• Publications of The Korean Astronomical Society
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• v.30 no.2
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• pp.443-445
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• 2015

We provide results of near-infrared (NIR) spectroscopic observations of 83 nearby (0.002< z <0.48) and bright (K <14 mag) type 1 active galactic nuclei (AGNs). For the observations, we used the Infrared Camera (IRC) on AKARI allowing us to obtain the spectrum in the rarely studied spectral range of $2.5-5.0{\mu}m$. The $2.5-5.0{\mu}m$ spectral region suffers less dust extinction than ultra violet (UV) or optical wavelength ranges, and contains several important emission lines such as $Br{\beta}$ ($2.63{\mu}m$), $Br{\alpha}$ ($4.05{\mu}m$), and polycyclic aromatic hydrocarbon (PAH; $3.3{\mu}m$). The sample is selected from the bright quasar surveys of Palomar Green and SNUQSO, and AGNs with black hole (BH) masses estimated from reverberation mapping method. We measure the Brackett line properties for 11 AGNs, which enable us to derive BH mass estimators and investigate circum-nuclear environments. Moreover, we perform spectral modeling to fit the hot and warm dust components by adding photometric data from SDSS, 2MASS, WISE, and ISO to the AKARI spectra, and estimate hot and warm dust temperatures of ~1100K and ~220 K, respectively.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.2
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• pp.74.2-74.2
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• 2012

Metallicity is an important tracer of star formation in galaxy evolution. Based on the flux ratios of broad emission lines, AGN metallicity has shown a correlation with AGN luminosity. However, it is not clear what physical parameter drives the observed correlation. Using a sample 69 Palomar-Green QSOs at low-z (z<0.5), we determine BLR gas metallicity from emission line flux ratios, i.e., N V1240/C IV1549, (Si IV1398+O IV1402)/C IV1549 and N V1240/He II1640 based on the UV spectra from the HST and IUE archives. We compare BLR gas metallicity with various AGN properties, i.e., black hole mass, AGN luminosity and Eddington ratio, in order to investigate physical connection between metal enrichment and AGN activity. In contrast to high-z QSOs, which show the correlation between metallicity and black hole mass, we find that the metallicity of low-z QSOs correlates with Eddington ratio, but not with black hole mass, suggesting that metallicity enrichment mechanism is different between low-z and high-z.

• Advances in nano research
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• v.3 no.2
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• pp.55-66
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• 2015

Crystalline $Ce^{3+}$ co-doped $LaPO_4$:RE ($RE=Dy^{3+}$, $Tb^{3+}$, $Eu^{3+}$, $Sm^{3+}$) and mix doped rare earth ions of $Dy^{3+}$, $Tb^{3+}$ and $Eu^{3+}$ were prepared by the polyol method at $150^{\circ}C$. Strongly enhance luminescence intensity is obtained with the co-doping of $Ce^{3+}$ with $LaPO_4$:$Dy^{3+}$ and $LaPO_4$:$Tb^{3+}$ due to charge transfer (CT) occurring from $Ce^{3+}$ to $Dy^{3+}$ and $Ce^{3+}$ to $Tb^{3+}$, where as there is no significant changes in luminescence intensity of $Ce^{3+}$ co-doped $Eu^{3+}$ and $Sm^{3+}$ doped $LaPO_4$ samples. The luminescence color can be tuned from green to white by varying the excitation wavelength for the mix ions $Ce^{3+}$, $Dy^{3+}$, $Tb^{3+}$ and $Eu^{3+}$ doped with $LaPO_4$.

• Korean Journal of Materials Research
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• v.13 no.8
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• pp.509-513
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• 2003

In the present investigation, $La^{3＋}$ and $Ce^{V}$ ions were substituted for $Y^{3＋}$ in the $YBO_3$: Tb in various concentrations. It has been found that these phosphors form solid solutions within limited concentration ranges Excitation and emission spectra under 254 nm and 147 nm were investigated for these phosphors to evaluate influences of $La^{3＋}$ and $Ce^{3＋}$ ions on brightness and CIE color coordinates. It has been observed that brightness of $(Y, La)BO_3$: Tb under 254 nm and 147 nm when $La^{3＋}$ ions are added show an increase of 2.7 times and 1.25 times, respectively. On the other hand, emission intensities of peaks in $Y_{0.8-x}$ $BO_3$: $Tb_{0.2}$ , $Ce_{x}$ show continuos decrease as $Ce^{3＋}$ / content is increased from 0 to 0.4. CIE color coordinates of prepared phosphors show yellowish green which is needed to be improved to be used for display applications.

• KIEAE Journal
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• v.11 no.2
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• pp.67-74
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• 2011

Recently environmental regulations like the Kyoto Protocol, adopted in 1997, required the reduction of the greenhouse gas of 5.2% up to 1990's emissions and 13th General Assembly in 2007, held in Bali of India, have agreed to duty reduction even in developing countries in 2013. Korean government needs research on climate change and greenhouse gas management, such as carbon emissions calculation system and the introduction of greenhouse gas reduction program. Using Top-Down approach with method of IPCC, greenhouse gas emissions from energy, transportation, agriculture, land use and forest, and waste was calculated. Total amount from Shiheung-City in 2007 was about 3,299.581 tons of greenhouse gas $CO_2$. By sectors, the total greenhouse gas emissions in the energy sector mostly accounted for 78 percent, 12 percent from transportation, 6 percent of waste, the landuse/forest sector, 4% of the greenhouse gas emissions. Approximately 5,401,618 tons of the greenhouse gas $CO_2$ was total amount from Ansan-City in 2007. The share of energy sector greenhouse gas emissions was the highest portion of 79 % and 14 percent of transportation, 4% from the waste sector, 3 % from landuse/forest sector.

• Electrical & Electronic Materials
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• v.10 no.1
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• pp.33-38
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• 1997

The green emitting phosphors of the Field Emission Display(FED), Al codoped ZnGa$_{2}$O$_{4}$:Mn, were synthesized and sintered at high temperature. From X-ray diffraction measurements, it was confirmed that poly crystalline ZnGa$_{2}$O$_{4}$ and ZnAI$_{2}$O$_{4}$ solid solution coexist in Al codoped ZnGa$_{2}$O$_{4}$:Mn. Photoluminescence spectra of Al codoped ZnGa$_{2}$O$_{4}$:Mn show that the main peak position is shifted from 504 nm to 513 nm with the increase of Al concentration. The brightness was improved with the amount of Al dopant. It showed the maximum value at the doping level of 0.03 mole and then, it degraded rapidly. These results are due to the superposition of emission from . ZnGa$_{2}$O$_{4}$:Mn and ZnAI$_{2}$O$_{4}$:Mn.

• Journal of the Korean Society of Combustion
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• v.17 no.4
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• pp.5-10
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• 2012

The reformer system is a chemical device that drives the conversion of hydrocarbon to hydrogen rich gas under high temperature environment($600-1,000^{\circ}C$). Generally, NG(Natural Gas) or AOG(Anode Off Gas) is used as fuel of fuel cell reformer combustion system. The experimental study to analyze the combustion characteristics of a premixed ceramic burner used for 0.5-1.0 kW fuel cell reformer was performed. Ceramic burner experiments using NG and AOG were carried out to investigate the flame stability characteristics by heating capacity, equivalence ratio and different fuels respectively. The results show that surface flames can be classified into green, red, blue and lift-off flames as the equivalence ratio of methane-air mixture decreases. And the stable flames can be established using NG and AOG as reformer fuel in the perforated ceramic burner. In particular, the blue flame is found to be stable at a lean equivalence ratio under different mixture conditions of NG and AOG for the 0.5 to 1.0 kW fuel cell system power range. NOx emission is under 60 ppm between 0.70 to 0.78 of equivalence ratio and CO emission is under 50 ppm between 0.70 to 0.84 of equivalence ratio.

• Korean Journal of Optics and Photonics
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• v.7 no.2
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• pp.120-128
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• 1996

We studied the red, green and blue upconverted emission in 1 at.% $Er^{3+}: LaF_3$ and 1 at.% $Er^{3+}:YAlO_3$ crystals y pumping in 780~820 nm range at 14 K and 295 K. A cw titanium-sapphire laser was used to pump the $^4I_{9/2}$ level in two materials. The spectral analysis of the emission from $^4F_{9/2},\;^4S_{3/2}$ and $^2P_{3/2}$ levels allowed to reveal the upconversion process with multi-step absorption and cross-relaxation energy transfer.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.68-68
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• 2010

Electroluminescence (EL) characteristics of green-emission ZnS:Cu,Cl-based ac-type inorganic powder electroluminescent structures were examined by inserting carbon nanotubes (CNTs) into or next to the dielectric layer. For the top-emission type EL structure, where the luminescent light was emitted from the top of the structure, was fabricated by assembling in order, a top electrode, an emitting layer, a dielectric layer, and a bottom electrode from the top. $BaTiO_3$ powder mixed with CNTs was used as a dielectric layer or CNTs were deposited between the bottom electrode and $BaTiO_3$ dielectric layer in order to improve the role of the dielectric layer in the structure. Luminance of an EL structure with CNTs inclusion was greatly enhanced possibly due to the high dielectric constant in the dielectric layer of $BaTiO_3$/CNTs, which is one of hot research topics utilizing nano-objects for intensifying dielectric constant and reducing dielectric loss at the same time. A variation on the CNTs themselves and their inclusion methods in the dielectric layer has been exhorted, and the underlying mechanism for the role of CNTs in the EL structure will be explained in the poster. In order to extend the flexibility of EL devices, EL devices were fabricated on the paper substrate and their performance was compared other EL devices on the plastic-based substrate.

• Journal of the Semiconductor & Display Technology
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• v.9 no.2
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• pp.1-6
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• 2010

Star-like ZnO nanostructures were grown on SI(100) substrates with carbon(C) catalyst by employing vapor-solid(VS) mechanism. The morphologies and structure of ZnO nanostructures were investigated by Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and Raman spectrum, Photoluminescence spectrum. The results demonstrated that the as-synthesized products consisted of star-like ZnO nanostructure with hexagonal wurtzite phase. Nanostructures grown at 1100 were mainly star-like in structure with diameters of 500 nm. The legs of the star-like nanostructures were preferentially grown up along the [0001] direction. A vapor.solid (VS) growth mechanism was proposed to explain the formation of the star-like structures. Photoluminescence spectrum exhibited a narrow emission band peak around 380 nm and a broad one around 491 nm. Raman spectrum of the ZnO nanostructures showed oxygen defects in ZnO nanostructures due to the existence of Ar gas during the growth process, leading to the dominant green band peak in the PL spectrum.