data of those industries. Instead, it seems that there is the convergence club among most advance countries in renewable energy area.

Quality Control of Radiation Counting Systems and Measurement of Minimum Delectable Activity (방사선 계측기의 품질관리 및 최소검출방사능 측정)

  • 송병철;한성심;김영복;지광용;손세철
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 한국방사성폐기물학회 2004년도 학술논문집
    • /
    • pp.419-424
    • /
    • 2004
  • Various radiation counters have been using to determine radioactivity of radwastes for disposal. A radiation counting system was set up using a radiation detector chosen in this study and its stability was investigated through the periodic determination of background and counting efficiencies in accordance with a quality control program to increase the confidence level. The average background level for the $\gamma$-spectrometer was 1.59 cps and the average counting level for the standard sample was 45248 Ops within $2{\sigma}$ confidence levels. The average alpha background level for the low background ${\alpha}{\beta}$ counting system was 0.31 cpm and the efficiency for alpha counting was 34.38%. The average beta background level for the ${\alpha}{\beta}$ counting system was 1,30 cpm and the efficiency for beta counting was 46.5%, The background level in the region of 3H and 14C for the liquid scintillation counting system was 2.52 and 3.31 cpm and the efficiency for alpha counting was 58.5 and 95.6%, respectively. The minimum detectable activity for the$\gamma$-spectrometer was found to be 3.2 Bq/$m\ell$ and 3.8 Bq/$m\ell$ for the liquid scintillation counter, and 20.5 and 23.0 Bq/$m\ell$, respectively for the $\alpha$ and $\beta$ counting system.

  • PDF

Conformational Analyses for Hydrated Oligopeptides by Quantum Chemical Calculation (양자화학적 계산에 의한 올리고펩티드 수화물의 구조분석)

  • Sim, Jae-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • 제19권7호
    • /
    • pp.95-104
    • /
    • 2018
  • The structures and energies of the anhydrate and hydrate (hydrate rate: h of 1) states of L-alanine (LA) and glycine (G) were calculated by quantum chemical calculations (QCCs) using B3LYP/6-31G(d,p) for four types of conformers (${\beta}$-extended: ${\Phi}/{\Psi}=t-/t+$, $PP_{II}$: g-/t+, $PP_{II}$-like: g-/g+, and ${\alpha}$-helix: g-/g-). In LA and G, which have an imino proton (NH), three conformation types of ${\beta}$-extended, $PP_{II}$-like, and ${\alpha}$-helix were obtained, and water molecules were inserted mainly between the intra-molecular hydrogen bond of $CO{\cdots}HN$ in $PP_{II}$-like and ${\alpha}$-helix, and attached to the CO group in ${\beta}$-extended. In LA and G, $PP_{II}$-like conformers were most stable in the anhydrate and hydrate states, and the result for LA was different from some experimental and theoretical results from other studies reporting that the main stable conformation of alanine oligopeptide was $PP_{II}$. The formation pattern and stability of the conformation of the oligopeptide was strongly dominated by the presence/absence of intra-molecular hydrogen bonding of $CO{\cdots}HN$, or the presence/absence of an $NH_2$ group in the starting amino acid.

Culture characteristics and genetic relationship of morel mushroom (Morchella spp.) isolates from Korea and other countries (곰보버섯 (Morchella spp.) 수집균주의 배양적특성 및 유전적 유연관계)

  • Min, Gyeong-Jin;Park, Hye-sung;Lee, Eun-ji;Lee, Chan-Jung
    • Journal of Mushroom
    • /
    • 제18권1호
    • /
    • pp.100-106
    • /
    • 2020
  • Eight morel mushroom species were collected from Korea and other countries. The culture characteristics, genetic relationships, and beta-glucan content of the strains were analyzed. The mycelia of Morchella species exhibited optimal growth when cultured in dark at 25 ℃ in media with pH 7. The mycelia had a distinctive mycelial scent and characteristically changed color, being white initially, and then turning dark yellow to dark brown as it grew. The mycelia were classified into five types based on morphology. The isolates were identified as Morchella conica, two M. sextelata, M. importuna, M. esculenta, and three M. crassipes, based on ITS-rDNA sequences. PCR polymorphisms were variably produced within Morchella spp. using Universal Fungal Fingerprinting Primers (UFPF) and classified into four groups at the intra and inter species level. The strains, KMCC04971 and KMCC04407, showed the same banding pattern as M. conica and M. sextelata, respectively; however, these results were different from those of ITS analysis. Glucan content analysis by strain showed that the KMCC 04973 strain of M. importuna had the highest alpha- and beta-glucan content, at 16.4 g and 33.1 g per 100 g, respectively.

Complexation of Piroxicam and Tenoxicam with $Hydroxypropyl-{\beta}-cyclodextrin$ (히드록시프로필-베타-시클로덱스트린과 피록시캄 및 테녹시캄 간의 복합체 형성)

  • Kim, Ju-Hyun;Choi, Hoo-Kyun
    • Journal of Pharmaceutical Investigation
    • /
    • 제30권1호
    • /
    • pp.33-37
    • /
    • 2000
  • One of the methods to increase the solubility of a drug is to use complexation with a cyclodextrin. Due to the hydrophobic nature of the interior cavity of the cyclodextrin, it has been known that undissociated lipophilic drugs can be included within the cyclodextrin by hydrophobic interaction. Recently, inclusion of hydrophilic or dissociated form of a drug has been investigated. In this study, the synergism of pH and complexation with $hydroxypropy-{\beta}-cyclodextrin\;(HP\;{\beta}\;CD)$ to increase the solubility of two oxicam derivatives was investigated. In addition, the effect of partition coefficient of dissociated and undissociated form of the drug on the extent of complexation with HP ${\beta}$ CD was studied. The solubility was measured by equilibrium solubility method. The solubility of tenoxicam and piroxicam increased exponentially with an increase in solution pH above the pKa of the drug in the presence and absence of HP ${\beta}$ CD. The solubility of the drugs increased linearly as a function of HP ${\beta}CD$ concentration at fixed pH. Although the stability constant of ionized species is less than that of the unionized species, the concentration of the ionized drug complex is greater than that of the unionized drug complex due to higher concentration of ionized species at pH 7.3.

  • PDF

Production Conditions and Characterization of ${\beta}$-Lactamase Inhibitor from Pseudomonas sp. X-8 (슈도모나스 sp. X-8의 베타락타마제 억제제의 생산 조건과 특성)

  • Kim, Kyoung-Ja;Kim, Tae-Sung
    • YAKHAK HOEJI
    • /
    • 제41권5호
    • /
    • pp.658-665
    • /
    • 1997
  • Identification of a soil microorganism strain X-8, producer of ${\beta}$-lactamase inhibitor, based on its morphological, physiological, biochemical and chemotaxonomical characteristics was performed. The strain X-8 was identified as Pseudomonas sp. The beta-lactamase inhibitor produced by this strain was highly achieved in fermentation medium contained glucose 0.5%, urea 0.25%, $K_2HPO_4{\cdot}3H_2O\;0.5%,\;MgSO_4{\cdot}7H_2O\;0.5%,\;FeSO_4{\cdot}7H_2O\;0.01%,\;CuSO_4,\;ZnSO_4,\;MnSO_4\;0.02%$. The beta-lactamase inhibitor was not extracted by organic solvent such as n-butanol and ethyl acetate but remained in aqueous layer. The n-butanol extract showed antimicrobial activity against M. smegmatis. The ${\beta}$-lactamase inhibitor was stable at pH 7.0~8.0 and 4$^{\circ}C$ for 24h. The ${\beta}$-lactamase inhibitor was bound on ion exchanger Diaion WA-30 and HP-20 and eluted with 2N-$NH_4OH$ and acetone, respectively.

  • PDF