• Title/Summary/Keyword: Green emission

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Synthesis of 3-Chromonealdehyde(2,2-disubstituted)hydrazone Derivatives for Green Light Emitting Materials (녹색발광 3-크로몬알데히드(2,2-이치환)하이드라존 유도체의 합성)

  • Chung, Pyung Jin;Chang, Hong Joon
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.670-674
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    • 2009
  • 3-Chromonealdehyde(2,2-disubstituted)hydrazone derivatives were synthesized by dehydration condensation. They are green-emitting materials for organic light emitting device (OLED) composed of electron acceptor of 3-chromonealdehydes and electron donor of 2,2-disubstituted hydrazones by a conjugated structure. The structural properties of reaction products were analyzed FT-IR and $^1H-NMR$ spectroscopy. The thermal stabilities and reactivities were measured by melting points and yields. The UV-visibles and PL properties can be determined by excitation spectra and emission spectra, respectively.

Study of Europium-activated Calcium Aluminium Silicate Phosphors (유로피움-활성화 칼슘 알루미늄 실리케이트 형광체 연구)

  • Hwang, Jung-Ha;Park, Ju-Seok;Jang, Bo-Yun;Nahm, Sahn;Kim, Joon-Soo;Yu, Soon-Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.11
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    • pp.1020-1024
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    • 2006
  • Europium$(Eu^{2+}\;or\;Eu^{3+})$-activated calcium aluminium silicate phosphors were synthesized for the first time and the structures and luminescence characteristics of these phosphors were investigated. The phosphors in this study emitted blue, green, and even red light depending on the starting milterials and annealing conditions for synthesis. In addition, the structure was also changed when the different starting materials were used. When $CaCO_3$ was used as a starting material, tetragonal $Ca_2Al_2SiO_7$ was formed. However, pure green light was emitted when the annealing was conducted in reduced atmosphere and red one was emitted by annealing in air. In the case of $CaSiO_3$ as a starting material, triclinic $CaAl_2Si_2O_8$ was formed and only pure blue emission was observed. Moreover, this blue phosphor exhibited higher intensity than that of commercial YAG:Ce phosphor, which showed the possibility of application on the phosphor for new light source such as a UV-LED.

The Logistics Equipment Carbon Emission Monitoring System for a Green Port (Green Port 구현을 위한 물류장비 탄소배출 모니터링 시스템)

  • Choi, Hyung-Rim;Park, Byoung-Kwon;Lee, Byung-Ha;Park, Yong-Sung;Lee, Chang-Sup;Kwon, Tae-Woo
    • 한국IT서비스학회:학술대회논문집
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    • 2010.05a
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    • pp.80-84
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    • 2010
  • 미국 환경단체가 발표한 자료에 따르면, 항만이 대기오염의 주범으로 알려진 자동차나 발전소보다 더 많은 오염물질을 배출하고 있으며, 특히 컨테이너트럭과 하역장비에서 많은 오염물질을 배출하는 것으로 확인되었다. 세계 5위의 컨테이너 물동량을 처리하는 부산항을 비롯하여 많은 항만을 보유하고 있는 우리나라도 적극적으로 항만에서 배출하는 온실가스를 감축하기 위한 노력이 필요하다. 이를 해결하기 위해서 본 연구에서는 IP-RFID라는 새로운 기술을 이용하여 항만 터미널내의 물류장비(컨테이너 트럭, 하역장비 등)들의 탄소배출량을 실시간으로 관리할 수 있는 모니터링시스템을 개발하고자 한다. 본 연구에서는 개발하는 모니터링시스템은 개별 물류장비의 탄소량을 실시간으로 측정하여 IP통신을 통해 다양한 사용자에게 직접 정보를 전달할 수 있는 IP-Tag를 부착하여, 개별 물류장비별 탄소배출량을 적극적으로 관리할 수 있는 시스템이다. 이 시스템을 통해 물류장비별로 탄소배출량 관리가 가능해지고 운전자도 실시간으로 장비의 탄소배출량을 확인할 수 있기 때문에, 항만의 탄소배출량을 감축할 수 있을 것이다.

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Effects of Organic and Inorganic Binder Core on Microstructure and Mechanical Properties of Al Casting Products (알루미늄 주조품의 미세조직 및 기계적 특성에 미치는 유·무기 화합물 중자의 영향)

  • Shin, Sang-Soo;Kim, Woo-Chun;Kim, Eok-Soo;Lim, Kyoung-Mook;Park, Jeong-Wook
    • Journal of Korea Foundry Society
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    • v.33 no.4
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    • pp.147-156
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    • 2013
  • The effects of core materials on the microstructure and mechanical properties of Al casting products have been investigated. The Al casting samples and cylinder head were fabricated by using organic and inorganic binder core respectively, and their microstructure and mechanical properties were evaluated. The Al casting samples fabricated by using inorganic core showed the better mechanical properties such as tensile strength and elongation than those of the Al casting samples fabricated by using organic core. That's because the Al casting samples contained small amount of pore defects and had fine microstructure compared with the Al casting samples fabricated by using organic core. Also, the use of inorganic core effectively reduced harmful gas emission and pollution.

Electroluminescent Characteristics of Green Phosphorescent Organic Light Emitting Devices with the Mixed Host Layer of TCTA:TAZ between TCTA and TAZ (TCTA-TAZ 사이 TCTA:TAZ 혼합호스트 층을 갖는 녹색 인광소자의 전계발광 특성)

  • Jang, J.G.;Shin, S.B.;Shin, H.K.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.427-428
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    • 2008
  • New high efficiency green light emitting phosphorescent devices with emission layers of [TCTA/TCTA:TAZ/TAZ]:Ir$(ppy)_3$ have been fabricated and evaluated in this paper. Among the devices having different thicknesses of TCTA:TAZ mixed layer in the total 300$\AA$-thick host of TCTA(80$\AA$)/TCTA:TAZ (50~100$\AA$)/TAZ, the device with host of TCTA(80$\AA$)/TCTA:TAZ(90$\AA$)/TAZ(130$\AA$) showed the best electroluminescent characteristics with the current density of 95 mA/$cm^2$ and luminance of 25,000 cd/$m^2$ at an applied voltage of 10V. The maximum current efficiency was 52 cd/A under the luminance of 400 cd/$m^2$.

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CdS Nanoparticles as Efficient Fluorescence Resonance Energy Transfer Donors for Various Organic Dyes in an Aqueous Solution

  • Ock, Kwang-Su;Ganbold, Erdene-Ochir;Jeong, Sae-Ro-Mi;Seo, Ji-Hye;Joo, Sang-Woo
    • Bulletin of the Korean Chemical Society
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    • v.32 no.10
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    • pp.3610-3613
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    • 2011
  • CdS nanoparticles (NPs) were synthesized in an aqueous phase in order to investigate their spectral behaviors as efficient fluorescence resonance energy transfer (FRET) donors for various organic dye acceptors. Our prepared CdS NPs exhibiting strong and broad emission spectra between 480-520 nm were able to transfer energy in a wide wavelength region from green to red fluorescence dyes. Rhodamine 6G (Rh6G), rhodamine B (RhB), and sulforhodamine 101 acid (Texas red) were tested as acceptors of the energy transfer from the CdS NPs. The three dyes and synthesized CdS NPs exhibited good FRET behaviors as acceptors and donors, respectively. Energy transfers from the CdS NPs and organic Cy3 dye were compared to the same acceptor Texas red dye at different concentrations. Our prepared CdS NPs appeared to exhibit better FRET behaviors comparable to those of the Cy3 dye. These CdS NPs in an aqueous solution may be efficient FRET donors for various organic dyes in a wide wavelength range between green and red colors.

Photoluminescence Properties of Green Phosphor Y1-xBO3:Tbx3+ Synthesized by Solid-state Reaction Method (고상 반응법으로 제조한 녹색 형광체 Y1-xBO3:Tbx3+의 형광 특성)

  • Cho, Shin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.8
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    • pp.659-663
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    • 2011
  • [ $Y_{1-x}BO_3:Tb_x^{3+}$ ]ceramic phosphors were synthesized with changing the concentration of $Tb^{3+}$ at a sintering temperature of $1,100^{\circ}C$ and a reduction temperature of $950^{\circ}C$ by using a solid-state reaction method. The crystal structure, surface morphology, and photoluminescence properties of the phosphors were investigated as a function of $Tb^{3+}$ ion concentration by using XRD (x-ray diffractometer), scanning electron microscopy, and photoluminescence spectrophotometry, respectively. The XRD results showed that the main peak of the phosphor powders occurs at (101) plane. As for the photoluminescence properties, the excitation spectra showed the broad band centered at 306 nm and the emission intensity of the spectra peaked at 543 nm indicated a significant decrease as the concentration of $Tb^{3+}$ ion is increased.

The Improvement of color reproduction ratio used to CCFL with high color rendering characteristic in TFT-LCD (고연색 CCFL을 이용한 TFT-LCD 색재현율의 향상)

  • Park, Ki-Duck;Song, Yong-Ki;Park, Doo-Sung;Kim, Seo-Yoon;Lim, Young-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.438-440
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    • 2005
  • At present, characteristic of high color reproduction for LCD TV is needed in Display market according to start mass production of LCD TV. Therefore development target for LCD is focused on improvement of color reproduction. The improving methods of high color reproduction are alteration of color Filter or Red, Green, Blue phosphor alteration of CCFL. But decrease of luminance and panel transmittance is caused by alteration of Color Filter. Accordingly, we completed LCD with high color reproduction by the most suitable emission spectrum of CCFL phosphor at panel with conventional color filter. In this experiment, we knew that LCD applied to CCFL with high color rendering characteristic had color reproduction range of 81% compared with NTSC in CIE color coordinate. According to increase of intensity peak and alteration of Red, Green, Blue phosphor spectrum, we made LCD with high color reproduction characteristic. In conclusion we achieved improvement of color reproduction ratio by alteration of CCFL phosphor without changing color filter.

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QoS Aware Energy Allocation Policy for Renewable Energy Powered Cellular Networks

  • Li, Qiao;Wei, Yifei;Song, Mei;Yu, F. Richard
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.10 no.10
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    • pp.4848-4863
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    • 2016
  • The explosive wireless data service requirement accompanied with carbon dioxide emission and consumption of traditional energy has put pressure on both industria and academia. Wireless networks powered with the uneven and intermittent generated renewable energy have been widely researched and lead to a new research paradigm called green communication. In this paper, we comprehensively consider the total generated renewable energy, QoS requirement and channel quality, then propose a utility based renewable energy allocation policy. The utility here means the satisfaction degree of users with a certain amount allocated renewable energy. The energy allocation problem is formulated as a constraint optimization problem and a heuristic algorithm with low complexity is derived to solve the raised problem. Numerical results show that the renewable energy allocation policy is applicable not only to soft QoS, but also to hard QoS and best effort QoS. When the renewable energy is very scarce, only users with good channel quality can achieve allocated energy.

Synthesis of Green Emitting Materials for OLED (유기발광 디바이스용 녹색 발광재료의 합성)

  • Chung, Pyung Jin;Kim, Mi Rae
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.594-598
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    • 2011
  • We study on the preparation of green emitting materials for organic light emitting device. 3-chromonealdehyde derivatives possessing a conjugated structure, which were composed of electron acceptor of 3-chromonealdehydes and electron donor of diamines, were synthesized by dehydration-condensation process. The structural properties of reaction products were analyzed FT-IR and $^1H-NMR$ spectroscopy. The thermal stabilities and reactivities were measured by melting points and yields. The UV-visibles and PL properties can be determined by excitation spectra and emission spectra, respectively.