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Performance of carbon nanotube-coated steel slag for high concentrations of phosphorus from pig manure

  • Kang, Kyeong Hwan;Kim, Junghyeon;Jeon, Hyeonjin;Kim, Kyoungwoo;Byun, Imgyu
    • Membrane and Water Treatment
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    • v.11 no.1
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    • pp.59-68
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    • 2020
  • The study objective was to evaluate the enhanced removal of high concentrations of phosphorus from synthetic wastewater (solely phosphorus-containing) and real wastewater (pig manure) by using carbon nanotube (CNT)-coated steel slag. Generally, phosphorus removal by steel slag is attributed to Ca2+ eluted from the slag. However, in this study, CNT was used to control the excess release of Ca2+ from steel slag and increase the phosphorus removal. The phosphorus removal rate by the uncoated steel slag was lower than that of the CNT-coated steel slag, even though the Ca2+ concentrations were higher in the solution containing the uncoated steel slag. Therefore, the phosphorus removal could be attributed to both precipitation with Ca2+ eluted from steel slag in aqueous solution and adsorption onto the surface of the CNT-coated steel slag. Furthermore, the protons released from the CNT surface by exchanging with divalent cations acted to reduce the pH increase of the solution, which is attributed to the OH- eluted from the steel slag. The adsorption isotherm and kinetics of the CNT-coated steel slags followed the Freundlich isotherm and pseudo-second-order model, respectively. The maximum adsorption capacity of the uncoated and CNT-coated steel slags was 6.127 and 9.268 mg P g-1 slag, respectively. In addition, phosphorus from pig manure was more effectively removed by the CNT-coated steel slag than by the uncoated slag. Over 24 hours, the PO4-P removal in pig manure was 12.3% higher by the CNT-coated slag. This CNT-coated steel slag can be used to remove both phosphorus and metals and has potential applications in high phosphorus-containing wastewater like pig manure.

A Study on DeNOx Characteristics of Corona/Catalyst Hybrid System (코로나/촉매 일체형 시스템의 탈질특성에 관한 연구)

  • Chang, Hong-Ki;Choi, Chang-Sik;Shin, Jung-Uk;Ji, Young-Yeon;Hong, Min-Sun;Chung, Yoon-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.6
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    • pp.699-707
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    • 2007
  • This study was carried out to investigate the reaction characteristics of corona/catalyst hybrid $DeNO_x$ process. The experiments were performed by using the multi-staged pin-to-hole type corona reactor which is enable to control the pin-to-hole gap and to insert the catalyst. Also, used for this study, were catalysts which commercially used Pt, Pd and $TiO_2$, and oxygen and hydrocarbon ($C_2H_4$) as reagents. In the syn-gas test, at high temperatures in the range of $100{\sim}200^{\circ}C$, the corona-only $DeNO_x$ process did not reduce the $NO_x$ concentration effectively. However in the presence of ethylene and oxygen as reagents, the $NO_x$ removal efficiency was better at these high temperatures than corona-only $DeNO_x$ process. In addition, coronal catalyst hybrid process with $TiO_2$ showed more efficiency of $NO_x$ removal than Pt and Pd catalyst, because the $TiO_2$ catalyst was more active than Pt and Pd catalyst to converse the $NO_2$ to $HNO_3$. Furthermore, at the condition of real diesel exhaust gas, the $DeNO_x$ efficiency of corona/catalyst hybrid process was not good at higher reaction temperature and plasma density.

A Study on the Comparative Analysis and Improvement of Indoor Environmental Factor in Green Building Rating Systems (국내외 친환경건축물 인증제도 실내 환경 관련 부문 비교분석 및 개선안 연구)

  • Joh Hahn
    • Korean Institute of Interior Design Journal
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    • v.15 no.4 s.57
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    • pp.21-28
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    • 2006
  • To promote environmentally responsible architectural practice, many nations have established their own green building rating system. Among other criteria, recently the indoor environmental quality section has been paid great attention due to Sick Building Syndrome, as this believed to caused by polluted indoor environment. In this context, indoor environmental quality is one of very important sections of each green building rating system and closely related to the very happiness of building users. The goal of this research is to compare and analyze the indoor environmental sections of three green building rating systems, GBCC, LEED v2.1, and BREEAM Office 2005, and find a direction for the improvement of GBCC. First, the three rating systems are analyzed in general to compare the importance of indoor environmental factors in each system. Second, the indoor environmental factors are reclassified within related sub-categories for the comparable analysis. Finally, based upon the comparable analysis, directions for the improvement of GBCC are as follows: 1. GBCC's h4r Environment Section needs to clarify its VOCs criteria based upon types of finish materials. 2. Sound Environment Section's noise control criteria needs to be revised based upon types of building usages and application method. 3. An indoor lighting related section needs to be included in GBCC, as even though light is the one of the most important factors in indoor environment, it has not been included in GBCC yet. 4. The sub-section of Confortable Indoor Environment Section related to the resting space and the universal accessibility are not in accord with the goal of green building rating system. These items need to be dealt within general building codes. 5. The rating evaluation structure and process need to be streamlined.

An Organic Electrophosphorescent Device Driven by All-Organic Thin-Film Transistor using Polymeric Gate Insulator

  • Pyo, S.W.;Shim, J.H.;Kim, Y.K.
    • Journal of Information Display
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    • v.4 no.2
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    • pp.1-6
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    • 2003
  • In this paper, we demonstrate that the organic electrophosphorescent device is driven by the organic thin film transistor with spin-coated photoacryl gate insulator. It was found that electrical output characteristics in our organic thin film transistors using the staggered-inverted top-contact structure showed the non-saturated slope in the saturation region and the sub-threshold nonlinearity in the triode region, where we obtained the maximum power luminance that was about 90 $cd/m^2$. Field effect mobility, threshold voltage, and on-off current ratio in 0.45 ${\mu}m$ thick gate dielectric layer were 0.17 $cm^2/Vs$, -7 V, and $10^6$ , respectively. In order to form polyimide as a gate insulator, vapor deposition polymerization process was also introduced instead of spin-coating process, where polyimide film was co-deposited by high-vacuum thermal evaporation from 4,4'-oxydiphthalic anhydride (ODPA) and 4,4'-oxydianiline (ODA) and cured at 150${\sqsubset}$for 1hr. It was also found that field effect mobility, threshold voltage, on-off current ratio, and sub-threshold slope with 0.45 ${\mu}m$ thick gate dielectric films were 0.134 $cm^2/Vs$, -7 V, and $10^6$ A/A, and 1 V/decade, respectively.

Thermal-hydraulic analysis of a new conceptual heat pipe cooled small nuclear reactor system

  • Wang, Chenglong;Sun, Hao;Tang, Simiao;Tian, Wenxi;Qiu, Suizheng;Su, Guanghui
    • Nuclear Engineering and Technology
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    • v.52 no.1
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    • pp.19-26
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    • 2020
  • Small nuclear reactor features higher power capacity, longer operation life than conventional power sources. It could be an ideal alternative of existing power source applied for special equipment for terrestrial or underwater missions. In this paper, a 25kWe heat pipe cooled reactor power source applied for multiple use is preliminary designed. Based on the design, a thermal-hydraulic analysis code for heat pipe cooled reactor is developed to analyze steady and transient performance of the designed nuclear reactor. For reactor design, UN fuel with 65% enrichment and potassium heat pipes are adopted in the reactor core. Tungsten and LiH are adopted as radiation shield on both sides of the reactor core. The reactor is controlled by 6 control drums with B4C neutron absorbers. Thermoelectric generator (TEG) converts fission heat into electricity. Cooling water removes waste heat out of the reactor. The thermal-hydraulic characteristics of heat pipes are simulated using thermal resistance network method. Thermal parameters of steady and transient conditions, such as the temperature distribution of every key components are obtained. Then the postulated reactor accidents for heat pipe cooled reactor, including power variation, single heat pipe failure and cooling channel blockage, are analyzed and evaluated. Results show that all the designed parameters satisfy the safety requirements. This work could provide reference to the design and application of the heat pipe cooled nuclear power source.

Characterization of Cooked Meat Models using Grasshopper (Sphenarium purpurascens) Soluble Protein Extracted by Alkalisation and Ultrasound as Meat-Extender

  • Cruz-Lopez, Salvador Osvaldo;Escalona-Buendia, Hector Bernardo;Roman-Guerrero, Angelica;Dominguez-Soberanes, Julieta;Alvarez-Cisneros, Yenizey Merit
    • Food Science of Animal Resources
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    • v.42 no.3
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    • pp.536-555
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    • 2022
  • The most abundant Orthoptera in Mexico is a small grasshopper (Sphenarium purpurascens) which is considered a food source with increased nutritional value due to its high protein content. Insect proteins have gained relevance because of their high potential as gelling, texturing, and extender agents in the food industry. The objective of this study was to evaluate the effect of substituting meat with a soluble protein extract from grasshopper obtained by alkalisation or alkalisation-piezoelectric ultrasound, on the techno-functional, physicochemical, and sensory characteristics of cooked meat models (sausages). The soluble protein was extracted in NaHCO3 pH 8 and a piezoelectric ultrasound 5-mm sonotrode at 20 kHz with 99% amplitude. Different formulations with meat substitution: 0%, 5%, 10%, and 15% were prepared and characterised for their rheological behaviour, emulsion stability, weight loss by cooking, total protein content, colour, and texture. Sensory evaluation was conducted with consumers using a test involving check-all-that-apply and overall liking. The alkalisation-piezoelectric ultrasound method improved the solubility and the techno-functional properties of the soluble grasshopper protein when applied in sausages at maximum levels of 10% meat substitution. The sensory evaluation indicated that the formulation with 5% meat substitution exhibited the same acceptability as the control sample. Given these results, the soluble protein treated with alkalisation and piezoelectric ultrasound could be used as an extender in meat products.

Carbon monoxide releasing molecule-2 suppresses stretchactivated atrial natriuretic peptide secretion by activating largeconductance calcium-activated potassium channels

  • Li, Weijian;Lee, Sun Hwa;Kim, Suhn Hee
    • The Korean Journal of Physiology and Pharmacology
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    • v.26 no.2
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    • pp.125-133
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    • 2022
  • Carbon monoxide (CO) is a known gaseous bioactive substance found across a wide array of body systems. The administration of low concentrations of CO has been found to exert an anti-inflammatory, anti-apoptotic, anti-hypertensive, and vaso-dilatory effect. To date, however, it has remained unknown whether CO influences atrial natriuretic peptide (ANP) secretion. This study explores the effect of CO on ANP secretion and its associated signaling pathway using isolated beating rat atria. Atrial perfusate was collected for 10 min for use as a control, after which high atrial stretch was induced by increasing the height of the outflow catheter. Carbon monoxide releasing molecule-2 (CORM-2; 10, 50, 100 μM) and hemin (HO-1 inducer; 0.1, 1, 50 μM), but not CORM-3 (10, 50, 100 μM), decreased high stretch-induced ANP secretion. However, zinc porphyrin (HO-1 inhibitor) did not affect ANP secretion. The order of potency for the suppression of ANP secretion was found to be hemin > CORM-2 >> CORM-3. The suppression of ANP secretion by CORM-2 was attenuated by pretreatment with 5-hydroxydecanoic acid, paxilline, and 1H-[1,2,4] oxadiazolo [4,3-a] quinoxalin-1-one, but not by diltiazem, wortmannin, LY-294002, or NG-nitro-L-arginine methyl ester. Hypoxic conditions attenuated the suppressive effect of CORM-2 on ANP secretion. In sum, these results suggest that CORM-2 suppresses ANP secretion via mitochondrial KATP channels and large conductance Ca2+-activated K+ channels.

Momordicine I alleviates isoproterenol-induced cardiomyocyte hypertrophy through suppression of PLA2G6 and DGK-ζ

  • Hongming Li;Yumei Qiu;Mengdie Xie;Changsheng Ouyang;Xiaoyun Ding;Hao Zhang;Wei Dong;Yinhua Xiong;Xilan Tang
    • The Korean Journal of Physiology and Pharmacology
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    • v.27 no.1
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    • pp.75-84
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    • 2023
  • This study aimed to observe the protective effect of momordicine I, a triterpenoid compound extracted from momordica charantia L., on isoproterenol (ISO)-induced hypertrophy in rat H9c2 cardiomyocytes and investigate its potential mechanism. Treatment with 10 μM ISO induced cardiomyocyte hypertrophy as evidenced by increased cell surface area and protein content as well as pronounced upregulation of fetal genes including atrial natriuretic peptide, βmyosin heavy chain, and α-skeletal actin; however, those responses were markedly attenuated by treatment with 12.5 ㎍/ml momordicine I. Transcriptome experiment results showed that there were 381 and 447 differentially expressed genes expressed in comparisons of model/control and momordicine I intervention/model, respectively. GO enrichment analysis suggested that the anti-cardiomyocyte hypertrophic effect of momordicine I may be mainly associated with the regulation of metabolic processes. Based on our transcriptome experiment results as well as literature reports, we selected glycerophospholipid metabolizing enzymes group VI phospholipase A2 (PLA2G6) and diacylglycerol kinase ζ (DGK-ζ) as targets to further explore the potential mechanism through which momordicine I inhibited ISO-induced cardiomyocyte hypertrophy. Our results demonstrated that momordicine I inhibited ISO-induced upregulations of mRNA levels and protein expressions of PLA2G6 and DGK-ζ. Collectively, momordicine I alleviated ISO-induced cardiomyocyte hypertrophy, which may be related to its inhibition of the expression of glycerophospholipid metabolizing enzymes PLA2G6 and DGK-ζ

The Effect of Photosynthesis, Stomatal Conductivity, Thermotolerance and Growth on Foliar Fertilization of Carbonated Water at Lettuce Hydroponic Cultivation (상추 양액재배 시 탄산수 엽면시비가 광합성, 기공전도, 내서성, 생육에 미치는 영향)

  • Woo, Y.H.;Kim, D.E.;Lee, J.W.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.21 no.1
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    • pp.115-122
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    • 2019
  • Foliar fertilization of carbonated water during lettuce hydroponic cultivation was increased photosynthetic rate and stomatal conductance as higher carbon dioxide concentration of carbonated water The higher the carbon dioxide concentration in the carbonated water was better growth of lettuce. However, the carbon dioxide concentration of 500 ppm and 700 ppm in the carbonated water was increased the tip-burn occurrence, and the yield was higher in the 300 ppm. the carbon dioxide concentration of 300 ppm in the carbonated water was lower in the fresh weight but increased yield resulted in the lower of the tip-burn occurrence The high temperature limits for growth were 32℃ in the control, 33℃ in the 300ppm and 34℃ in the 500 ppm according to analyze chlorophyll fluorescent Fo. The high temperature tolerance in lettuce increased approximately 4℃ by foliar fertilization treatments of carbonated water under this experiment conditions. Also the activity of SOD(superoxide dismutase), the antioxidant enzyme, was higher with high carbon dioxide concentration of the carbonated water.

Air-Processed Efficient Perovskite Solar Cell via Antisolvent Additive Engineering (안티솔벤트 첨가제 공정에 의한 대기 중 고효율 페로브스카이트 태양전지 제작)

  • Se-Yeong Baek;Seok-Soon Kim
    • Applied Chemistry for Engineering
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    • v.35 no.2
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    • pp.128-133
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    • 2024
  • Although antisolvent-assisted crystallization is one of the promising processes to produce high-quality perovskite films, general antisolvents such as chlorobenzene (CB) have toxic and volatile properties. In addition, CB is not suitable to control the crystallization of perovskite in the atmospheric air. In this work, isopropyl acetate (IA) is used as an eco-friendly antisolvent to demonstrate air-processed perovskite solar cells, and ethyl-4-cyanocinnamate (E4CN) with a cyano group, carbonyl group, and aromatic ring is introduced in IA to improve the performance and stability of devices. Defects at the surface and grain boundaries of the perovskite layer, such as un-coordinated Pb2+ and iodine, can be decreased resulting from the interaction of E4CN and perovskite, and thus reduced recombination and enhanced carrier transport can be expected. As a result, the perovskite device with E4CN achieves a high maximum power conversion efficiency (PCE) of 18.89% and outstanding stability, maintaining 60% of the initial efficiency for 300 h in the air without any encapsulation.