• Journal of Korean Society of Water and Wastewater
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• v.24 no.1
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• pp.109-117
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• 2010

In the present study, the degradation characteristics of Lindane by Advanced Oxidation Processes(UV/$H_2O_2$, Photo-Fenton process) were studied. The degradation efficiency of Lindane in aqueous solution was investigated at various initial pH values, Fenton's reagent concentrations and initial concentrations of Lindane. GC-ECD was used to analyze lindane. Lindane has not been degraded without application of AOPs over two hours. But, approximately 5% of lindane was degraded with UV or $H_2O_2$ alone. Lindane with UV/$H_2O_2$ process showed approximately 7% higher removal efficiency than $H_2O_2$ process. In the UV/$H_2O_2$ process, the pH values did not affect the removal efficiency. The optimal mole ratio of $H_2O_2/Fe^{2+}$ for lindane degradation is about 1.0 in Photo-Fenton process. Also, the experimental results showed that lindane removal efficiency increased with the decrease of initial concentration of lindane. Under the same conditions, the order lindane of removal efficiency is as following : Photo-Fenton process > UV/$H_2O_2$ process > $H_2O_2$ process. In addition, intermediate products were identified by GC-MS techniques. Than PCCH(Pentachlorocyclohexene) was identified as a reaction intermediate of the Photo-Fenton process.

• Journal of the Mineralogical Society of Korea
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• v.20 no.4
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• pp.267-275
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• 2007

Melting slag generated from municipal-incinerator ash contains lots of impurities which have adverse effects on zeolite synthesis. These impurities are detrimental to zeolite synthesis, and the yield and purity of zeolite was decreased. And thus its performance is lowered. In melting slag, there are lots of components such as $Fe_2O_3$, FeO and CaO. To remove these impurities, we treated the melting slag with hydrochloric acid at initial pH 1, 3, 5, and 7. After the treatment, the $SiO_2,\;Fe_2O_3,\;and\;TiO_2$ ratios increased, but the $Al_2O_3,\;FeO,\;CaO,\;Na_2O$ and MgO ratios decreased. We reacted these treated slag in a NaOH solution under hydrothermal conditions at $80^{\circ}C$. The hydrothermal products from the slag and the slag treated at pH 7 and pH 5 were determined to be tobermorite, whereas those at pH 3 and pH 1, Na-P1 and Na-X zoelite respectively. CaO was found to inhibit the synthesis of zeolite.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.12
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• pp.1147-1153
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• 2010

To evaluate the solar photocatalytic degradation efficiency of chloroform in a real solar-light driven compound parabolic concentrators (CPCs) system, $TiO_2$ was irradiated with a metalhalide lamp (1000 W), which has a similar wavelength to sunlight. The results were applied to a pilot scale reactor system by converting the data to a standardized illumination time. In addition, the effects of initial pH and the $TiO_2$ dose on the photocatalytic degradation of chloroform were investigated. The results were compared with the specific surface area (S.S.A) and particle size of $TiO_2$, which changed according to the pH, to determine the relationship between the S.S.A, particle size and the photocatalytic degradation of chloroform. The experiment was carried out at pH 4~7 using 0.1, 0.2, 0.4 g/L of $TiO_2$. The particle size and specific surface area of $TiO_2$ were measured. There was no significant difference between the variables. However, pH affects the particle size distribution and specific surface area of $TiO_2$. Inaddition, the activation of a photocatalyst did not show a linear relationship with the specific surface area of $TiO_2$ in the photocatalytic degradation of chloroform.

• Journal of Magnetics
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• v.5 no.1
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• pp.23-25
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• 2000

We have investigated the effects of Ar and$O_2$-ion milling on the exchange coupling field ($H_{ex}$) and coercive field ($H_c$) at the interfaces between substrates and NiO/NiFe films, to understand the exchange biasing mechanism. The $O_2$-ion milling was successfully performed by means of the electron cyclotron resonance (ECR) process. We found that the local roughness gradient of the NiO surface increased by $O_2$-ion milling. The ratio of $H_{ex}/H_c$ increased from 0.87 to 1.77, whereas $H_c$ decreased by almost a half as a results of the ion milling. The decrease in $H_c$could be interpreted as due to the refinement of magnetic domain size, which arose from the increase of the local roughness gradient of the NiO surface. The decrease in low $H_c$, and increase in $H_{ex}$ in NiO spin valves by ECR-ion milling are in the right direction far use in magnetoresistance (MR) heads.

• Applied Chemistry for Engineering
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• v.5 no.5
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• pp.819-824
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• 1994

A membrane-like $H_3PMo_{12}O_{40}$-polysulfone film was prepared by blending $H_3PMo_{12}O_{40}$ with polysulfone using dimethylformamide as a common solvent. SEM and EDX analysis showed that $H_3PMo_{12}O_{40}$ was uniformly and finely distributed in the film catalyst. The ESCA measurement also revealed that the oxidation state of Mo was not changed. The $H_3PMo_{12}O_{40}$-polysulfone catalyst showed lower activity for acid-catalyzed reaction and higher activity for oxidation reaction than $H_3PMo_{12}O_{40}$ in ethanol conversion reaction. The oxidation activity of the film catalyst was about 10 times higher than $H_3PMo_{12}O_{40}$. The decrease of acidic activity was due to DMF strongly adsorbed in acid sites of $H_3PMo_{12}O_{40}$, whereas the increase of oxidation activity was mainly due to uniform distribution of $H_3PMo_{12}O_{40}$. Adsorption results showed that the surface character of $H_3PMo_{12}O_{40}$ was drastically increased, while the bulk property of that was almost same after blending. It is suggested that the control of surface/bulk property as well as acid/redox property of heteropoly acid would be possible by blending it with a polymer.

• Fire Science and Engineering
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• v.29 no.5
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• pp.104-109
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• 2015

The purpose of this study was to compare the ventilatory volume and airway pressure of a facial mask, endotracheal intubation, King tube, and I-gel devices with an Oxylator EM-100 using a RespiTrainer. The data were obtained from July 20 to 21, 2015. Data were analyzed using SPSS WIN 18.0 software. The ventilatory volume for endotracheal intubation was 537 ml (95% CI 530~545 ml), that for the King tube was 502 ml (95% CI 499~506 ml), that for the I-gel was 88 ml (95% CI 485~491 ml), and that for the facial mask was 499 ml (95% CI 496~503 ml). The airway pressure for endotracheal intubation was $11.34cmH_2O$ (95% CI $11.21{\sim}11.41cmH_2O$), that for the King tube was $10.67cmH_2O$ (95% CI $10.60{\sim}10.75cmH_2O$), that for the I-gel was $10.42cmH_2O$ (95% CI $10.35{\sim}10.67cmH_2O$), and that for the facial mask was $10.61cmH_2O$ (95% CI $10.55{\sim}10.68cmH_2O$). As a result, we were able to identify the appropriate ventilatory volume using the Oxylator EM-100.

• Journal of the Korean Chemical Society
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• v.31 no.2
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• pp.178-183
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• 1987

The kinetics of the reaction of $[Mo_3O_4(H_2O)_9]^{4+}$ with $VO_2^+$have been studied at $25^{\circ}C$ by spectrophotometric method. With$VO_2^+$ in excess, the $[Mo_3O_4(H_2O)_9]^{4+}$ reaction can be expressed as $Mo^{IV}_3+6V^V{\rightleftarrows}3Mo^{IV}+6V^IV}$. Observed rate constants for the reaction are dependent on [$H^+$] and [$VO_2^+$]. Mechanism for the redox of $[Mo_3O_4(H_2O)_9]^{4+}$and $VO_2^+$ is proposed and discussed.

• Journal of the Korean Chemical Society
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• v.30 no.6
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• pp.532-537
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• 1986

The kinetics of the reaction of $[Mo_2O_4(H_2O)_6]^{2+}$ with $VO_2^+$ have been studied at $25^{\circ}C$ by spectrophotometric method. Stoichiometry of the oxidation of$ [Mo_2O_4(H_2O)_6]^{2+}$ is followed as $Mo_2^V + 2V^V {\rightleftharpoons} 2Mo^{VI} + 2V^{IV}$. Observed rate constants are dependent on $ [H^+]\;and\;[VO_2^+]$. Mechanism for the redox of $[Mo_2O_4(H_2O)_6]^{2+}\;and\;VO_2^+$ is proposed and discussed.

• Resources Recycling
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• v.20 no.4
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• pp.71-77
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• 2011

$MoO_3$ powders were reduced to $MoO_2$ under Ar+$H_2$ gas mixture in a tubular furnace at temperature range 723~873 K. Reaction rate was quantitatively deduced by measuring relative humidity of off gas. Observed reaction rate increased significantly with hydrogen partial pressure and reaction temperature and the rate of $H_2O$ evolution increased drastically during the initial period of reduction. As reduction proceeded, however, $H_2O$ partial pressure decreased noticeably. During the initial period of the reduction, a linear relationship for time dependence of the reduction fraction was observed. The activation energy for the reduction of $MoO_3$ to $MoO_2$was 73.56 kJ/mol during the initial period of reduction.

• Proceedings of the Acoustical Society of Korea Conference
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• autumn
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• pp.313-316
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• 2001

이동전화 서비스에 있어서 가장 중요한 것 중 하나가 H/O이다. 그동안 동일 세대간$(2G\leftrightarrow2G)$ H/O를 위해 소프트 H/O방식과 소프터 H/O방식이 이용되어 왔으며 별다른 문제점이 없었다. 그러나 사용자의 욕구와 통신기술의 발달로 세대가 다른 시스템이 공존하여 서비스를 시작하므로써 세대간$(2.5\leftrightarrow2G)$ H/O를 위해 파이롯 비컨 방식과 주기형 비컨 방식이 이용되어 왔으나 비경제적이고 능률적이지 못하였다. 이를 개선하기 위해 2001년 4월 ENHHO방식이 개발되어 현재 이용되고 있다. 이 방식 또한 파이롯 신호가 5개 이상인 경우 H/O가 진행되는 동안 통화정보가 순간적으로 단절되는 단점을 갖고 있다. 따라서 본 논문에서는 ENHHO방식의 문제점을 개선하기 위한 알고리즘을 제안하고 이를 이용한 현장측정 결과를 분석하므로써 그 타당성을 검증하였다.