• Title/Summary/Keyword: H/Q Ratio

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Identification of Tetrachloroethylene Sorption Behaviors in Natural Sorbents Via Sorption Models

  • Al Masud, Md Abdullah;Choi, Jiyeon;Shin, Won Sik
    • Journal of Soil and Groundwater Environment
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    • v.27 no.6
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    • pp.47-57
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    • 2022
  • A number of different methods have been used for modeling the sorption of volatile organic chlorinated compounds such as tetrachloroethylene/perchloroethylene (PCE). In this study, PCE was adsorbed in several natural sorbents, i.e., Pahokee peat, vermicompost, BionSoil®, and natural soil, in the batch experiments. Several sorption models such as linear, Freundlich, solubility-normalized Freundlich model, and Polanyi-Manes model (PMM) were used to analyze sorption isotherms. The relationship between sorption model parameters, organic carbon content (foc), and elemental C/N ratio was studied. The organic carbon normalized partition coefficient values (log Koc = 1.50-3.13) in four different sorbents were less than the logarithm of the octanol-water partition coefficient (log Kow = 3.40) of PCE due to high organic carbon contents. The log Koc decreased linearly with log foc and log C/N ratio, but increased linearly with log O/C, log H/C, and log (N+O)/C ratio. Both log KF,oc or log KF,oc decreased linearly with log foc (R2 = 0.88-0.92) and log C/N ratio (R2 = 0.57-0.76), but increased linearly with log (N+O)/C (R2 = 0.93-0.95). The log qmax,oc decreased linearly as log foc and log C/N increased, whereas it increased with log O/C, log H/C and log (N+O)/C ratios. The log qmax,oc increased linearly with (N+O)/C indicating a strong dependence of qmax,oc on the polarity index. The results showed that PCE sorption behaviors were strongly correlated with the physicochemical properties of soil organic matter (SOM).

Thermally Stratified Hot Water Storage (태양열의 성층축열과 주택이용에 관한 연구(성층축열))

  • Pak, Ee-Tong
    • Solar Energy
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    • v.10 no.3
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    • pp.3-12
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    • 1990
  • This paper deals with experimental research to increase thermal storage efficiency of hot water stored in an actual storage tank for solar application. The effect of increased energy input rate due to stratification has been discussed and illustrated through experimental data, which was taken by changing dynamic and geometric parameters. Ranges of the parameters were defined for flow rate, the ratio of diameter to height of the tank and inlet-exit water temperature difference. During the heat storage, when the flow was lower, the temperature difference was larger and the ratio of diameter to height of the tank was higher, the momentum exchange decreased. As for this experiment, when the flow rate was 8 liter/min, the temperature difference was $30^{\circ}C$ and the ratio of diameter to height of the tank was 3, the momentum exchange was minimized resulting in a good thermocline and a stable stratification. In the case of using inlet ports, if the modified Richardson number was less than 0.004, full mixing occured and so unstable stratification occured, which mean that this could not be recommended as storage through thermal stratification. Using a distributor was better than using inlet ports to form a sharp thermocline and to enhance the stratification. It was possible to get storage efficiency of 95% by using the distributor, which was higher than a storage efficiency of 85% obtained by using inlet ports in same operation condition. Furthermore, if the distributor was manufactured so that the mainpipe decreases in diameter toward the dead end to maintain constant static pressure, it might be predicted that further stable stratification and higher storage efficiency are obtainable(ie:more than 95%).

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Spontaneously Adsorbed Mo Layers on Pt(111) and Pt(100) Single Crystal Electrode Surfaces

  • Han, Yoon-gu;Jung, Chang-hoon;Rhee, Choong-Kyun
    • Bulletin of the Korean Chemical Society
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    • v.23 no.3
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    • pp.395-399
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    • 2002
  • The voltammetric behavior of spontaneously adsorbing Mo layers on Pt(111) and Pt(100) electrodes has been studied to estimate the number of electrons involved in the electrochemical processes of spontaneously adsorbed Mo and the number of the bloc ked Pt sites for hydrogen adsorption. On Pt(111) and Pt(100) surfaces, the spontaneously adsorbed Mo layers showed redox peaks at 0.10 V and 0.15 V, respectively, and continuous current-potential waves in the conventional hydrogen region. Since the potential range of the Mo redox processes on both surfaces overlapped partially with the potential range of hydrogen adsorption, the variation in the ratio of the total charge of Mo and H ($Q_H$ +$Q_{MO}$) to the hydrogen charge of clean Pt electrode ($Q_H^0$) was analyzed. From the analysis, six electrons were estimated to be involved in the electrochemical processes of the spontaneously adsorbed Mo, and four Pt sites for hydrogen adsorption were calculated to be blocked by one adsorbed Mo atom. Based on these figures and the pH dependence of the Mo redox processes, we have proposed an electrochemical equation for the spontaneously adsorbed Mo. This electrochemical equation led us to conclude that the saturation coverage of the spontaneously adsorbed Mo is 0.25. The coverage of Mo less than 0.25, however, could not be determined voltammetrically due to the convolution of the charges of Mo and H.

Comparing Changes in Knee Muscle Strength after Reconstruction of the Anterior and Posterior Cruciate Ligaments

  • Hyun, SangWook;Kim, SoHee;Kim, TaeHo
    • The Journal of Korean Physical Therapy
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    • v.31 no.6
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    • pp.339-345
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    • 2019
  • Purpose: The purpose of this study was to identify changes in knee muscle strength after reconstruction of the anterior cruciate ligament (ACL) and the posterior cruciate ligament (PCL). Methods: Thirteen subjects (males) with anterior ligament injury and ten subjects (males) with posterior ligament injury voluntarily participated in this study. Both groups were evaluated at the pre-and post-reconstruction stages using an isokinetic dynamometer. Peak torque, total work, and the hamstrings to quadriceps (H/Q) peak torque ratio were calculated at angular velocities of 60°/sec and 180°/sec. Statistical analysis was conducted on SPSS 18.0 for Windows using t-tests to compare mean differences. Results: At an angular velocity of 60°/sec, both the ACL and PCL groups showed a significant increase in muscle strength in the flexors and extensors. Muscle strength in the extensors was significantly increased in the PCL group compared to the ACL group. At an angular velocity of 180°/sec, the ACL group showed a significant increase in muscle endurance in the flexors and extensors, and the PCL group showed a significant increase in muscle endurance in the flexors. At angular velocities of 60°/sec and 180°/sec, the H/Q peak torque ratio increased in the ACL group but decreased in the PCL group. Consequently, the H/Q peak torque ratio was significantly different for the two groups. Conclusion: The results suggest that the patients with ACL injury should focus on strengthening the knee extensors and that the patients with PCL injury need to strengthen the knee flexors.

The Effects of Experimental Warming on Seed Germination and Growth of Two Oak Species (Quercus mongolica and Q. serrata) (온난화 처리가 신갈나무(Quercus mongolica)와 졸참나무(Q. serrate)의 종자발아와 생장에 미치는 영향)

  • Park, Sung-ae;Kim, Taekyu;Shim, Kyuyoung;Kong, Hak-Yang;Yang, Byeong-Gug;Suh, Sanguk;Lee, Chang Seok
    • Korean Journal of Ecology and Environment
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    • v.52 no.3
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    • pp.210-220
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    • 2019
  • Population growth and the increase of energy consumption due to civilization caused global warming. Temperature on the Earth rose about $0.7^{\circ}C$ for the last 100 years, the rate is accelerated since 2000. Temperature is a factor, which determines physiological action, growth and development, survival, etc. of the plant together with light intensity and precipitation. Therefore, it is expected that global warming would affect broadly geographic distribution of the plant as well as structure and function ecosystem. In order to understand the effect of global warming on the ecosystem, a study about the effect of temperature rise on germination and growth in the plant is required necessarily. This study was carried out to investigate the effects of experimental warming on the germination and growth of two oak species(Quercus mongolica and Q. serrata) in temperature gradient chamber(TGC). This study was conducted in control, medium warming treatment($+1.7^{\circ}C$; Tm), and high warming treatment ($+3.2^{\circ}C$; Th) conditions. The final germination percentage, mean germination time and germination rate of two oak species increased by the warming treatment, and the increase in Q. serrata was higher than that in Q. mongolica. Root collar diameter, seedling height, leaf dry weight, stem dry weight, root dry weight, and total biomass were the highest in Tm treatment. Butthey were not significantly different in the Th treatment. In the Th treatment, Q. serrata had significantly higher H/D ratio, S/R ratio, and low root mass ratio (RMR) compared with control plot. Q. mongolica had lower RMR and higher S/R ratio in the Tm and Th treatments compared with control plot. Therefore, growth of Q. mongolica are expected to be more vulnerable to warming than that of Q. serrata. The main findings of this study, species-specific responses to experimental warming, could be applied to predict ecosystem changes from global warming. From the result of this study, we could deduce that temperature rise would increase germination of Q. serrata and Q. mongolica and consequently contribute to increase establishment rate in the early growth stage of the plants. But we have to consider diverse variables to understand properly the effects that global warming influences germination in natural condition. Treatment of global warming in the medium level increased the growth and the biomass of both Q. serrata and Q. mongolica. But the result of treatment in the high level showed different aspects. In particular, Q. mongolica, which grows in cooler zones of higher elevation on mountains or northward in latitude, responded more sensitively. Synthesized the results mentioned above, continuous global warming would function in stable establishment of both plants unfavorably. Compared the responses of both sample plants on temperature rise, Q. serrata increased germination rate more than Q. mongolica and Q. mongolica responded more sensitively than Q. serrata in biomass allocation with the increase of temperature. It was estimated that these results would due to a difference of microclimate originated from the spatial distribution of both plants.

Effects of Energy System Contribution on Isokinetic Muscle Strength in Various Sport Events Athletes (무산소, 유산소 운동종목별 엘리트선수의 등속성 근기능에 미치는 영향)

  • Kwon, Hyeong-Tae;Kim, Ki-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.10
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    • pp.272-279
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    • 2018
  • This study was conducted to compare the muscle strength, muscle power, and H/Q ratio according to energy system contribution in athletes participating in various sports. Subjects of the study were assigned into an Anaerobic Exercise Group (AEG, n=60; Short-Distance, Weight Lifting, Jumping, Throwing, Bowling, Golf) and an Endurance Exercise Group (EEG, n=60; Modern Pentathlon, Field Hockey, Handball, Cycle, Boxing, Rowing) groups. Isokinetic peak torque/body weight% and flexor/extensor ratio at 60, 180 deg/sec of knee extension and flexion were measured using an cybex 770. Data analysis was conducted using an independent t-test and one-way ANOVA. Based on the results of this study, there was higher extension, flexion strength and flexion power in the AEG than the EEG (p<0.05). We also confirmed higher muscle strength and muscle power in short distance and jumping athletes than other athletes participating in other events (p<0.05). However, there was no significant difference within the endurance exercise group. The HS ratio was within a stable range of 50% to 60% in all events. Collectively, the outcomes of this study indicate that routine physiological and performance testing can provide measurable benefits for elite athletes and their coaches.

Enhancement for Magnetic Property of Ba-ferrite for Perpendicular Magnetic Recording Using Ultrasonic Dispersion (초음파 분산에 의한 수직자기기록용 Ba-ferrite의 자기적 특성 향상)

  • Choi, Hyun-Seung;Kim, Chang-Gon;Jang, Hak-Jin;Jung, Ji-Hyung;Yoon, Seog-Young;Kim, Tae-Ok
    • Journal of the Korean Ceramic Society
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    • v.39 no.8
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    • pp.758-763
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    • 2002
  • The various ultrasonic energies (28 kHz, 40 kHz, 70 kHz) were used to improve the magnetic properties of Ba-ferrite as the perpendicular magnetic recording materials. In the sheet formation process, the different orientation hars were used to orientate perpendicularly the dispersed Ba-ferrite to sheet. Throughout these experiments, we have obtained relatively higher value of S. Q. (Squreness Ratio : 0.783) and O. R. (Orientation Ratio : 2.87) magnetic properties at 2 h ultrasonic treatment of 40 kHz ultrasonic energy. With aid of SEM(Scanning Electron Microscopy) images, the obtained sheet with dispersed of Ba-ferrite could be used for perpendicular magnetic recording due to orientated to easy magnetization axis, c-axis. In addition, the value of S. Q. of sheet decreased with increasing applied magnetic field angle during measuring of S. Q. value with changing applied magnetic field angle by VSM (Vibrating Sample Magnetrometer). This result also induced the probability for prependicular magnetic recording.

Influence of Suction Force of Plate Anchor Embedded in Kaolinite (Kaolinite에 근입된 앵커에서 흡입력이 미치는 영향)

  • 이준대;이봉직
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.108-113
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    • 1997
  • Plate anchors are primarily used in the foundation construction of earth-supported and earth-retaining structures. In order to estimate uplift capacity as well as suction force of clay, model tests were peformed with respect to various embedment depths and two different moisture contents in the prepared saturated kaolinite. Further, suction effects on the ultimate uplift capacity, at the various embedment depths of anchor, were also taken into account. Test results show that ultimate uplift capacity including suction force increases from 4.2kg at H/D=1 upto 11.6kg at H/D=5 in K1 and from 2.3kg at H/D=1 upto 7.3kg at H/D=5 in K2 respectively. The ratio of $F_s/Q_n/$ decreases along with the increases in the embedment ratio. In general, mud suction force under the ultimate uplift capacity in kaolinite decreases or becomes constant along with the increase of the embedment ratio.

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SOME NEW RESULTS ON THE RUDIN-SHAPIRO POLYNOMIALS

  • Taghavi, M.;Azadi, H.K.
    • Journal of applied mathematics & informatics
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    • v.26 no.3_4
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    • pp.583-590
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    • 2008
  • In this article, we focuss on. sequences of polynomials with {$\pm1$} coefficients constructed by recursive argument that is known as Rudin-Shapiro polynomials. The asymptotic behavior of these polynomials defines as the ratio of their 2q-norm with 2-norm to be dominated by some number depending on q or "the best" by an absolute constant. In this work we first show the conjecture holds for some finite numbers of m and then introduce a technique that give the result for any positive odd integer m whenever it holds for all pervious even numbers.

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2.22-inch qVGA ${\alpha}$-Si TFT-LCD Using a 2.5 um Fine-Patterning Technology by Wet Etch Process

  • Lee, J.B.;Park, S.;Heo, S.K.;You, C.K.;Min, H.K.;Kim, C.W.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1649-1652
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    • 2006
  • 2.22-inch qVGA $(240{\times}320)$ amorphous silicon thin film transistor liquid active matrix crystal display (${\alpha}$- Si TFT-AMLCD) panel has been successfully demonstrated employing a 2.5 um fine-patterning technology by a wet etch process. Higher resolution 2.22-inch qVGA LCD panel with an aperture ratio of 58% can be fabricated because the 2.5 um fine pattern formation technique is combined with high thermal photo-resist (PR) development. In addition, a novel concept of unique ${\alpha}$-Si TFT process architecture, which is advantageous in terms of reliability, was proposed in the fabrication of 2.22-inch qVGA LCD panel. Overall results show that the 2.5 um finepatterning is a considerably significant technology to obtain higher aperture ratio for higher resolution ${\alpha}$-Si TFT-LCD panel realization.

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