• Title/Summary/Keyword: H/sub ∞/ control

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Effective Control of CH4/H2 Plasma Condition to Synthesize Graphene Nano-walls with Controlled Morphology and Structural Quality

  • Park, Hyun Jae;Shin, Jin-ha;Lee, Kang-il;Choi, Yong Sup;Song, Young Il;Suh, Su Jeong;Jung, Yong Ho
    • Applied Science and Convergence Technology
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    • v.26 no.6
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    • pp.179-183
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    • 2017
  • The direct growth method is simplified manufacturing process used to avoid damages and contaminants from the graphene transfer process. In this paper, graphene nano-walls (GNWs) were direct synthesized using electron cyclotron resonance (ECR) plasma by varying the $CH_4/H_2$ gas flow rate on the copper foil at low temperature (without substrate heater). Investigations were carried out of the changes in the morphology and characteristic of GNWs due to the relative intensity of hydrocarbon radical and molecule in the ECR plasma. The results of these investigations were then discussed.

Understanding Behaviors of Electrolyzed Water in Terms of Its Molecular Orbitals for Controlling Electrostatic Phenomenon in EUV Cleaning (EUV 세정에서 정전기 제어를 위한 전해이온수 거동의 분자궤도 이해)

  • Kim, Hyung-won;Jung, Youn-won;Choi, In-sik;Choi, Byung-sun;Kim, Jae-young;Ryoo, Kun-kul
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.4
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    • pp.6-13
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    • 2022
  • The electrostatic phenomenon seriously issued in extreme ultraviolet semiconductor cleaning was studied in junction with molecular dynamic aspect. It was understood that two lone pairs of electrons in water molecule were subtly different each other in molecular orbital symmetry, existed as two states of large energy difference, and became basis for water clustering through hydron bonds. It was deduced that when hydrogen bond formed by lone pair of higher energy state was broken, two types of [H2O]+ and [H2O]- ions would be instantaneously generated, or that lone pair of higher energy state experiencing reactions such as friction with Teflon surface could cause electrostatic generation. It was specifically observed that, in case of electrolyzed cathode water, negative electrostatic charges by electrons were overlapped with negative oxidation reduction potentials without mutual reaction. Therefore, it seemed that negative electrostatic development could be minimized in cathode water by mutual repulsion of electrons and [OH]- ions, which would be providing excellences on extreme ultraviolet cleaning and electrostatic control as well.

Robust control of positioning systems with a bang-bang actuator (뱅-뱅 액츄에이터를 가진 위치 제어계의 강인 제어)

  • Choe, Jin-Tae;Kim, Jong-Sik
    • Journal of Institute of Control, Robotics and Systems
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    • v.2 no.4
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    • pp.257-263
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    • 1996
  • 본 논문에서는 기계적 위치 제어계에서 다단계 뱅-뱅 액츄에이터의 비선형성에 의한 목표 위치에서의 리미트 사이클을 방지하는 제어방법을 제안한다. 다단계 뱅-뱅 액츄에이터의 선형화된 모델인 기술함수를 이용하여 비선형성을 보상한다. 강인성을 확보하기 위해 루프 형성 기법에 의한 H/sub .inf./ 제어기가 설계된다. 제안된 제어방법은 기존의 선형제어기보다 비선형성이 보상되어 사역대가 작아지므로 최소 제어 가능 구간을 줄일 수 있다. 1축 위치 제어계의 실험을 하여 제안된 제어방법이 리미트 사이클을 줄이고 제어정도를 향상 시키는데 유효함을 입증하였다.

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Robust servo control of high speed optical disk drives (고속 광 디스크 드라이브의 강인 서보제어)

  • 임승철;정태영
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1997.10a
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    • pp.438-444
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    • 1997
  • Recently, optical disk drives are increasingly demanded to have higher speed as well as high information density, especially for applications like CD-ROM drives. To this end, improvement of their optical pick-up structure and control is recognized the very challenging issue. In this paper, the 2-D motion of the pick-up is first analytically modelled to identify the cause and effect of the troublesome cross coupling between auto-focusing and tracking directions. Subsequently, the overall system equations are derived to include the dynamics of the related components in the auto-focusing servo system. While its unmeasurable parameters being estimated by the least square error method, a simple but decent linear model can be obtained within its operating frequency range. To design the high speed and robust positional servo controller, the design specifications are detailed and H$\sub$.inf./ control method is employed based on the simple model. Using the pickup in a commercial 8 fold speed CD-ROM drive as an example, performance of the designed controller is verified by realtime experiments.

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Effect of Treatment with Selected Plant Extracts on the Physiological and Biochemical Parameters of Rice Plants under Salt Stress

  • Hyun-Hwa Park;Pyae Pyae Win;Yong-In Kuk
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.69 no.1
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    • pp.1-14
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    • 2024
  • High soil salinity is the most severe threat to global rice production as it causes a significant decline in rice yield. Here, we investigated the effects of various plant extracts on rice plant stress associated with high salinity. Additionally, we examined various physiological and biochemical parameters such as growth, photosynthetic activity, chlorophyll content, and lipid peroxidation - in rice plants after treatment with selected plant extracts under salt stress conditions. Of the 11 extracts tested, four - soybean leaf, soybean stem, moringa (Moringa oleifera), and Undaria pinnatifida extracts - were found to effectively reduce salt stress. A reduction of only 3-23% in shoot fresh weight was observed in rice plants under salt stress that were treated with these extracts, compared to the 43% reduction observed in plants that were exposed to stress but not given plant extract treatments (control plants). The effectiveness varied with the concentration of the plant extracts. Water content was higher in rice plants treated with the extracts than in the control plants after 6 d of salt stress, but not after 4 d of salt stress. Although photosynthetic efficiency (Fv/Fm), electron transport rate (ETR), and the content of pigments (chlorophyll and carotenoid) varied based on the types and levels of stress and the extracts that the rice plants were treated with, generally, photosynthetic efficiency and pigment content were higher in the treated rice compared to control plants. Reactive oxygen species (ROS), such as superoxide radicals, hydrogen peroxide (H2O2), and malondialdehyde (MDA), increased as the duration of stress increased. ROS and MDA levels were lower in the treated rice than in the control plants. Proline and soluble sugar accumulation also increased with the duration of the stress period. However, proline and soluble sugar accumulation were lower in the treated rice than in the control plants. Generally, the values of all the parameters investigated in this study were similar, regardless of the plant extract used to treat the rice plants. Thus, the extracts found to be effective can be used to alleviate the adverse effects of stress on rice crops associated with high-salinity soils.

A study on Safety Management and Control in Wet-Etching Process for H2O2 Reactions (습식 에칭 공정에서의 과산화수소 이상반응에 대한 안전 대책 및 제어에 관한 연구)

  • Yoo, Heung-Ryol;Son, Yung-Deug
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.4
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    • pp.650-656
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    • 2018
  • The TFT-LCD industry is a kind of large-scale industrial Giant Microelectronics device industry and has a similar semiconductor process technology. Wet etching forms a relatively large proportion of the entire TFT process, but the number of published research papers on this topic is limited. The main reason for this is that the components of the etchant, in which the reaction takes place, are confidential and rarely publicized. Aluminum (Al) and copper (Cu), which have been used in recent years for the manufacture of large area LCDs, are very difficult materials to process using wet etching. Cu, a low-resistance material, can only be used in the wet etching process, and is used as a substitute for Al due to its high speed etching, low failure rate, and low power consumption. Further, the abnormal reaction of hydrogen peroxide ($H_2O_2$), which is used as an etching solution, requires additional piping and electrical safety devices. This paper proposes a method of minimizing the damage to the plant in the case of adverse reactions, though it cannot limit the adverse reaction of hydrogen peroxide. In recent years, there have been many cases in which aluminum etching equipment has been changed to copper. This paper presents a countermeasure against abnormal reactions by implementing safety PLC with a high safety grade.

Spherical-shape Y2SiO5:Ce Phosphor Prepared from Organic Precursor Solution by Spray Pyrolysis (고분자 전구체 용액으로부터 분무열분해법에 의해 합성되어진 구형 형상의 Y2SiO5:Ce 형광체)

  • Kang, H.S.;Kang, Y.C.;Park, H.D.;Shul, Y.G.
    • Korean Journal of Materials Research
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    • v.13 no.3
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    • pp.180-184
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    • 2003
  • Ce-doped $Y_2$SiO$_{5}$ phosphor particles of spherical morphology, fine size, high crystallinity and high photoluminescence (PL) intensity were prepared by spray pyrolysis. When nitrate precursor solution is adopted, hollow particles were formed by uneven drying rate between surface and inside of droplet. Citric acid and ethylene glycol were introduced as polymeric precursor to control the morphology of particles. When polymeric solution is adopted, polymeric chain is formed by the esterification reaction between carboxyl and hydroxy groups of citric acid and ethylene glycol, and considered as controlling the drying characteristics of droplet. $Y_2$$SiO_{5}$ :Ce phosphor particles prepared from polymeric precursor solution were spherical, filled, fine size and not agglomerate before and after post heat treatment. The optimum doping concentration of cerium was 0.5 mol% of overall solution concentration. The optimum amount of TBOS of high PL intensity and pure crystallinity of X2-type $Y_2$$SiO _{5}$ was 105% of stoichiometric amount. The PL intensity of $Y_2$X$/_{5}$ :Ce phosphor particles prepared using the polymeric precursor solution was 164% of that of the nitrate precursor solution due to homogeneous composition and good morphology.y.

P123-Templated Co3O4/Al2O3 Mesoporous Mixed Oxides for Epoxidation of Styrene

  • Jung, Mie-Won;Kim, Young-Sil
    • Korean Journal of Materials Research
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    • v.22 no.6
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    • pp.316-320
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    • 2012
  • $Co_3O_4$, $Al_2O_3$ and $Co_3O_4$/$Al_2O_3$ mesoporous powders were prepared by a sol-gel method with starting matierals of aluminum isopropoxide and cobalt (II) nitrate. A P123 template is employed as an active organic additive for improving the specific surface area of the mixed oxide by forming surfactant micelles. A transition metal cobalt oxide supported on alumina with and without P123 was tested to find the most active and selective conditions as a heterogeneous catalyst in the reaction of styrene epoxidation. A bBlock copolymer-P123 template was added to the staring materials to control physical and chemical properties. The properties of $Co_3O_4$/$Al_2O_3$ powder with and without P123 were characterized using an X-ray diffractometer (XRD), a Field-Emission Scanning Electron Microscope (FE-SEM), a Bruner-Emmertt-Teller (BET) surface analyzer, and $^{27}Al$ MAS NMR spectroscopy. Powders with and without P123 were compared in catalytic tests. The catalytic activity and selectivity were monitored by GC/MS, $^1H$, and $^{13}C$-NMR spectroscopy. The performance for the reaction of epoxidation of styrene was observed to be in the following order: [$Co_3O_4$/$Al_2O_3$ with P123-1173 K > $Co_3O_4$/$Al_2O_3$ with P123-973 K > $Co_3O_4$-973 K>$Co_3O_4$/$Al_2O_3$-973 K > $Co_3O_4$/$Al_2O_3$ with P123-1473 K > $Al_2O_3$-973 K]. The existence of ${\gamma}$-alumina and the nature of the surface morphology are related to catalytic activity.

Hazard Evaluation of Runaway Reaction in Deboronation Process Using H2O2 in DIET Synthesis of Pharmaceutical Raw Material (의약품 원료 DIET 합성 중 H2O2를 이용한 붕소제거 반응공정에서의 폭주반응 위험성 평가)

  • Kim, Won Sung;Lee, Keun Won
    • Journal of the Korean Institute of Gas
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    • v.22 no.4
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    • pp.49-54
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    • 2018
  • In the Active Pharmaceutical Ingredient(API) manufacturing company, since the product is produced by the chemical reaction, fire and explosion are frequently occurred in the process of inputting the raw powder as the chemical reaction stage. There are not many studies on safety measures through analysis of cause of accident in the actual chemical reaction stage. In this study, we investigated the heat flow in the boron removal reaction process to investigate the risk in the chemical reaction stage. The study reaction process was performed by using the reaction calorimeter for the products synthesized at the actual raw material in pharmaceutical factory. The risk was estimated by comparing the maximum temperature of the synthesis reaction, which can generate heat due to the failure of cooling in the actual manufacturing process, and the technical temperature. These results are applied to commercial manufacturing sites and safety measures to control the risk of runaway reaction due to reaction heat are suggested.

Study on the Reduction Kinetics of In2O3 with Hydrogen (수소에 의한 In2O3의 환원반응속도론 연구)

  • Nahm, Kee-Suk;Kim, Youn-Sop;Lee, Wha-Young
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.305-311
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    • 1992
  • The experimental study on the reduction of $In_2O_3$ was performed by using thermogravimetric analyzer. The reduction of $In_2O_3$ was occurred at above $300^{\circ}C$. The reduction rates were rapidly increased with the reaction temperature, whilehardly affectedby the flow rate of hydrogen gas. It was found that the unreacted core model could be applied for the analysis of the reduction data and the rate control step was the chemical reaction of $In_2O_3$ with hydrogen on the surface of unreacted $In_2O_3$. The apparent activation energy for this reaction was 20kcal/g-mol $H_2$ and the rate equation of $In_2O_3$ reduction with hydrogen could be expressed in the following equation. ${\frac{dX}{dt}}=1.6{\times}10^5e^{-20000/RT}(1-X)^{2/3}$

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