Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
권호 표지

Synthesis of 3-Chromonealdehyde(2,2-disubstituted)hydrazone Derivatives for Green Light Emitting Materials

녹색발광 3-크로몬알데히드(2,2-이치환)하이드라존 유도체의 합성

  • Chung, Pyung Jin (Department of Materials Science and Engineering, Dankook University) ;
  • Chang, Hong Joon (Department of Materials Science and Engineering, Dankook University)
  • 정평진 (단국대학교 신소재공학과) ;
  • 장흥준 (단국대학교 신소재공학과)
  • Received : 2009.09.01
  • Accepted : 2009.10.07
  • Published : 2009.12.10
Download PDF
⟨ Previous Next ⟩

Abstract

3-Chromonealdehyde(2,2-disubstituted)hydrazone derivatives were synthesized by dehydration condensation. They are green-emitting materials for organic light emitting device (OLED) composed of electron acceptor of 3-chromonealdehydes and electron donor of 2,2-disubstituted hydrazones by a conjugated structure. The structural properties of reaction products were analyzed FT-IR and $^1H-NMR$ spectroscopy. The thermal stabilities and reactivities were measured by melting points and yields. The UV-visibles and PL properties can be determined by excitation spectra and emission spectra, respectively.

본 연구는 유기발광디바이스용(OLED) 녹색형광물질인 3-크로몬알데히드(2,2-이치환)하이드라존 유도체의 합성에 관한 것으로서, 유도체들은 탈수축합반응으로 합성되었다. 이들은 전자흡인성의 3-크로몬알데히드류와 전자공여성의 2,2-이치환하이드라존류의 공액구조를 가지고 있다. 합성한 물질은 각각 FT-IR, $^1H-NMR$ 스펙트럼으로부터 그의 구조적 특성을 확인하였고, 융점, 수득률에 의하여 열적 안정성, 반응성을 확인하였으며, 여기스펙트럼과 발광스펙트럼으로부터 자외가시광과 발광특성을 확인하였다.

Keywords

Acknowledgement

Supported by : 단국대학교

References

  1. T. W. Hagler, K. Pakbaz, K. F. Voss, and A. J. Heeger, Phys. Rev. B, 44, 8652 (1991) https://doi.org/10.1103/PhysRevB.44.8652
  2. M. Pope, H. Kallmann, and J. Giachino, J. Chem. Phys., 42, 2540 (1965) https://doi.org/10.1063/1.1696329
  3. C. W. Tang and S. A. VanSlyke, Appl. Phys. Lett., 51. 913 (1987) https://doi.org/10.1063/1.98799
  4. J. H. Burroughes, D. D. C. Bradley, A. R. Brown, R. N. Marks, K. Mackay, R. H. Friend, P. L. Burns, and A. B. Holmes, Nature, 347, 539 (1990) https://doi.org/10.1038/347539a0
  5. P. J. Chung and J. H. Sung, J. Korean Ind. Eng. Chem., 17, 609 (2006)
  6. P. J. Chung and J. H. Sung, J. Korean Ind. Eng. Chem., 18, 587 (2007)
  7. P. J. Chung and J. H. Sung, J. Korean Ind. Eng. Chem., 20, 40 (2009)