• Title/Summary/Keyword: Ground state

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The Effect of the Ligand's Spin-Orbit Coupling on the Zero-Field Splitting in the Low Spin Octahedral Ti(Ⅲ), V(Ⅲ), Fe(Ⅲ) and Ni(Ⅱ) Complexes (리간드의 Spin-Orbit Coupling이 작은 스핀팔면체 Ti(Ⅲ), V(Ⅲ), Fe(Ⅲ) 및 Ni(Ⅱ) 착물의 Zero-Field Splitting에 미치는 영향)

  • Ahn Sangwoon;Lee Kee Hag
    • Journal of the Korean Chemical Society
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    • v.23 no.2
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    • pp.65-74
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    • 1979
  • An effect of the spin-orbit coupling interaction of ligand orbitals on the ground state for octahedral $[Ti(Ⅲ)A_3B_3]$, $ [V(Ⅲ)A_3B_3]$, $ [Fe(Ⅲ)A_3B_3]$ and $ [Ni(Ⅱ)A_3B_3]$ type complexes has been investigated in this work, applying the degenerate perturbation theory. The wave functions are not affected but the energy level splitting for the ground state of these complexes by the spin-orbit coupling interaction of ligand orbitals. The extent of effect on the energy level splitting for the ground state is decreased in order Ti(Ⅲ) > V(Ⅲ) > Fe(Ⅲ).

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Blind Drift Calibration using Deep Learning Approach to Conventional Sensors on Structural Model

  • Kutchi, Jacob;Robbins, Kendall;De Leon, David;Seek, Michael;Jung, Younghan;Qian, Lei;Mu, Richard;Hong, Liang;Li, Yaohang
    • International conference on construction engineering and project management
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    • 2022.06a
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    • pp.814-822
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    • 2022
  • The deployment of sensors for Structural Health Monitoring requires a complicated network arrangement, ground truthing, and calibration for validating sensor performance periodically. Any conventional sensor on a structural element is also subjected to static and dynamic vertical loadings in conjunction with other environmental factors, such as brightness, noise, temperature, and humidity. A structural model with strain gauges was built and tested to get realistic sensory information. This paper investigates different deep learning architectures and algorithms, including unsupervised, autoencoder, and supervised methods, to benchmark blind drift calibration methods using deep learning. It involves a fully connected neural network (FCNN), a long short-term memory (LSTM), and a gated recurrent unit (GRU) to address the blind drift calibration problem (i.e., performing calibrations of installed sensors when ground truth is not available). The results show that the supervised methods perform much better than unsupervised methods, such as an autoencoder, when ground truths are available. Furthermore, taking advantage of time-series information, the GRU model generates the most precise predictions to remove the drift overall.

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Numerical Simulation of Ground Heat Exchanger Embedded Pile Considering Unsaturated Soil Condition (불포화 지반 조건을 고려한 파일 매입형 열교환기의 수치해석)

  • Choi, Jung-Chan;Lee, Seung-Rae
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.03a
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    • pp.213-220
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    • 2010
  • This study presents a numerical simulation model of vertical ground heat exchangers, considering unsaturated hydro static ground conditions induced by the ground water table fluctuation. Heat transfer in ground and grout is modeled by a 3-D FEM transient conductive heat transfer model, where heat transfer between circulating fluid and heat exchanging pipe is treated as 1-D quasi steady state forced convective elements. To take into account the unsaturated ground condition, soil thermal conductivity and heat capacity which are dependent on the matric suction are applied to ground elements. Parametric studies considering various ground water table conditions are conducted to investigate the influence of unsaturated hydro static ground condition on the mean heat exchange rate of ground heat exchanger. Simulation results considering water table fluctuation show 60~100% of mean heat exchange rate for a saturated soil condition and 125~208% of that for a dry soil condition. Thus consideration of unsaturated soil condition is substantially recommended for more accurate design and performance evaluation for ground heat exchangers.

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Prediction of Residual Settlement of Ground Improved by Vertical Drains Using the Elasto-Viscous Consolidation Model - Application for Field Condition - (탄-점성 압밀이론에 의한 버티칼 드레인 타설지반의 잔류침하 예측 (II) - 현장조건에의 적용 -)

  • Baek, Won-Jin;Lee, Kang-Il;Kim, Woo-Jin
    • Journal of the Korean Geotechnical Society
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    • v.23 no.6
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    • pp.85-95
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    • 2007
  • In this study, in order to propose the prediction method of the residual settlement of clayey ground improved by vertical drains, a series of numerical analyses for a model ground were carried out using the elasto-viscous consolidation model. And the effects of ground improvement conditions of the ratio of effective radii $(r_e/r_w)$, consolidation pressure $({\Delta}p)$ on normally consolidated state, and the OCR (overconsolidation ratio) on overconsolidated state to reduce the residual settlement in three-dimensional consolidation by vertical drains were investigated by performing a series of numerical analyses. Furthermore, based on the results of a series of numerical analyses for the model ground, the predicting method of the residual settlement of clayey ground with vertical drains and the determination method of the value of OCR required to control the residual settlement within an acceptable value are proposed.

Evaluation of Tunnel Face Stability with the Consideration of Seepage Forces (침투력을 고려한 토사터널 막장의 안정성 평가방법에 대한 고찰)

  • 남석우;이인모
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.10a
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    • pp.193-200
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    • 1999
  • Since Broms and Bennermark(1967) suggested the face stability criterion based on laboratory extrusion tests and field observations, the face stability of a tunnel driven in cohesive material has been studied by several authors. And recently, more general solution for the tunnel front is given by Leca and Panet(1988). They adopted a limit state design concept to evaluate the face stability of a shallow tunnel driven into cohesionless material and showed that the calculated upper bound solution represented the actual behavior reasonably well. In this study, two factors are simultaneously considered for assessing tunnel face stability: One is the effective stress acting on the tunnel front calculated by upper bound solution; and the other is the seepage force calculated by numerical analysis under the condition of steady state ground water flow. The model tests were performed to evaluate the seepage force acting on the tunnel front and these results were compared with results of numerical analysis. Consequently, the methodology to evaluate the stability of a tunnel face including limit analysis and seepage analysis is suggested under the condition of steady state ground water flow.

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Spectroscopic Evidence for Aggregation of Stilbene Derivatives in Solution

  • Aguiar, M.;Akcelrud, L.;Pinto, M.R.;Atvars, T.D.Z.;Karasz, F.E.;Saltiel, Jack
    • Journal of Photoscience
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    • v.10 no.1
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    • pp.149-155
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    • 2003
  • The absorption, fluorescence and fluorescence-excitation spectra of concentrated toluene solutions of selected para substituted trans-stilbene derivatives provide strong evidence for aggregation. A red-shifted fluorescence spectrum peaking at 420 nm gains in intensity as the stilbene concentration is increased. The excitation spectrum of this new emission is well to the red of the normal stilbene absorption spectrum, consistent with the appearance of a red shifted shoulder in the UV spectrum. Formation of a fluorescent ground state dimer (or higher aggregate) is proposed to account for these observations. The presence of polar substituents is crucial to the formation of this ground state complex.

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Seismic fragility evaluation of piping system installed in critical structures

  • Ju, Bu Seog;Jung, Woo Young;Ryu, Yong Hee
    • Structural Engineering and Mechanics
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    • v.46 no.3
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    • pp.337-352
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    • 2013
  • Seismic performance of critical facilities has been focused on the structural components over the past decade. However, most earthquake damages were observed to the nonstructural components during and after the earthquakes. The primary objective of this research was to develop the seismic fragility of the piping system incorporating the nonlinear Tee-joint finite element model in the full scale piping configuration installed in critical facilities. The procedure for evaluating fragility curves corresponding to the first damage state was considered the effects of the top floor acceleration sensitivities for 5, 10, 15, and 20 story linear RC and steel building systems subjected to 22 selected ground motions as a function of ground motion uncertainties. The result of this study revealed that the conditional probability of failure of the piping system on the top floor in critical facilities did not increase with increased level of story height and in fact, story level in buildings can tune the fragilities between the building and the piping system.

Deformation and Strength Characteristics of Compacted Weathered Granite Soil under Pland Strain Condition (평면변형률 조건에서 다짐화강토의 변형과 강도특성)

  • 정진섭
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.41 no.2
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    • pp.70-79
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    • 1999
  • The lower ground of structure, in which the strip loads, such as earth dams and embankments , are signiificantly working on , is required to be interpreted as a state of plane strain where the strain of intermediated principal stress direction is put '0' . The plane strain state is frquently observed in actural soil engineering case. For those case, drained stress-strain and strength behavior of Iksan weathered granite soil prepared in cubical specimens with cross-anisotropic fabric was studied by conventional triaxial compression, plane strain and cubial triaxial tests with independent control of the three principal stress. All specimens were loaded under conditions of principl stress directions fixed and aligned with the directions of the material axes. As a result of research , when a ground condition is analyzed under plane strain state, the shear strength obtained from the conventional triaxial compression test can be understimated.

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Self-weight Consolidation Analysis of Soft Dredged Clay Ground (준설성토지반의 자중압밀해석)

  • Kim, Hyun-Tae;Lee, Eun-Sung;Kim, Seog-Yeol;Hong, Byung-Man
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2003.10a
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    • pp.151-154
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    • 2003
  • This paper reviews depositional environments and consolidation characteristic of Soft Dredged Clay fill and then analytical solution of self-weight consolidation is made to find consolidated state. It's known that Soft Dredged Clay Ground is in the under-consolidated state under $U{\fallingdotseq}30%$ from analytical solution. It is effective for higher consolidation rate that the time of Dredge is shorter ani the time of leave is longer. It is conclude that the under-consolidated state should be considered in prediction of consolidation settlement.

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Evaluation of Bridge Fragility by Capacity Spectrum Method (성능스펙트럼에 의한 교량의 손상도 평가)

  • ;Shinozuka, Masanobu
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2001.04a
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    • pp.329-336
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    • 2001
  • This study examines the fragility curves of a bridge by Capacity Spectrum Method. A sample of 10 nominally identical but statistically different bridge and 80 ground-motion time histories are considered to account for the uncertainties related to the structural capacity and ground motion, respectively. The comparison of fragility curves by Capacity Spectrum Method with those by time-history analysis indicates that the agreement is excellent for the state of at least minor damage, but not as good for the state of major damage where nonlinear effects clearly play a crucial role. Overall, however, the agreement is adequate even in the state of major damage considering the large number of typical assumptions under which the analyses of fragility characteristics are performed.

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