• Title/Summary/Keyword: Green solution

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Solution-processed Organic Trilayer Solar Cells Incorporating Conjugated Polyelectrolytes

  • Cha, Myoung Joo;Walker, Bright;Seo, Jung Hwa
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.192.1-192.1
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    • 2014
  • We report solution-processed organic trilayer solar cells consisting of poly (3-hexylthiophene) (P3HT), a conjugated polyelectrolyte (CPE) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM), wherein the effect CPE layer thickness on device properties was investigated. The current-voltage characteristics under illumination and dark as well as photoluminescence were characterized using various concentrations (0.02, 0.1, and 0.3wt%) of to deposit the CPE interlayer between the donor and acceptor layers. We also investigated the influence of molecular dipole moments in the trilayer solar cells by external stimuli. These results provide an experimental approach for investigating the influence of interfacial dipoles on solar cell parameters when placed between the donor and acceptor and allow us to obtaining fundamental information about the donor/acceptor interface in organic solar cells.

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On the Surge Motion of a Ship in Rectangular Harbor (항만내 계류선박의 수평운동 해석)

  • 최항순;조일형
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.1 no.1
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    • pp.81-86
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    • 1989
  • Herein the surge-heave-pitch motion of a ship has been analyzed within the framework of linear potential theory. The ship is assumed slender weakly moored along the centerline of a rectangular harbor with constant depth and straight coastline. The method of matched asymptotic expansion is us-ed to obtain the leading-order solution. The ship and harbor responses to incident long waves can be re-presented in terms of Green's function, which is the solution of the Helmholtz equation satisfying necessary boundary conditions. Numerical results clearly indicate the importance of the surge motion.

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Well-Defined Thermoresponsive Copolymers with Tunable LCST and UCST in Water

  • Jung, Seo-Hyun;Lee, Hyung-Il
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.501-504
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    • 2014
  • A thermoresponsive polymer, poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA), was successfully synthesized by atom transfer radical polymerization (ATRP). Different amounts of 1,3-propanesultone were used as quaternization agent to transit the PDMAEMA into partially modified poly(zwitterions), resulting in p[DMAEMA-co-3-dimethyl(methacryloyloxyethyl)ammonium propanesulfonate] (PDMAEMA-co-PDMAPS). Molecular weight, molecular weight distribution, and degree of quarternization were determined by gel permeation chromatography (GPC) and 1H NMR spectroscopy. The transmission spectra of the 1.0 wt % aqueous solutions of the resulting polymers at 650 nm were measured as a function of temperature. Results showed that the lower critical solution temperature (LCST) and the upper critical solution temperature (UCST) could be easily controlled by the different composition of dimethylamino and zwitterion groups. The effect of partial quaternization on thermoresponsive properties was also studied by dynamic light scattering (DLS) with the same aqueous concentration (1.0 wt %) as employed for turbidimetry studies. The LCST and UCST values measured by DLS correlated well with those determined by turbidimetry.

Nonlinear Motion for an Elliptic Cylinder under Free Surface (자유표면 아래의 타원형 실린더에 대한 비선형 운동)

  • 이호영;임춘규
    • Journal of the Society of Naval Architects of Korea
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    • v.41 no.4
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    • pp.38-44
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    • 2004
  • The motion response analysis of a submerged elliptic cylinder in waves is presented and the elliptic cylinder is a simplification of the section of submarine in this paper. The method is based on boundary integral method and two-dimensional 3 degree motions are calculated in regular harmonic waves. The fully nonlinear free surface boundary condition is assumed in an numerical domain and this solution is matched along an assumed boundary as a linear solution composed of transient Green function, The large amplitude motions of an elliptic cylinder are directly simulated and effects of wave frequency, wave amplitude and the distance from buoyancy center to gravity center are discussed.

Facile and Room Temperature Preparation and Characterization of PbS Nanoparticles in Aqueous [EMIM][EtSO4] Ionic Liquid Using Ultrasonic Irradiation

  • Behboudnia, M.;Habibi-Yangjeh, A.;Jafari-Tarzanag, Y.;Khodayari, A.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.53-56
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    • 2009
  • At room-temperature, a facile, seedless, and environmentally benign green route for the synthesis of star like PbS nanoclusters at 7 min in aqueous solution of 1-ethyl-3-methylimidazolium ethyl sulfate, [EMIM] [$EtSO_{4}$], room-temperature ionic liquid (RTIL), via ultrasonic irradiation is proposed. The X-ray diffraction studies display that the products are excellently crystallized in the form of cubic structure. An energy dispersive X-ray spectroscopy (EDX) investigation reveals the products are extremely pure. The absorption spectra of the product exhibit band gap energy of about 4.27 eV which shows an enormous blue shift of 3.86 eV that can be attributed to very small size of PbS nanoparticles produced and quantum confinement effect. A possible formation mechanism of the PbS nanoparticles using ultrasonic irradiation in aqueous solution of the RTIL is presented.

Adsorption of Dyes from Aqueous Solution by Cow Dung Ash

  • Rattan, V.K.;Purai, Abhiti;Singh, Harminder;Manoochehri, Mahboobeh
    • Carbon letters
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    • v.9 no.1
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    • pp.1-7
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    • 2008
  • The ability of cow dung ash without any pretreatment to remove color from textile dyes N Blue RGB, Green B and EOSIN YWS from aqueous solution has been investigated in this work. Cow dung ash, an ecofriendly and low cost adsorbent was prepared by burning cow dung cakes in the muffle furnace at $500^{\circ}C$. The adsorption was achieved under different pH and adsorbate concentration. The data was fitted to simple polynomial and the isotherms similar to Langmuir and Freundlich isotherms.

MAX-NORM ERROR ESTIMATES FOR FINITE ELEMENT METHODS FOR NONLINEAR SOBOLEV EQUATIONS

  • CHOU, SO-HSIANG;LI, QIAN
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.5 no.2
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    • pp.25-37
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    • 2001
  • We consider the finite element method applied to nonlinear Sobolev equation with smooth data and demonstrate for arbitrary order ($k{\geq}2$) finite element spaces the optimal rate of convergence in $L_{\infty}\;W^{1,{\infty}}({\Omega})$ and $L_{\infty}(L_{\infty}({\Omega}))$ (quasi-optimal for k = 1). In other words, the nonlinear Sobolev equation can be approximated equally well as its linear counterpart. Furthermore, we also obtain superconvergence results in $L_{\infty}(W^{1,{\infty}}({\Omega}))$ for the difference between the approximate solution and the generalized elliptic projection of the exact solution.

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Moment of inertia of liquid in a tank

  • Lee, Gyeong Joong
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.6 no.1
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    • pp.132-150
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    • 2014
  • In this study, the inertial properties of fully filled liquid in a tank were studied based on the potential theory. The analytic solution was obtained for the rectangular tank, and the numerical solutions using Green's 2nd identity were obtained for other shapes. The inertia of liquid behaves like solid in recti-linear acceleration. But under rotational acceleration, the moment of inertia of liquid becomes small compared to that of solid. The shapes of tank investigated in this study were ellipse, rectangle, hexagon, and octagon with various aspect ratios. The numerical solutions were compared with analytic solution, and an ad hoc semi-analytical approximate formula is proposed herein and this formula gives very good predictions for the moment of inertia of the liquid in a tank of several different geometrical shapes. The results of this study will be useful in analyzing of the motion of LNG/LPG tanker, liquid cargo ship, and damaged ship.

A polynomial mathematical tool for foundation-soil-foundation interaction

  • Sbartai, Badreddine
    • Geomechanics and Engineering
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    • v.23 no.6
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    • pp.547-560
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    • 2020
  • This paper studies the dynamic foundation-soil-foundation interaction for two square rigid foundations embedded in a viscoelastic soil layer. The vibrations come from only one rigid foundation placed in the soil layer and subjected to harmonic loads of translation, rocking, and torsion. The required dynamic response of rigid surface foundations constitutes the solution of the wave equations obtained by taking account of the conditions of interaction. The solution is formulated using the frequency domain Boundary Element Method (BEM) in conjunction with the Kausel-Peek Green's function for a layered stratum, with the aid of the Thin Layer Method (TLM), to study the dynamic interaction between adjacent foundations. This approach allows the establishment of a mathematical model that enables us to determine the dynamic displacements amplitude of adjacent foundations according to their different separations, the depth of the substratum, foundations masss, foundations embedded, and the frequencies of excitation. This paper attempts to introduce an approach based on a polynomial mathematical tool conducted from several results of numerical methods (BEM-TLM) so that practicing civil engineers can evaluation the dynamic foundations displacements more easy.

UNIQUENESS OF TOPOLOGICAL SOLUTIONS FOR THE GUDNASON MODEL

  • Kim, Soojung;Lee, Youngae
    • Journal of the Korean Mathematical Society
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    • v.58 no.4
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    • pp.873-894
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    • 2021
  • In this paper, we consider the Gudnason model of 𝒩 = 2 supersymmetric field theory, where the gauge field dynamics is governed by two Chern-Simons terms. Recently, it was shown by Han et al. that for a prescribed configuration of vortex points, there exist at least two distinct solutions for the Gudnason model in a flat two-torus, where a sufficient condition was obtained for the existence. Furthermore, one of these solutions has the asymptotic behavior of topological type. In this paper, we prove that such doubly periodic topological solutions are uniquely determined by the location of their vortex points in a weak-coupling regime.